• Title/Summary/Keyword: solid oxide fuel cells

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Development of Ionomer Binder Solutions Using Polymer Grinding for Solid Alkaline Fuel Cells (고분자 분쇄 기술을 활용한 고체 알칼리연료전지용 이오노머 바인더 용액 개발)

  • Shin, Mun-Sik;Kim, Do-Hyeong;Kang, Moon-Sung;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.107-113
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    • 2016
  • In this study, an anion-exchange ionomer solution was prepared by grinding poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) in liquid nitrogen for solid alkaline fuel cells (SAFCs). Type of quaternized PPO (QPPO) solutions was controlled by grinding time. The ionomer binder solutions were characterized in terms of dispersity, particle size, and electrochemical properties. As a result, ionomer binder solutions using grinded polymer showed higher dispersion and smaller particle size distribution than that using non-grinded polymer. The highest ionic conductivity and IEC of the membrane recast by using BPPO-G120s were $0.025S\;cm^{-1}$ and $1.26meq\;g^{-1}$, respectively.

Numerical Study on Oxygen Depletion Characteristics of Porous Cathodes in Anode-Supported Solid Oxide Fuel Cells (음극지지 고체산화물 연료전지 다공성 양극에서의 산소고갈 특성에 관한 수치해석 연구)

  • Shin, Dongwoo;Nam, Jin Hyun;Kim, Charn-Jung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.257-268
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    • 2017
  • This paper proposes an efficient two-dimensional simulation model for solid oxide fuel cells (SOFCs) based on the electrochemical effectiveness model. The effectiveness model is known to accurately predict the current generation performance of SOFC electrodes, by considering the complex reaction/transport processes that occur within thin active functional layers near the electrolyte. After validation tests, the two-dimensional simulation model was used to calculate the distribution of current density and oxygen concentration transverse to the flow channel in anode-supported SOFCs, with which the oxygen depletion characteristics were investigated in detail. In addition, simulations were also conducted to determine the minimum number of grids required in the transverse direction to efficiently obtain accurate results.

Fabrication and Characterization of Composite LSCF-Ag Cathode for Solid Oxide Fuel Cells using Electron Beam Irradiation Process

  • Kang, Hyun Suk;Jung, Yung-Min;Song, Rak-Hyun;Peck, Dong-Hyun;Park, ChangMoon;Lee, Byung Cheol
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.2969-2973
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    • 2014
  • A new process to fabricate a composite LSCF-Ag cathode material for SOFCs by electron beam (e-beam) irradiation process has been suggested for operation under intermediate temperature range of $600-700^{\circ}C$. A composite LSCF-Ag cathode with uniformly coated Ag nanoparticles on the surface of the LSCF material was prepared by a facile e-beam irradiation method at room temperature. The morphology of the composite LSCF-Ag material was analyzed using a TEM, FE-SEM, and EDS. The prepared composite LSCF-Ag material can play a significant role in increasing the electro-catalytic activities and reducing the operating temperature of SOFCs. The performance of a tubular single cell prepared using the composite LSCF-Ag cathode, YSZ electrolyte and a Ni/YSZ anode was evaluated at reduced operating temperature of $600-700^{\circ}C$. The micro-structure and chemical composition of the single cell were investigated using a FE-SEM and EDS.

Fuel cell based CHP technologies for residential sector (연료전지와 마이크로 열병합 발전기술)

  • Son, Young Mok
    • Journal of Energy Engineering
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    • v.25 no.4
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    • pp.251-258
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    • 2016
  • This article reports current status of micro fuel cell-combined heat and power (${\mu}FC$-CHP) systems which utilize both power and heat generated by fuel cells. There are several options for constructing CHP systems and among them, fuel cells are the most useful and their total energy efficiency combining heat and power can reach up to about 90%. Fuel cells are classified as five types based on the electrolyte, but the most suitable fuel cell types for the ${\mu}FC$-CHP system are proton exchange membrane fuel cells (PEMFCs) and solid oxide fuel cells (SOFCs). ${\mu}FC$-CHP systems have several advantages such as decrease of the transmission-distribution loss, reduced costs of electricity due to distributed power generation, and environmental-friendliness owing to zero emission. The main drawback of the ${\mu}FC$-CHP systems is the high initial investment, however, it keeps decreasing as the technology development reduces production costs. Currently, Japan is the most leading country of the ${\mu}FC$-CHP market, however, Korea tries to expand the market by planning the deployment of 1 million units of ${\mu}FC$-CHP systems and governmental subsidiary supporting of half of the install price. In this report, integration technologies for connecting FC and CHP, and technology trends of leading countries are presented as well.

The Electrochemical Property of the Single-Chamber Solid Oxide Fuel Cell Based on a Zirconia Electrolyte (지르코니아 전해질을 이용한 단실형 고체산화물 연료전지의 전기화학 특성)

  • Park, Hee Jung;Joo, Jong Hoon;Yang, Jae-Kyo;Jin, Yun Ho;Lee, Kyu Hyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.510-515
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    • 2016
  • Single-chamber solid oxide fuel cells (SC-SOFCs) consist of only one gas chamber, in which both the anode and the cathode are exposed to the same fuel-oxidant mixture. Thus, this configuration shows good thermal and mechanical resistance and allows rapid start-up and -down. In this study, the unit cell consisting of $La_{0.8}Sr_{0.2}MnO_3$ (cathode) / $Zr_{0.84}Y_{0.16}O_{2-x}$ (electrolyte) / $Ni-Zr_{0.84}Y_{0.16}O_{2-x}$ (anode) was fabricated and its electrochemical property was investigated as a function of temperature and the volume ratio of fuel and oxidant for SC-SOFCs. Impedance spectra were also investigated in order to figure out the electrical characteristics of the cell. As a result, the cell performance was governed by the polarization resistances of the electrodes. The cell exhibited an acceptable cell-performance of $86mW/cm^2$ at $800^{\circ}C$ and stable performance for 3 hs under 0.7 V.

A Study of Deduction of evaluation Items for Design of SOFC stack safety performance evaluation system (SOFC 스택 안전성능 평가 시스템 제작을 위한 평가항목 도출에 관한 연구)

  • Park, Tae-Seong;Nam, Tae-Ho;Lee, Duk-Gwon;Lee, Seung-Kuk;Moon, Jong-Sam
    • Journal of the Korean Institute of Gas
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    • v.21 no.6
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    • pp.81-87
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    • 2017
  • SOFC(Solid Oxide Fuel Cell) is one of the high-temperature fuel cells, SOFC system and Stack has a high temperature operating Characteristics. These Characteristics cause a lot of trouble in the design of the system and selection materials, securing durability, and securing safety performance. Therefore, For Commercialization and Supply of SOFC, the development of safety performance assessment techniques and evaluation systems should go together. In this study, we analyzed the evaluation items of SOFC Safety performance standards and risk factors of the stack for design of stack safety performance evaluation system. Based on the analyzed data, the evaluation item was deducted for design of stack safety performance evaluation system. Through the results of this study, we expect to facilitate the supply of SOFC and contribute to a safe use environment.