• Title/Summary/Keyword: stack-structure

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Structure and Heme-Independent Peroxidase Activity of a Fully-Coordinated Mononuclear Mn(II) Complex with a Schiff-Base Tripodal Ligand Containing Three Imidazole Groups

  • Sarkar, Shuranjan;Moon, Do-Hyun;Lah, Myoung-Soo;Lee, Hong-In
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3173-3179
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    • 2010
  • New complex $[Mn(II)H_{1.5}L]_2[Mn(II)H_3L]_2(ClO_4)_5{\cdot}3H_2O$ (1), where $H_3L$ is tris {2-(4-imidazolyl)methyliminoethyl} amine (imtren), has been prepared by reacting manganese(II) perchlorate hexahydrate with the imtren ligand in methanol. X-ray crystallographic study revealed that the imtren ligand hexadentately binds to Mn(II) ion through the three Schiff-base imine N atoms and three imidazole N atoms with a distorted octahedral geometry, and the apical tertiary amine N atom of the ligand pseudo-coordinates to Mn(II), forming overall a pseudo-seven coordination environment. The hydrogen-bonds between imidazole and imidazolate of $[Mn(II)H_{1.5}L]^{0.5+}$ complex ions are extended to build a 2D puckered network with trigonal voids. $[Mn(II)H_3L]^{2+}$ complex ions constitutes another extended 2D puckered layer without hydrogen bonds. Two layers are wedged each other to constitute overall stack of the crystal. Peroxidase activity of complex 1 was examined by observing the oxidation of 2,2'-azinobis(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS) with hydrogen peroxide in the presence of complex 1. Generation of $ABTS^{+{\cdot}}$ was observed by UV-vis and EPR spectroscopies, indicating that the complex 1, a fully-coordinated mononuclear Mn(II) complex with nitrogen-only ligand, has a heme-independent peroxidase activity.

Highly Flexible Touch Screen Panel Fabricated with Silver Nanowire Crossing Electrodes and Transparent Bridges

  • Jeon, Youngeun;Jin, Han Byul;Jung, Sungchul;Go, Heungseok;Lee, Innam;Lee, Choonhyop;Joo, Young Kuil;Park, Kibog
    • Journal of the Optical Society of Korea
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    • v.19 no.5
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    • pp.508-513
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    • 2015
  • A capacitive-type touch screen panel (TSP) composed of silver nanowire (AgNW) crossing electrodes and transparent bridge structures was fabricated on a polycarbonate film. The transparent bridge structure was formed with a stack of Al-doped ZnO (AZO) electrodes and SU-8 insulator. The stable and robust continuity of the bridge electrode over the bridge insulator was achieved by making the side-wall slope of the bridge insulator low and depositing the conformal AZO film with atomic layer deposition. With an extended exposure time of photolithography, the lower part of the SU-8 layer around the region uncovered by the photomask can be exposed enough to the UV light scattered from the substrate. This leads to the low side-wall slope of the bridge insulator. The fabricated TSP sample showed a large capacitance change of 22.71% between with and without touching. Our work supplies the technological clue for ensuring long-term reliability to the highly flexible and transparent TSP made by using conventional fabrication processes.

Electrical Conduction Mechanism in the Insulating TaNx Film (절연성 TaNx 박막의 전기전도 기구)

  • Ryu, Sungyeon;Choi, Byung Joon
    • Korean Journal of Materials Research
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    • v.27 no.1
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    • pp.32-38
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    • 2017
  • Insulating $TaN_x$ films were grown by plasma enhanced atomic layer deposition using butylimido tris dimethylamido tantalum and $N_2+H_2$ mixed gas as metalorganic source and reactance gas, respectively. Crossbar devices having a $Pt/TaN_x/Pt$ stack were fabricated and their electrical properties were examined. The crossbar devices exhibited temperature-dependent nonlinear I (current) - V (voltage) characteristics in the temperature range of 90-300 K. Various electrical conduction mechanisms were adopted to understand the governing electrical conduction mechanism in the device. Among them, the PooleFrenkel emission model, which uses a bulk-limited conduction mechanism, may successfully fit with the I - V characteristics of the devices with 5- and 18-nm-thick $TaN_x$ films. Values of ~0.4 eV of trap energy and ~20 of dielectric constant were extracted from the fitting. These results can be well explained by the amorphous micro-structure and point defects, such as oxygen substitution ($O_N$) and interstitial nitrogen ($N_i$) in the $TaN_x$ films, which were revealed by transmission electron microscopy and UV-Visible spectroscopy. The nonlinear conduction characteristics of $TaN_x$ film can make this film useful as a selector device for a crossbar array of a resistive switching random access memory or a synaptic device.

