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http://dx.doi.org/10.5012/bkcs.2009.30.12.3061

Synthesis of Heteroarylferrocenes by FriedlanderReaction and Their Spectral Properties  

Lee, Woo-Jin (College of Pharmacy, Yeungnam University)
Chea, Jong-Myoung (College of Pharmacy, Yeungnam University)
Jahng, Yurng-Dong (College of Pharmacy, Yeungnam University)
Publication Information
Bulletin of the Korean Chemical Society / v.30, no.12, 2009 , pp. 3061-3065 More about this Journal
Abstract
A series of mono- and 1,1'-bis(heteroaryl)-substituted ferrocenes were prepared by employing Frielander reaction of acetyl- and 1,1'-diacetylferrocene with a series of o-aminoaldehydes. Reactions of 1,1'-diacetylferrocene with two equivalents of 1-aminonaphthalene-2-carbaldehyde and 8-aminoquinoline-7-carbaldehyde afforded a mixture of mono- and 1,1'-bis(heteroaryl)-substituted ferrocenes in a ratio of 1 : 3.1 - 3.8, while the reaction with 4-aminoacridine-3-carbaldehyde did not provide any characterizable product presumably due to the redox instability of the product induced by low reduction potential of benzo[b]-1,10-phenanthroline. Structural and optical properties of the compounds prepared were described.
Keywords
Ferrocene; Benzo[h]quinoline; 1,10-Phenanthroline; Benzo[b]-1,10-phenanthroline; Heteroarylferrocene;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By Web Of Science : 2  (Related Records In Web of Science)
Times Cited By SCOPUS : 3
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