• The Korean Journal of Rheology
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• v.2 no.1
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• pp.33-45
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• 1990

This study analyzes the planar 4:1 contraction flow of viscoelastic fluids with retardation time using finite volume method. To consider separately the elasticity effect of the viscoelastic fluid without shear thinn-ing effect, Oldroyd B liquid model is adopted for the numerical simulation. Instead of the stream function-vorticity formulation, SIMPLER algorithm with staggered grid system which incorporates primitive variable has been introduced in discretizing the momentum equations. An upwind corrected scheme has been used in discetizing the constitutive equations for the non-Newtonian part of the stress. The size of the corner vortex is shown to be slightly influenced by the Weissenberg number. However as the Weissenberg number is increased the chang-ing of the vortex shape agrees qualitatively well with some experimental studies.

• Korea-Australia Rheology Journal
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• v.11 no.4
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• pp.269-273
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• 1999

Immiscible polymer blends containing a liquid crystalline polymer dispersed phase can be described by existing blend theories when the dispersed-phase droplets are large relative to the orientation correlation length ("domain size") of the LCP. There does not appear to be an interfacial contribution to the linear viscoelastic properties of the blend from droplets smaller than the correlation length. Polyester blends, where interfacial interactions occur between the LCP and the matrix, exhibit a reduction in viscosity to below the viscosity of either component at low shear rates, where the droplet morphology is spherical. These anomalies cannot be explained in the context of existing theory.ng theory.

• Korea-Australia Rheology Journal
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• v.18 no.1
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• pp.9-14
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• 2006

We show that some network and pom-pom constitutive models are essentially the same. Instead of the usual confrontation, we suggest that the two approaches can offer useful mutual support: vital information about network destruction rates found from detailed pom-pom calculations can be used to improve the network models, while deductions about network creation rates can pinpoint areas needing further attention in the tube modelling area. A new form of the PTT model, the PTT-X model, results in improved shear and elongational flow descriptions, plus an improved recoil behaviour. The remaining problems of strain-time separation, second normal stress difference description, and reduction of parameters are also discussed and some suggestions for progress are offered.

• The Korean Journal of Rheology
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• v.7 no.2
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• pp.120-127
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• 1995

중량비가 측쇄의 함량이 각각 4.37%(시료I)와 8.97%(시료II)인 두종류의 사과 펙틴을 이용하여 측쇄가 펙틴용액의 점탄성에 미치는 역할에 대하여 연구하였다. 시료II가 시료 I보 다 동일한 농도에서 더높은 전단속도에서는 오히려 시료 I의 전단점도가 시료 II보다 높은 값을 보였다. 시료I과 시료 II의 η0는 농도에 대하여 각각 η0 C4.23의 관계를보여 시료II가 더높은 농도의존성을 보였다. 한편 용액의 탄성특성을 나타내는 저장탄성계수(G＇)와 zero-shear recoverable compliance(Jeo)의 경우에는 시료II가 시료I보다 높은 값을 보였는데 이는 측쇄가 탄성과 밀접한 관계가 있다는 것을 의미한다. 펙틴용액의 전단점도와 복소점도 를 비교했을 때 거의 비슷한 값을 보였으나 예외적으로 고측쇄의 시료 II의 경우 고농도에 서 서로 상이한 값을 보였다. 본연구의 결과는 진한 용액하에서 측쇄가 분자간의 상호엉킴 에 상당한 기여를 하고 있음을 나타내었다.

• Korea-Australia Rheology Journal
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• v.21 no.3
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• pp.185-191
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• 2009

Polystyrene/multi-walled carbon nanotube (PS/MWCNT) composites were prepared by the use of latex technology. The monodisperse PS latex was synthesized by an emulsifier-free emulsion polymerization from styrene/potassium persulfate/water system in the presence of ethanol. The MWCNTs were first treated with acid mixture to eliminate impurities, dispersed in deionized water driven by ultrasonicator, and then mixed with the PS latex. From these mixtures, PS/MWCNT composites were prepared by freeze-drying and subsequent compression molding. In the small-amplitude oscillatory shear experiments, both complex viscosity and storage modulus increased with increasing MWCNT content. A pronounced effect of MWCNT content was observed, resulting in larger storage modulus and stronger yield behavior at low frequencies when compared to unmodified PS. It showed a transition from viscous to elastic behavior with increasing MWCNT content. Over the MWCNT content of 3 wt%, the storage modulus was higher than the loss modulus across all frequencies.

