• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.491-495
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• 2005

Vanadium pentoxide xerogels with a doping ratio of $Al/V_2O_5$ ranging from 0.01 to 0.05 were synthesized by doping Al into $V_2O_5$ xerogel via the sol-gel process. By using the synthesized $Al_xV_2O_5$, the $Li/Al_xV_2O_5$ cells were assembled to investigate the chemical and electrochemical properties. Surface morphology of the $Al_xV_2O_5$ xerogel showed an anisotropic corrugated sheet-like matrix, and the interlayer distance was about $11.5{\AA}$. The IR spectra of the $Al_xV_2O_5$ revealed that the doped Al was coordinated to the vanadyl group in $V_2O_5$. The $Al_xV_2O_5$ xerogels showed enhanced reversibility and energy density compared with the $V_2O_5$ xerogel. The specific capacity of the $Al_{0.05}V_2O_5$ xerogel was more than 200 mAh/g at 10 mA/g discharge rate, and cycle efficiency was about 90% after the 31st cycling test between 1.9 V and 3.9 V.

• Transactions of the Korean hydrogen and new energy society
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• v.9 no.4
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• pp.169-176
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• 1998

An experimental study on effect of vapor-cooled heat stations in a 5.5 liter cryogenic vessel has been performed. The cryogenic vessel is made of stainless steel of thickness of 1mm and insulated by the combined insulation of vacuum, MLI(multi-layer insulation) and vapor-cooled radiation shield. Vapor-cooled heat stations are also constructed based on the 1-dimensional thermal analysis to reduce the heat inleak through a filling tube. Thermal analysis indicates that the vapor-cooled heat stations can substantially enhance the performance of vessel for cryogenic fluids with high $C_p/h_{fg}$ where $C_p$ the specific heat and $h_{fg}$ the heat of vaporization, such as $LH_2$ and LHe. The experimental results for $LN_2$ shows that the total heat inleak into inner vessel consists of 14% radiation and 86% conduction through the filling tube. Therefore, it is expected that the conduction heat in leak of the vessel for high $C_p/h_{fg}$ cryogenic fluids can be significantly reduced. powders. The amount of copper coating was 20wt%. In order to examine corrosion behavior of the electrodes, the corrosion current and the current density, in 6M KOH aqueous solution after removal of oxygen in the solution, were measured by potentiodynamic and cyclic voltamo methods. The results showed that Co in the alloy increased corrosion resistance of the electrode whereas Ni decreased the stability of the electrode during the charge-discharge cycles. The electrode used Si sealant as a binder showed a lower corrosion current density than the electrode used PTFE and the electrode used Cu-coated alloy powders showed the best corrosion resistance.

• Journal of Korea Water Resources Association
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• v.41 no.12
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• pp.1187-1198
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• 2008

Many reservoirs in Korea and their downstream environments are under increased pressure for water utilization and ecosystem management from longer discharge of turbid flood runoff compared to a natural river system. Turbidity($C_T$) is an indirect measurement of water 'cloudiness' and has been widely used as an important indicator of water quality and environmental "health". However, $C_T$ modeling studies have been rare due to lack of experimental data that are necessary for model validation. The objective of this study is to validate a coupled three-dimensional(3D) hydrodynamic and particle dynamics model (ELCOM-CAEDYM) for the simulation of turbid density flows in stratified Daecheong Reservoir using extensive field data. Three different groups of suspended solids (SS) classified by the particle size were used as model state variables, and their site-specific SS-$C_T$ relationships were used for the conversion between field measurements ($C_T$) and state variables (SS). The simulation results were validated by comparing vertical profiles of temperature and turbidity measured at monitoring stations of Haenam(R3) and Dam(R4) in 2004. The model showed good performance in reproducing the reservoir thermal structure and propagation of stream density flow, and the magnitude and distribution of turbidity in the reservoir were consistent with the field data. The 3D model and turbidity modeling framework suggested in this study can be used as a supportive tool for the best management of turbidity flow in other reservoirs that have similar turbidity problems.

