• 약학회지
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• 제38권3호
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• pp.223-229
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• 1994

From the methanolic extractive of the fruits of Quercus acutissima $C_{ARRUTHERS}$(Fagaceae) a mixture(QC-A saponin) of two ester glycosides, which were named as dotorioside I(3) and ll(4), was separated by silica gel column chromatography and HPLC. The structures of these two glycosides including their genuine aglycones(1,2) were elucidated as 1: $2{\alpha}$, $3{\beta}$, $19{\alpha}$, 23-tetrahydroxyolean-12-en-28-oic acid, 2: $2{\alpha}$, $3{\beta}$, $19{\alpha}$, 23-tetrahydroxyurs-12-en-28-oci acid, 3: 28-O-${\beta}$-D-glucopyranosyl ester of 1, 4: 28-O-${\beta}$-D-glucopyranosyl ester of 2, respectively, on the basis of chemical and spectral evidence.

• 생약학회지
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• 제51권3호
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• pp.158-162
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• 2020

Three coumarins, one chromone, and a phytosterol were isolated from the stem of Ostericum koreanum. Basis on the spectral data, we determined to be the structures of isolated compounds as bergapten, xanthotoxin, auraptenol, hamaudol, and mixture of phytosterols. Auraptenol was isolated for the first time from this plant.

• 통합자연과학논문집
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• 제2권3호
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• pp.207-210
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• 2009

Multiple rugate structures can be etched on a silicon wafer and placed in the same physical location, showing that many sharp spectral lines can be obtained in the optical reflectivity spectrum. Porous silicon samples were prepared by electrochemical etch of heavily doped p-type silicon wafers. The etching solution consisted of a 3:1 volume mixture of aqueous 48% hydrofluoric acid and absolute ethanol. Galvanostatic etch was carried out in a Teflon cell by using a two-electrode configuration with a Pt mesh counterelectrode. A sinusoidal current density waveform varying between 51.5 and $74.6mA/cm^2$ is applied. The anodization current was supplied by a Keithley 2420 high-precision constant current source which is controlled by a computer to allow the formation of PSi multilayer.

• Journal of Mechanical Science and Technology
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• 제15권6호
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• pp.752-763
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• 2001

Although there are many different solution schemes proposed for multidimensional radiative transfer, reference solutions to benchmark these methods are very rare in the literature. In this paper we produced some accurate solutions for purely absorbing gray and nongray gases including H$_2$O and CO$_2$by using the discrete transfer method with sufficiently accurate T(sub)95 quadrature set. The spectral transmittances of the mixtures of H$_2$O and CO$_2$are estimated by using the narrow band model. The gray gas solutions are obtained for different absorption coefficients, and the nongray real gas solutions are obtained for different mixture fractions of H$_2$O and CO$_2$. The numerical solutions presented in this paper are proved to be sufficiently accurate as compared to the available exact solutions and they may be used as reference solutions in evaluating various solution schemes.

• IEIE Transactions on Smart Processing and Computing
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• 제2권4호
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• pp.197-202
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• 2013

Large gains in speech intelligibility can be obtained using the SNR-based binary mask approach. This approach retains the time-frequency (T-F) units of the mixture signal, where the target signal is stronger than the interference noise (masker) (e.g., SNR > 0 dB), and removes the T-F units, where the interfering noise is dominant. This paper introduces two alternative binary masks based on the distortion constraints to improve the speech intelligibility. The distortion constraints are induced by a gain function for estimating the short-time spectral amplitude. One binary mask is designed to retain the speech underestimated (T-F) units while removing the speech overestimated (T-F)units. The other binary mask is designed to retain the noise overestimated (T-F) units while removing noise underestimated (T-F) units. Listening tests with oracle binary masks were conducted to assess the potential of the two binary masks in improving the intelligibility. The results suggested that the two binary masks based on distortion constraints can provide large gains in intelligibility when applied to noise-corrupted speech.

• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.3061-3065
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• 2009

A series of mono- and 1,1'-bis(heteroaryl)-substituted ferrocenes were prepared by employing Frielander reaction of acetyl- and 1,1'-diacetylferrocene with a series of o-aminoaldehydes. Reactions of 1,1'-diacetylferrocene with two equivalents of 1-aminonaphthalene-2-carbaldehyde and 8-aminoquinoline-7-carbaldehyde afforded a mixture of mono- and 1,1'-bis(heteroaryl)-substituted ferrocenes in a ratio of 1 : 3.1 - 3.8, while the reaction with 4-aminoacridine-3-carbaldehyde did not provide any characterizable product presumably due to the redox instability of the product induced by low reduction potential of benzo[b]-1,10-phenanthroline. Structural and optical properties of the compounds prepared were described.

• 약학회지
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• 제47권5호
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• pp.261-265
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• 2003

Near-infrared (NIR) system was used to determine rapidly and simply indomethacin in buffer solution for a dissolution test of tablets and capsules. Indomethacin standards were prepared ranging from 10 to 50 ppm using the mixture of phosphate buffer (pH 7.2) and water (1 : 4). The near-infrared (NIR) transmittance spectra of indomethacin standard solutions were collected by using a quartz cell in 1 mm and 2 mm pathlength. Partial least square regression (PLSR) was explored to develop calibration models over the spectral range 1100∼1700 nm. The model using 1 mm quartz cell was better than that using 2 mm quartz cell. The PLSR models developed gave standard error of prediction (SEP) of 0.858 ppm. In order to validate the developed calibration model, routine analysis was performed using another standard solutions. The NIR routine analysis showed good correlation with actual values. Standard error of prediction (SEP) is 1.414 ppm for 7 indomethacin samples in routine analysis and its error was permeable in the regulation of Korean Pharmacopoeia (VII). These results show the potential use of the real time monitoring for indomethacin during a dissolution test.

• 한국연소학회지
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• 제1권2호
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• pp.9-20
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• 1996

We construct a mobile broadband coherent anti-Stokes Raman spectroscopy system to measure the temperature of combustion gases. To improve the accuracy of CARS temperatures due to Stokes lasers, a modeless dye laser is constructed. A monochromator to disperse CARS spectra is also constructed in the spectrometer for easy portability. The accuracy of CARS temperature, measured in graphite tube furnace in reference to a radiation pyrometer, is better than 2 % from 1000 K to 2400 K. The CARS temperature error due to the variation of the spectral distribution of the modeless laser is measured to be less than 1.5 % during five hours operation. As a demonstration of combustion diagnosis, we applied the spectrometer to measure the temperature distribution of the propane air premixed flame.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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• pp.334-336
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• 2003

Satellite and airborne hyperspectral sensor images are suitable for investigating the vegetation state in agricultural land. However, image data obtained by an optical sensor inevitably includes mixels caused by high altitude observation. Therefore, mixel analysis method, which estimates both the pure spectra and the coverage of endmembers simultaneously, is required in order to distinguish the qualitative spectral changes due to the chlorophyll quantity or crop variety, from the quantitative coverage change. In this paper, we apply our agricultural independent component analysis (ICA) model to an airborne hyperspectral sensor image, which includes noise and fluctuation of coverage, and estimate pure spectra and the mixture ratio of crop and soil in agricultural land simultaneously.

• Bulletin of the Korean Chemical Society
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• 제10권1호
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• pp.15-19
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• 1989

Mass spectral fragmentations of some s-triazine herbicides have been investigated using tandem mass spectrometry. Major pathways driven by the side chains have been confirmed. However, most of the previously proposed pathways which were thought to be characteristic of the ring have been found unlikely. A class of ring cleavage reactions characteristic of s-triazine rings with alkylamino side chains has been found and the mechanism has been proposed. In addition, tandem mass spectrometry has been utilized to differentiate tautomeric structures and to analyze the fragmentation reactions occurring from the mixture of isobaric ions.