• 제목/요약/키워드: shape memory polymer

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Flexural analysis of thermally actuated fiber reinforced shape memory polymer composite

  • Tiwari, Nilesh;Shaikh, A.A.
    • Advances in materials Research
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    • 제8권4호
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    • pp.337-359
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    • 2019
  • Shape Memory Polymer Composites (SMPC) have gained popularity over the last few decades due to its flexible shape memory behaviour over wide range of strains and temperatures. In this paper, non-linear bending analysis has been carried out for SMPC beam under the application of uniformly distributed transverse load (UDL). Simplified C0 continuity Finite Element Method (FEM) based on Higher Order Shear Deformation Theory (HSDT) has been adopted for flexural analysis of SMPC. The numerical solutions are obtained by iterative Newton Raphson method. Material properties of SMPC with Shape Memory Polymer (SMP) as matrix and carbon fibre as reinforcements, have been calculated by theory of volume averaging. Effect of temperature on SMPC has been evaluated for numerous parameters for instance number of layers, aspect ratio, boundary conditions, volume fraction of carbon fiber and laminate stacking orientation. Moreover, deflection profile over unit length and behavior of stresses across thickness are also presented to elaborate the effect of glass transition temperature (Tg). Present study provides detailed explanation on effect of different parameters on the bending of SMPC beam for large strain over a broad span of temperature from 273-373K, which encompasses glass transition region of SMPC.

Mechanical Behavior of Shape Memory Fibers Spun from Nanoclay-Tethered Polyurethanes

  • Hong, Seok-Jin;Yu, Woong-Ryeol;Youk, Ji-Ho
    • Macromolecular Research
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    • 제16권7호
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    • pp.644-650
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    • 2008
  • This study examined the effect of nanoclays on the shape memory behavior of polyurethane (PU) in fibrous form. A cation was introduced into the PU molecules to disperse the organo-nanoclay (MMT) into poly($\varepsilon$-caprolactone) (PCL)-based PU (PCL-PU). The MMT/PCL-PU nanocomposites were then spun into fibers through melt-processing. The shape memory performance of the spun fibers was examined using a variety of thermo-mechanical tests including a new method to determine the transition temperature of shape memory polymers. The MMTs showed an improved the fixity strain rate of the MMT /PCL- PU fibers but a slight decrease in their recovery strain rate. This was explained by the limited movement of PU molecules due to the presence of nanoclays. The shape memory performance of the MMT/PCL-PU fibers was not enhanced significantly by the nanoclays. However, their recovery power was improved significantly up to a strain of approximately 50%.

Investigation of Fluorescent Shape Memory Polyurethanes Grafted with Various Dyes

  • Chung, Yong-Chan;Choi, Jae-Won;Lee, Seung-Hwan;Chun, Byoung-Chul
    • Bulletin of the Korean Chemical Society
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    • 제32권spc8호
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    • pp.2988-2996
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    • 2011
  • Shape memory polyurethane (SMPU), grafted with a fluorescent dye (Rhodamine, Mehylene violet, or Fluorescein) through an allophanate linking, was tested for the fluorescence and the shape recovery effect. The main chain of SMPU was composed of 4,4'-methylenebis(phenylisocyanate) (MDI), poly(tetramethyleneglycol) (PTMG), and 1,4-butanediol (BD), and a fluorescent dye was connected through a second MDI linked to the carbamate moiety of the main chain. Three series of SMPU, differing according to their dye content, were prepared to compare their shape recovery and fluorescence properties. In tensile mechanical property, maximum stress increased up to 350% compared to the linear SMPU, and strain remained above 2000%. Shape recovery went to as high as 97%, and remained almost same after repetitive shape recovery test cycles. Finally, the fluorescence emission of SMPU was demonstrated in the luminescence spectrum and fluorescent light emission pictures. In addition, the response of SMPU to external stimuli such as metal ions was investigated.

Synthetic bio-actuators and their applications in biomedicine

  • Neiman, Veronica J.;Varghese, Shyni
    • Smart Structures and Systems
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    • 제7권3호
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    • pp.185-198
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    • 2011
  • The promise of biomimetic smart structures that can function as sensors and actuators in biomedicine is enormous. Technological development in the field of stimuli-responsive shape memory polymers have opened up a new avenue of applications for polymer-based synthetic actuators. Such synthetic actuators mimic various attributes of living organisms including responsiveness to stimuli, shape memory, selectivity, motility, and organization. This article briefly reviews various stimuli-responsive shape memory polymers and their application as bioactuators. Although the technological advancements have prototyped the potential applications of these smart materials, their widespread commercialization depends on many factors such as sensitivity, versatility, moldability, robustness, and cost.

Compressive behavior of concrete confined with iron-based shape memory alloy strips

  • Saebyeok, Jeong;Kun-Ho E., Kim;Youngchan, Lee;Dahye, Yoo;Kinam, Hong;Donghyuk, Jung
    • Earthquakes and Structures
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    • 제23권5호
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    • pp.431-444
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    • 2022
  • The unique thermomechanical properties of shape memory alloys (SMAs) make it a versatile material for strengthening and repairing structures. In particular, several research studies have already demonstrated the effectiveness of using the heat activated shape memory effect of nickel-titanium (Ni-Ti) based SMAs to actively confine concrete members. Despite the proven effectiveness and wide commercial availability of Ni-Ti SMAs, however, their high cost remains a major obstacle for applications in real structural engineering projects. In this study, the shape memory effect of a new, much more economical iron-based SMA (Fe-SMA) is characterized and the compressive behavior of concrete confined with Fe-SMA strips is investigated. Tests showed the Fe-SMA strips used in this study are capable of developing high levels of recovery stress and can be easily formed into hoops to provide effective active and passive confining pressure to concrete members. Compared to concrete cylinders confined with conventional carbon fiber-reinforced polymer (CFRP) composites, Fe-SMA confinement yielded significantly higher compressive deformation capacity and residual strength. Overall, the compressive behavior of Fe-SMA confined concrete was comparable to that of Ni-Ti SMA confined concrete. This study clearly shows the potential for Fe-SMA as a robust and cost-effective strengthening solution for concrete structures and opens possibilities for more practical applications.