• Analytical Science and Technology
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• v.6 no.5
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• pp.443-451
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• 1993

Pentaethylenehexaamine(penten) was reacted with a chloromethylated polystyrene resin on the purpose of the synthesis of polyamine chelating resin, $(P)_c$-penten. The stepwise dissociation constants of the synthesized polyamine chelating resin and the stability constants with metal ions were determined by Bjerrum's method. These stability constants were compared with those of the free penten. The adsorptivities and eluting tendencies of several metal ions on the chelating resin were studied.

• Bulletin of the Korean Chemical Society
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• v.29 no.2
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• pp.372-376
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• 2008

The hydrolysis of gallium(III) has been studied using potentiometric techniques under physiological conditions of temperature 37 C and ionic strength 0.15 moldm-3 NaCl and at different metal ion concentrations. Changes in pH were monitored with a glass electrode calibrated daily in hydrogen ions concentrations. The titration data within the pH range of 2.5-9.99 were analyzed to determine stability constants of hydroxide species using the SUPERQUAD program. Several different species were considered during the calculation procedure and the following hydroxides have been characterized: Ga(OH)3, Ga(OH)4- Ga3(OH)112-, Ga4(OH)11+ and Ga6(OH)153+. Speciation calculations based on the determined constants were then used to simulate the species distribution.

• Journal of the Korean Chemical Society
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• v.27 no.3
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• pp.208-212
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• 1983

The stability constants for the complexes formed between dibenzo-18-crown-6 compound and alkaline earth metal cations in dimethylsulfoxide, dimethylformamide, and acetonitrile have been obtained by conductometry at $25{\circ}C\;and\;35{\circ}C$respectively. The stability constants were increased in order of $Ca^{2+} in any solvent, and the magnitudes were found to be reversely proportional to the solvent donicities. The result could be understood in terms of ion-cavity radius concept, solvent basicity, and solvation of the cations.

• Korean Journal of Mathematics
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• v.27 no.1
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• pp.81-92
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• 2019

We introduce a reciprocal-negative Fermat's equation generalized with constants coefficients and investigate its stability in a quasi-${\beta}$-normed space.

• Archives of Pharmacal Research
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• v.15 no.2
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• pp.176-183
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• 1992

The stabilizing effects of $\alpha$-$\beta$-$\gamma$- and dimethyl-$\beta$-cyclodextrins $(\alpha$-, $\beta$-, $\gamma$- and DM-$\beta-$-CyDs) on the degradation of hydrocortisone 17-butyrate (HC-17B) in aqueous solution was investigated. Hc-17B underwent a facile hydroxide ion-catalyzed rearrangement to the less active 21-butyrate ester by the apparent first-order kinetics, and maximum stability of HC-17B was obtained at around pH 4.0. The stability of HC-17B was increased by inclusion complexation with $\alpha$-, $\gamma$- and DM-$\beta$-CyD in the pH range of 2.0-8.0 examined, whereas $\beta$-CyD accelerated the degradation of HC-17B at the pH higher than 5.0. The effects of ionic strength, solvent, temperature and CyD concentration were also investigated. Stability constants and apparent degradation rate constants of HC-17B-$\gamma$-CyD and HC-17B-DM-$\beta$-CyD complexes were determined kinetically on the basis of 1:1 complexation. The results suggested that the inclusion complexation with $\gamma$-CyD or DM-$\beta$-CyD was most useful means to enhance the stability of the steroid.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.04a
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• pp.181-185
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• 2001

This paper deals with the dynamic stability of a disc brake pad taking into account of its shear deformation and rotary inertia. A brake pad can be modeled as a beam like model subjected to distributed friction forces and having two translational springs. The study of this model is intended to provide a fundamental understanding of dynamic stability of drum brake pad. Governing equations of motion are derived from extended Hamilton's principle and their corresponding numerical solutions are obtained by applying the finite element formulation. The critical distributed friction force and the instability types are investigated bt changing two translational spring constants, rotary inertia parameter and shear deformation parameter. Also, the changes of eigen-frequencies of a beam determining instability types are investigated for various combinations of two translational spring constants.

• Journal of Pharmaceutical Investigation
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• v.18 no.4
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• pp.203-208
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• 1988

The stability and solubility of piroxicam in propylene glycol (PG), polyethylene glycol (PEC), and PG-water cosolvents have been studied by using high performance liquid chromatography. The degradation rate followed an apparent first-order kinetic and the reaction rate constants at 70, 80, and $90^{circ}C$ were determined. From these rate constants, the activation energy and the rate constant of piroxicam at $25^{circ}C$ in pure PG calculated by Arrhenius equation were 23.34 kcal/mole and $7.0\;{\times}\;10^{-4}\;day^{-1}$, respectively. Both of PG and PEG increased the solubility of the drug, but PEG was more effective.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.11
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• pp.890-896
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• 2002

This paper deals with the dynamic stability of a brake shoe under pulsating frictional forces. A lining part of brake systems is assumed as a distributed spring, and the supported elements of a shoe are assumed as translational springs for a constant distributed frictional force and a pulsating frictional force. Governing equations are derived by the use of the extended Hamilton's principle, and numerical results are calculated by finite element method. The critical distributed frictional force and instability regions were investigated for the change of distributed spring constants and translational spring constants.

• Geomechanics and Engineering
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• v.16 no.6
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• pp.655-667
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• 2018

To evaluate the stability of a rock slope with one pre-exiting vertical crack, this paper performs corresponding probabilistic stability analysis. The existence of cracks is generally ignored in traditional deterministic stability analysis. However, they are widely found in either cohesive soil or rock slopes. The influence of one pre-exiting vertical crack on a rock slope is considered in this study. The safety factor, which is usually adopted to quantity the stability of slopes, is derived through the deterministic computation based on the strength reduction technique. The generalized Hoek-Brown (HB) failure criterion is adopted to characterize the failure of rock masses. Considering high nonlinearity of the limit state function as using nonlinear HB criterion, the multivariate adaptive regression splines (MARS) is used to accurately approximate the implicit limit state function of a rock slope. Then the MARS is integrated with Monte Carlo simulation to implement reliability analysis, and the influences of distribution types, level of uncertainty, and constants on the probability density functions and failure probability are discussed. It is found that distribution types of random variables have little influence on reliability results. The reliability results are affected by a combination of the uncertainty level and the constants. Finally, a reliability-based design figure is provided to evaluate the safety factor of a slope required for a target failure probability.

• Bulletin of the Korean Chemical Society
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• v.22 no.6
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• pp.641-643
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• 2001