• Title/Summary/Keyword: structural relaxation

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The structural and dielectric polarization characteristics of composite oxide material in $(Ba Ca)TiO_3$-Zn (복합산화물 $(Ba Ca)TiO_3$-ZnO의 구조적 및 유전분극 특성)

  • 홍경진;임장섭;정우성;민용기;김용주;김태성
    • Electrical & Electronic Materials
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    • v.10 no.3
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    • pp.239-246
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    • 1997
  • The ZnO is stabilize dielectric constant over a broad temperature range because its addition makes the relaxation time short. In this study, the composite oxide material (B $a_{0.85}$ $Ca_{0.15}$)Ti $O_{3}$ was mixed by ZnO additive material and the dielectric polarization characteristics was studied. The relative density was over 90[%] at all specimen in the structural characteristics. Among of the specimen, the relative density of (B $a_{0.85}$ $Ca_{0.15}$)Ti $O_{3}$ with ZnO (0.4mol) has a 95[%]. The grain size of composite oxide material with an increasing ZnO increased and it was 1.0[.mu.m]-1.22[.mu.m]. In the electrical characteristics, the charge and discharge current was increased by ZnO addition. The dielectric relaxation time was increased by space charge polarization at above 110[.deg. C] and the dielectric relaxation time was fixed by space charge polarization of para-dielectric layer at below 110[.deg. C]. The dielectric relaxation time was maximum when the grain size was small. The dielectric relaxation time is decreased with an additive material ZnO and interface polarization, existing void at the grain and grain boundary. The remnant polarization is increased and the coercive electric field is decreased by ZnO.

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Nucleus-phonon interactions of MCsSO4 (M = Na, K, or Rb) single crystals studied using spin-lattice relaxation time

  • Choi, Jae Hun;Kim, Nam Hee;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.18 no.1
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    • pp.15-23
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    • 2014
  • The structural properties and relaxation processes of $MCsSO_4$ (M = Na, K, or Rb) crystals were investigated by measuring the NMR spectra and spin-lattice relaxation rates $1/T_1$ of their $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei. According to the NMR spectra, the $MCsSO_4$ crystals contain two crystallographically inequivalent sites each for the M and Cs ions. Further, the relaxation rates of all these nuclei do not change significantly over the investigated temperature range, indicating that no phase transitions occur in these crystals in this range. The variations in the $1/T_1$ values of the $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei in these three crystals with increasing temperature are approximately proportional to $T^2$, indicating that Raman processes may be responsible for the relaxation. Therefore, for nuclear quadrupole relaxation of the $^{23}Na$, $^{39}K$, $^{87}Rb$, and $^{133}Cs$ nuclei, Raman processes with n = 2 are more effective than direct processes.

Shape Finding and Stress Finding for Pneumatic Membrane Structures by Dynamic Relaxation Method (동적이완법에 의한 공기막구조물의 형태탐색과 응력해석)

  • 문창훈;이경수;배종효;최옥훈;한상을
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1999.04a
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    • pp.268-275
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    • 1999
  • The purpose of this study is to propose the method of determining the initial pneumatic membrane structures surface and stresses and displacements. Tension structure such as pneumatic membrane structures is stabilized by their initial prestress and air pressure. The process to find initial structural overall shape of tension structures produced by initial prestress called shape finding. One of the most important factor for the design of membrane structures is to search initial smooth surface, because unlike steel or concrete building elements which resist loads in bending, all tension structure forces are carried within the surface by membrane stress. The result for initial surface of pneumatic membrane element and maximum displacement in large deformation in analysis is compared with well-known nonlinear numerical method such as Newton-raphson method and dynamic relaxation method

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A study on the non-linear analysis of the elastic catenary cable considering kinetic damping (동적감쇠를 고려한 탄성 현수선 케이블의 비선형 해석에 관한 연구)

  • 한상을;정명채;이진섭
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2000.10a
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    • pp.331-338
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    • 2000
  • In this paper, a non-linear finite element formulation for the spatial cable-net structures is simulated and using this formulation, the characteristics of structural behaviors for the elastic catenary cable are examined In the simulating procedure for the elastic catenary cable, nodal forces and tangential stiffness matrices are derived using catenary parameters of the exact solutions by a governing differential equation of catenary cable, cable self-weights and unstressed cable length. Dynamic Relaxation Method that considers kinetic damping is used for the structure analysis and Newton Raphson Method is used to verify the accuracy of solutions. In the analysis of two dimensional cable, the results obtain from the elastic catenary elements are shown more accurate than does of truss elements and in the case of spatial cable-net structures, Dynamic Relaxation Method is more stable to be converged than Newton Raphson Method.