• Bulletin of the Korean Chemical Society
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• v.30 no.8
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• pp.1719-1723
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• 2009

The LiFeP$O_4$ powder was synthesized by using the solid state reaction method with Fe($C_2O_4){\cdot}2H_2O,\;(NH_4)_2HPO_4,\;Li_2CO_3$, and chitosan as a carbon precursor material for a cathode of a lithium-ion battery. The chitosan added LiFePO4 powder was calcined at 350 ${^{\circ}C}$ for 5 hours and then 800 ${^{\circ}C}$ for 12 hours for the calcination. Then we calcined again at 800 ${^{\circ}C}$ for 12 hours. We characterized the synthesized compounds via the crystallinity, the valence states of iron ions, and their shapes using TGA, XRD, SEM, TEM, and XPS. We found that the synthesized powders were carbon-coated using TEM images and the iron ion is substituted from 3+ to 2+ through XPS measurements. We observed voltage characteristics and initial charge-discharge characteristics according to the C rate in LiFeP$O_4$ batteries. The obtained initial specific capacity of the chitosan added LiFeP$O_4$ powder is 110 mAh/g, which is much larger than that of LiFeP$O_4$ only powder.

• Journal of Korea Water Resources Association
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• v.44 no.6
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• pp.497-510
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• 2011

A levee height is determined by adding a deterministic freeboard to a flood water level in Korea. In the USA, a levee height is determined by choosing a value conditionally among the freeboard criteria and the levels resulted from a probabilistic method. The probabilistic method adopts a conditional non-exceedance probability (CNP) which is the probability that the target stage will not be exceeded given a specific flood event. The purpose of the study is to compare Korean criterion for levee height estimation with that of the USA. Levee heights were determined according to the above two criteria at twenty-five cross sections in five streams. The results show that Korean criterion on average yields levee heights 20 cm higher than those calculated by the criterion of the USA. The larger the flood discharges become, the higher the levee height differences are usually. It is caused by the freeboard estimation criterion of Korea that the larger design flood is, the higher freeboard is given. Korean criterion, however, resulted in lower levee heights for smaller streams than those by the criterion of the USA. To sum it up, the Korean levee height criteria can result in overestimation or underestimation depending on flood discharge amount, being compared with the criteria of the USA. The Korean freeboard especially needs to be increased for smaller flood discharges.

• Journal of the Korean Electrochemical Society
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• v.16 no.3
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• pp.151-156
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• 2013

As the cathode material for li-ion battery, $LiNi_{0.5}Mn_{0.3}Co_{0.2}O_2$ were synthesized by supercritical hydrothermal method and calcined $850^{\circ}C$ and $900^{\circ}C$ for 10hrs in air. The effect of temperature in the heat treatment on the powder and its performance were studied of xray diffraction pattern, SEM-image, physical properties and electrochemical behaviors. As a result, calcined at $900^{\circ}C$ material particle size more increase than calcined at $850^{\circ}C$ material, especially shows excellent electrochemical performance with initial reversible specific capacity of 163.84 mAh/g (0.1C/2.0-4.3V), 186.87 mAh/g (0.1C/2.0-4.5V) and good capacity retention of 91.49% (0.2C/2.0-4.3V) and 90.36% (0.2C/2.0-4.5V) after 50th charge/discharge cycle.

• Journal of Environmental Policy
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• v.9 no.1
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• pp.83-107
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• 2010

Urbanized environments are constructed to estimate peak flow and cost savings in response to possible BMP allocation at a watershed scale. The main goal is to explore the proper allocation of sub-watershed level BMPs for peak flow attenuation at a watershed scale. Since several individual site scale BMPs work as a form of aggregated BMPs at a sub-watershed scale, it is a question as to how to properly allocate the sub-watershed level BMPs at a watershed scale. The Hydrological Simulation Program-FORTRAN (HSPF) is set up for a hypothetically urbanized watershed. A peak flow is determined to be the primary variable of interest and targeted to characterize the spatial distribution of aggregated BMPs. Construction cost of a regional pond forms the basis of the economic valuation. The results indicate that when total size of BMPs is constant in the entire watershed, (1) it is most effective to have aggregated BMPs in some upper sub-watersheds while the BMPs in either the mainstem sub-watershed or a single sub-watershed are the least effective choices for peak flow attenuation at a watershed scale; (2) savings exist between allocation differences and reduced peak flow increases cost savings. The largest saving is found in the strategy of aggregated BMPs in some upper sub-watersheds. These findings, however, call for follow-up site specific case studies revisiting the watershed scale impacts of BMP allocation. Then, it will be argued that location and extent of decentralization are considerable policy variables for an alternative stormwater management policy at a watershed scale.