• Korea-Australia Rheology Journal
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• v.20 no.4
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• pp.189-196
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• 2008

The pulsatile flow of blood through a stenosed artery under the influence of external periodic body acceleration is studied. The effect of non-Newtonian nature of blood in small blood vessels has been taken into account by modeling blood as a Casson fluid. The non-linear coupled equations governing the flow are solved using perturbation analysis assuming that the Womersley frequency parameter is small which is valid for physiological situations in small blood vessels. The effect of pulsatility, stenosis, body acceleration, yield stress of the fluid and pressure gradient on the yield plane locations, velocity distribution, flow rate, shear stress and frictional resistance are investigated. It is noticed that the effect of yield stress and stenosis is to reduce flow rate and increase flow resistance. The impact of body acceleration is to enhance the flow rate and reduces resistance to flow.

• Korea-Australia Rheology Journal
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• v.20 no.4
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• pp.245-251
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• 2008

Two polysiloxanes having different chemical structures were blended with polycarbonate (PC) under ultrasonic irradiation in solution. The polysiloxanes used were poly(methylphenyl siloxane) and vinyl-terminated poly(dimethyl siloxane). It was of primary interest to investigate the effect of polysiloxane structure on the rheological properties of PC/polysiloxane blends. It was found that a small amount (1.5 phr) of polysiloxanes greatly altered the melt viscosities and elasticity of PC. In particular, incorporation of poly(methylphenylsiloxane) led to a notable increase in elasticity with greater shear sensitivity of PC. The observed rheological behaviors of PC/polysiloxane blends were partly explained in conjunction with the tendencies found in ultrasonic degradation of polysiloxanes. Thermal stability and morphology in sonicated blends of PC/polysiloxane blends were also discussed.

• Korea-Australia Rheology Journal
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• v.17 no.2
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• pp.35-40
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• 2005

Nanofluid is a novel heat transfer fluid prepared by dispersing nanometer-sized solid particles in traditional heat transfer fluid to increase thermal conductivity and heat transfer performance. In this research we have considered the rheological properties of nanofluids made of CuO particles of 10-30nm in length and ethylene glycol in conjunction with the thermal conductivity enhancement. When examined using TEM, individual CuO particles have the shape of prolate spheroid of the aspect ratio of 3 and most of the particles are under aggregated states even after sonication for a prolonged period. From the rheological property it has been found that the volume fraction at the dilute limit is 0.002, which is much smaller than the value based on the shape and size of individual particles due to aggregation of particles. At the semi-dilute regime, the zero shear viscosity follows the Doi-Edwards theory on rodlike particles. The thermal conductivity measurement shows that substantial enhancement in thermal conductivity with respect to particle concentration is attainable only when particle concentration is below the dilute limit.

• The Korean Journal of Rheology
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• v.3 no.1
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• pp.22-29
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• 1991

In an effort to predict the long term durability of carbon fiber/epoxy composites in a space environ-ment interlaminar shear strength (ILSS) of the composites was measured as a function of 0.5 MeV electron radiation dosage. For the ILSS measurements a notch method (ASTM D3846) was used with and without side-supports. the supports were used to prevent peeling or bending during the test. The ILSS of both T300/ 5209 longitudinal composite system increases monotonically with radiation when the test is corried out without the support the ILSS of the composites increases initially but then decreases with further radiation. It is also observed that the ILSS of the unsupported case is much lower than that of the supported case. Measurement of epoxy modulus shows that the elastic modulus increases monotonically with radiation. But the breaking strength of the epoxy decreases with radiation. Electron Spectroscopy for Chemcal Analysis shows that the oxygen contents at both the pure epoxy surface and the composite fracture surface increase with radiation dose resulting in the increase of polarity at the interfacial region. This may be a supporting evidence for the increase in the ILSS of the composites.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.10a
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• pp.358-361
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• 2005

The rotational barrel type equipment has been designed for the new rheology fabrication process. During the continuous rotation of barrel with a constant temperature, the shear rate is controlled with the rotation speed and rotation time of barrel. The barrel surface can be controlled the temperature by the induction heating and cooling system. Many experiments were widely examined by using this system with controlling the rotation speed and the rotation time. The possibility for the rheoforming process was investigated with microstructural characteristics.