Study on Implement of Remote Medical System With LAN (유선 근거리망을 사용하는 원격의료 시스템에 관한 연구)

  • Lee, Jung-Taek;Lee, Kang-Min;Kim, Young-Kil
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.38 no.3
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    • pp.22-30
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    • 2001
  • This paper investigated future telemedicine as implementation of the telemonitoring system using LAN environment. For telemonitoring system rapidly implementation used the PC compatible embedded computing system in the ROMDOS and application program used the WATTCP that free TCP/IP Stack. Host computer program - programed by Visual C++ - had saved ECG signal and Patient Data coming inside Embedded PC and displayed. Embedded PC acquired ECG signal and transmitted a Packet to Host Computer. Host Computer remote access Embedded PC. This structure is the same Client/Sever Model. This system will be basic telemedicine model. There are problems of realtime telemonitoring because of network delay and data packet. Because of these problems, telemedicine systems will be required faster network speed and method of bio-signal transmission.

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Effect of Composite Sandwich Endplates on the Improvement of Cold Start Characteristics for PEMFC (복합재료 샌드위치 엔드플레이트의 연료전지 냉시동성 향상에 미치는 효과)

  • Suh, Jung-Do;Ko, Jae-Jun;Ahn, Byung-Ki;Yu, Ha-Na;Lee, Dai-Gil
    • Journal of Hydrogen and New Energy
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    • v.22 no.6
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    • pp.859-867
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    • 2011
  • The cold start problem is one of major obstacles to overcome for the commercialization of fuel cell vehicles. However, the cold start characteristics of fuel cell systems are very complicated since various phenomena, i.e. ice-blocking, electro-chemical reactions, heat transfer, and defrosting of BOP components, are involved in them. This paper presents a framework to approach the problem at a full stack scale using Axiomatic Design (AD). It was characterized in terms of Functional Requirements (FRs) and Design Parameters (DPs) while their relations were established in a design matrix. Considering the design matrix, the endplates should have low thermal conductivity and capacity without increase in weight or decrease in structural stiffness. Consequently, composite sandwich endplates were proposed and examined both through finite element analyses and experiments simulating cold start conditions. From the examinations, it was found that the composite sandwich endplates significantly contributed to improving the cold start characteristics of PEMFC.

Design and Operation Characteristics of 2.4MJ Pulse Power System for Electrothermal-Chemical(ETC) Propulsion(I) (전열화학추진용 2.4MJ 펄스파워전원의 설계와 동작특성(I))

  • Jin, Y.S.;Lee, H.S.;Kim, J.S.;Cho, J.H.;Lim, G.H.;Kim, J.S.;Chu, J.H.;Jung, J.W.;Hwang, D.W.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1868-1870
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    • 2000
  • As a drive for an ETC (Electro-thermal Chemical) launcher, a large pulse power system of a 2.4MJ energy storage was designed, constructed and tested. The overall power system consists of eight capacitive 300kJ energy storage banks. In this paper we describe the design features, setup and operation test result of the 300kJ pulsed power module. Each capacitor bank of the 300kJ module consists of six 22kV 50kJ capacitors. A triggered vacuum switch (TVS-43) was adopted as the main pulse switch. Crowbar diode circuits, variable multi-tap inductors and energy dumping systems are connected to each high power capacitor bank via bus-bars and coaxial cables. A parallel crowbar diode stack is fabricated in coaxial structure with two series 13.5kV, 60kA avalanche diodes. The main design parameters of the 300kJ module are a maximum current of 180kA and a pulse width of 0.5 - 3ms. The electrical performances of each component and current output variations into resistive loads have been investigated.