• Journal of Korean Medicine Rehabilitation
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• v.28 no.4
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• pp.43-50
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• 2018

Objectives Upper lumbar disc herniation (LDH) (L1/2, L2/3) has specific anatomical characteristics and different outcome after conventional treatment compared to lower LDH (L3/4, L4/5, L5/S1). The purpose of this study was to compare the clinical features and effects of korean medical treatment of upper LDH between lower LDH. Methods We retrospectively reviewed the clinical data collected from 121 patients who was had admitted at the Haeundae Jaseng Hospital of Korean Medicine from June 1st, 2014 to August 31th, 2018. The patients who had treated at L1/2, L2/3 level LDH were grouped and compared with those treated at the L3/4, L4/5, L5/S1 level. We reviewed the patient characteristics such as age, the positive rate of Straight Leg Raise Test (SLR test), the presence or absence of previous lumbar surgery. Numeric Rating Scale (NRS) and Oswestry Disability Index (ODI) were evaluated at adimission and discharge. Results Mean age was significantly higher at upper LDH group and positive rate of SLR test was higher at lower LDH group. There was no significant difference of gender and previous lumbar surgery between two groups. Each group had a significant improvement of NRS, ODI scores. But between two groups, there was no significant difference of NRS, ODI scores. Conclusions Upper LDH group was older than lower LDH group. SLR test was useful tool to exclude upper LDH. Korean medical treatment was significantly effective to both upper and lower LDH groups. Further well designed prospective comparative studies are needed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.1
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• pp.369-377
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• 2013

This paper deals with the state of charge(SOC) and life cycle evaluation algorithm for lead-acid battery, which is essential factor of the electric vehicle(EV) and the stabilization of renewable energy in the smart grid. In order to perform the effective operation of the lead-acid battery, SOC and life cycle evaluation algorithm is required. Specific gravity with the change of electrolyte temperature inside battery case should be obtained to evaluate the SOC of lead-acid battery, however it is difficult to measure the electrolyte temperature of sealed type lead-acid battery. To overcome this problem, this paper proposes the equation of thermal transmission to compensate internal temperature of the lead-acid battery. Also, it is difficult to exactly evaluate the life cycle of battery, depending on the operation conditions of lead-acid battery such as charging and discharging state, self discharging rate and environmental issue. In order to solve the problem, this paper presents the concept for gravity accumulation of charge and discharge cycle, which is the value converted at $20^{\circ}C$. By using the proposed algorithm, this paper propose the test device based on the Labview software. The simulation results show that it is a practical tool for the maintenance of lead-acid battery in the field of industry.

• Korean Journal of Soil Science and Fertilizer
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• v.41 no.2
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• pp.112-117
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• 2008

A pot experiment was conducted to study the effect of application rate of anaerobically digested pig slurry on the growth of Chinese cabbage and the outflow characteristics of N and P from leaching and runoff in the upland. Anaerobically digested pig slurry(ADPS) was applied rates of 0, 6, 12, and $18L\;pot^{-1}$, and Chinese cabbages were grown for 50 days. Dry matter yield of Chinese cabbage increased significantly at the rates of 6 and $12L\;pot^{-1}$, but decreased at the rate of $18L\;pot^{-1}$ due probably to the high salinity. The EC(1:5) of the soil receiving $18L\;pot^{-1}$ of anaerobically digested pig slurry was $0.28dS\;m^{-1}$, which was significantly higher than those receiving 6 and $12L\;pot^{-1}$ of anaerobically digested pig slurry. For the leachate and runoff, N and P concentration increased with the application rate of ADPS. Therefore, considering the dual goal of optimum crop growth and minimal discharge of non-point pollution sources to water system, this study suggests that a testing of a site-specific proper application rate of liquid pig slurry including ADPS is prerequisite to achieving optimum agricultural productivity while minimizing water quality degradatio.