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Structural Characteristics of 3- and 4-Coordinate Borons from 11B MAS NMR and Single-Crystal NMR in the Nonlinear Optical Material BiB3O6

  • Kim, Woo Young;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.17 no.1
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    • pp.24-29
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    • 2013
  • The structural characteristics of 4-coordinate $BO_4$ [B(1)] and 3-coordinate $BO_3$ [B(2)] groups in $BiB_3O_6$ were studied by $^{11}B$ magic angle spinning (MAS) and single-crystal nuclear magnetic resonance (NMR) spectroscopy. The spin-lattice relaxation time in the laboratory frame, $T_1$, for $^{11}B$ decreased slowly with increasing temperature, whereas the spin-lattice relaxation times in the rotating frame, $T_{1{\rho}}$, for B(1) and B(2), which differed from $T_1$, were nearly constant. Further, $T_{1{\rho}}$ for B(1) and B(2) showed very similar trends, although the $T_{1{\rho}}$ value of B(2) was shorter than that of B(1). The 3-coordinate $BO_3$ and 4-coordinate $BO_4$ were distinguished by $^{11}B$ MAS NMR spectrum and $T_{1{\rho}}$.

Static Non-linear Finite Element Analysis of Spatial Cable Networks (3차원 케이블망의 초기평형상태 결정 및 정적 비선형 유한요소해석)

  • 김문영;김남일;안상섭
    • Computational Structural Engineering
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    • v.11 no.1
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    • pp.179-190
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    • 1998
  • A geometrically nonlinear finite element formulation of spatial cable networks is presented using two cable elements. Firstly, derivation procedures of tangent stiffness and mass matrices for the space truss element and the elastic catenary cable element are summarized. The load incremental method based on Newton-Raphson iteration method and the dynamic relaxation method are presented in order to determine the initial static state of cable nets subjected to self-weights and support motions. Furthermore, static non-linear analysis of cable structures under additional live loads are performed based on the initial configuration. Challenging example problems are presented and discussed in order to demonstrate the feasibility of the present finite element method and investigate static nonlinear behaviors of cable nets.

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Structural nature of chemically inequivalent borons in the nonlinear optical material β-BaB2O4 studied using 11B MAS NMR and 11B single-crystal NMR

  • Kim, Woo Young;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
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    • v.17 no.2
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    • pp.86-91
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    • 2013
  • Detailed information about the structural nature of three-coordinate borons in ${\beta}-BaB_2O_4$ is obtained through $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR. The three-coordinate $BO_3$ of the two borons B(1) and B(2) in ${\beta}-BaB_2O_4$ were distinguished. The spin-lattice relaxation time in the laboratory frame $T_1$ for B(1) and B(2) slowly decreases with increasing temperature, whereas the spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for B(1) and B(2), which differs from $T_1$, is nearly constant. The B(1) and B(2) of the two types were distinguished by $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR.

Ultrasonic Velocity and Absorption Measurements in an Aqueous Solution of Poly(sodium 4-styrenesulfonate)

  • Rae Jong-Rim
    • Macromolecular Research
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    • v.12 no.6
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    • pp.559-563
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    • 2004
  • Both the ultrasonic velocity at 3 MHz and the absorption coefficient in the frequency range from 0.2 to 2 MHz were measured for aqueous solutions of poly(sodium 4-styrenesulfonate) over the concentration range from 5 to $25\%$ (by weight). The pulse echo overlap method was employed to measure the ultrasonic velocity over the temperature range from 10 to $90^{\circ}C;$ the high-Q ultrasonic resonator method was used for the measurement of the absorption coefficient at $20^{\circ}C.$ The velocities exhibited their maximum values at ca. 55, 59, 63, 67, and $71^{\circ}C.$ for the 25, 20, 15, 10, and $5\%$ solutions, respectively. The velocity increased with respect to the poly(sodium 4-styrene-sulfonate) concentration at a given temperature. A study of the concentration dependence of the both the relaxation frequency and amplitude indicated that the relaxation at ca. 200 kHz is related to structural fluctuations of the polymer molecules, such as the segmental motions of the polymer chains and that the relaxation at ca. 1 MHz resulted from the proton transfer reactions of the oxygen sites of $SO_3.$ Both the absorption and the shear viscosity increase upon increasing the polymer concentration, but they decrease upon increasing the temperature.

A Study on the Post-Buckling Analysis of Spatial Structures Using Dynamic Relaxation Method (동적이완법을 이용한 후좌굴 해석법의 Hybrid 구조물의 적용성 평가)

  • Lee, Kyong-Soo;Lee, Sang-Ju;Han, Sang-Eul
    • Proceeding of KASS Symposium
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    • 2006.05a
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    • pp.58-65
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    • 2006
  • The present study is concerned with the application of dynamic relaxation method in the investigation of the large deflection behavior of spatial structures. The dynamic relaxation do not require the computation or formulation of any tangent stiffness matrix. The convergence to the solution is achieved by using only vectorial quantities and no stiffness matrix is required in its overall assembled form. In an effort to evaluate the merits of the methods, extensive numerical studies were carried out on a number of selected structural systems. The advantages of using dynamic relaxation methods, in tracing the post-buckling behavior of spatial structures, are demonstrated.

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