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Visualized Execution Analyzer for the Java Class File (자바 클래스 파일에 대한 시각화 실행 분석기)

  • Ko, Kwang-Man
    • The KIPS Transactions:PartA
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    • v.11A no.5
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    • pp.319-324
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    • 2004
  • The Java language is rapidly being adopted in the Internet. The distributed applications and their application range are being expanded beyond just a programing language and developed Into software applications. A variety of researches are going on with regard to the Java Virtual Machine runtime environment and methods of analyzing the Java class files and utilizing the information for applications. A class file is a converted file that is executable by the Java virtual machine. Analysis on the class file structure and the runtime processes will be convenient in arranging the decompilers and debugging the source programs. This paper is about the runtime process analyzer that presents the runtime processes, including class files, more visually. The content of a class file will be easily accessed and expressed as in a graphic user interface. The information in the class file displayed is divided into Constant_Pool, Class_file, Interface, Field, Method and Attribute with information on method area, operand stack and local variables expressed visually.

A Short Seismic Reflection Survey for Delineating the Basement and the Upper Units of the Gomso Bay, Yellow Sea (곰소만 지역의 기반암 및 상부 층서 파악을 위한 시험 탄성파반사법 탐사)

  • Kim Ji-Soo;Ryang Woo-Hun;Han Soo-Hyung;Kim Hak-Soo
    • The Journal of Engineering Geology
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    • v.16 no.2 s.48
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    • pp.161-169
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    • 2006
  • A short seismic reflection survey was performed to map the basement and the upper units in the Gomso Bay. This research was mainly aimed at clarifying the basement by improving the signal-to-noise ratio in data processing steps. The strategies employed in this research included enhancement of the signal interfered with large-amplitude noise, through pre- and post-stack processing such as time-variant filtering, bad trace edit, careful muting after f-k filter and NMO correction. The subsurface structure mapped from this survey mainly consists of the top of basement and the upper three units, which were well correlated to the result from the previously conducted MT survey. Furthermore seismic section clarifies approximately 30m deep subhorizontal event of the top of the basement, which was not shown in the central portion of the MT section due to data qualify.

Design of OpenStack Cloud Storage Systems - Applying Infiniband Storage Network and Storage Virtualization Performance Evaluation (인피니밴드 스토리지 네트워크를 적용한 오픈스택 클라우드 스토리지 시스템의 설계 및 스토리지 가상화 성능평가)

  • Heo, Hui-Seong;Lee, Kwang-Soo;Pirahandeh, Mehdi;Kim, Deok-Hwan
    • KIISE Transactions on Computing Practices
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    • v.21 no.7
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    • pp.470-475
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    • 2015
  • Openstack is an open source software that enables developers to build IaaS(Infrastructure as a Service) cloud platforms. Openstack can virtualize servers, networks and storages, and provide them to users. This paper proposes the structure of Openstack cloud storage system applying Infiniband to solve bottlenecking that may occur between server and storage nodes when the server performs an I/O operation. Furthermore, we implement all flash array based high-performance Cinder storage volumes which can be used at Nova virtual machines by applying distributed RAID-60 structures to three 8-bay SSD storages and show that Infiniband storage networks applied to Openstack is suitable for virtualizing high-performance storage.

Single-stage Power Factor Corrected AC-to-DC Converter for sustain/reset Driving Power Supply of PDP TV (PDP TV의 sustain/reset 구동전원 공급을 위한 1단방식의 역률보상형 AC-to-DC 컨버터)

  • Kang, Feel-Soon;Park, Jin-Hyun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.12 no.2
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    • pp.282-289
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    • 2008
  • To improve the efficiency of PDP TV, it should minimize the power losses transpired during AC-to-DC power conversion and PDP driving process. Generally the input power supply for PDP driving employes a two-stage power factor corrected converter, and it needs additional DC-to-DC converters to supply driving power for reset circuit ed sustain driver, which has high power consumption. However, such a circuit configuration has a difficulty for the PDP market requires low cost. To alleviate this problem, a new circuit composition is presented. It integrates input power supply with reset and sustain driver in a single power stack The input power supply of the proposed circuit has a single-stage structure to minimize power conversion loss, and it directly supplies power to the sustain driver so as to reduce the system size and cost.