• Bulletin of the Korean Chemical Society
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• v.26 no.12
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• pp.1996-2000
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• 2005

Headspace hanging drop liquid phase micro-extraction (HS-HD-LPME) is studied as a novel solvent-based sample pretreatment method for floral volatile aroma compounds. This paper reports on application of the HSHD- LPME combined with GC-MS for the analysis of linalool component emitted from evening primrose flowers. The effect of several variables on the method performance was investigated. Additionally, the separation of enantiomers on a cyclodextrin capillary column was performed to identify chirality of (−)-linalool component. Since the unsurpassed volume of a few micro-liters of solvent is used, there is minimal waste or exposure to toxic organic solvents. This method enables to combine extraction, enrichment, clean-up, and sample introduction into a single step prior to the chromatographic process.

• Bulletin of the Korean Chemical Society
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• v.27 no.10
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• pp.1604-1608
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• 2006

A simple and efficient cloud point extraction-spectrofluorimetric method for the determination of thiamine in human urine is proposed. The procedure is based on the oxidation of thiamine with ferricyanide to form thiochrome, its extraction to Triton X-114 micelles and spectrofluorimetric determination. The variables affecting oxidation of thiamine, extraction and phase separation were studied and optimized. Under the experimental conditions used, the calibration graphs were linear over the range 2.5-1000 ng $mL^{-1}$. The limit of detection was 0.78 ng $mL^{-1}$ of thiamine and the relative standard deviation for 5 replicate determinations of thiamine at 400 ng $mL^{-1}$ concentration level was 2.42%. Average recoveries between 93-107% were obtained for spiked samples. The proposed method was applied to the determination of thiamine in human urine.

• Journal of applied mathematics & informatics
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• v.13 no.1_2
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• pp.53-65
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• 2003

Here we present a study of small-amplitude, shallow water waves on sloping beds. The beds considered in this analysis are linear and quadratic in nature. First we start with stating the relevant governing equations and boundary conditions for the theory of water waves. Once the complete prescription of the water-wave problem is available based on some assumptions (like inviscid, irrotational flow), we normalize it by introducing a suitable set of non-dimensional variables and then we scale the variables with respect to the amplitude parameter. This helps us to characterize the various types of approximation. In the process, a summary of equations that represent different approximations of the water-wave problem is stated. All the relevant equations are presented in rectangular Cartesian coordinates. Then we derive the equations and boundary conditions for small-amplitude and shallow water waves. Two specific types of bed are considered for our calculations. One is a bed with constant slope and the other bed has a quadratic form of surface. These are solved by using separation of variables method.

• Journal of the Korean Regional Science Association
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• v.8 no.1
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• pp.31-50
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• 1992

The aim of this paper is to define major factors influencing land development of each of major uses (residential, commercial, industrial) in the process of rapid urban expansion. The main hypothesis of this study is that land use changing patterns are directed by supply side of land managed to public policies rather than demand side. The graphic analysis is applied to relationships between urban growth and land development process of each use and between land development project managed to public policies and land development process. Public and land development projects and zonning protection seem to be major roles of land supply and main determinants of urban spatial structure. Location factors for land development of each uses are selected in 23 variables. Factor analysis is applied to test correlation between variables in 1971 and 1981. Factor structure between two years is similar, but progressive processing of functional separation is derived such as intensive land use is grouped, different location between residential and industrial use is deep. Dependent variables are standardized to logarithm of land development of each use per unit vacant land in two periods, between 1971 and 1980 year and between 1981 year. Correlation analysis between 6 dependent variables and 23 location factors in each years are applied. Major factors of each use are selected in criteria such as high correlation with dependent variables, low correlation between independent variables and common application in two periods. As the result, major factors for residential land development are Land Readjustment Project (LRP), percent of total zoned area in residential zone, residential floor space density per available area, percent of total area in industrial use; for commercial development is distance to CBD, percent of total area in commercial use, residential floor space density per available area in each year, and volumn rate of industrial use; for industrial use is percent of total area of industrial use is percent of total area of industrial use, Industrial Estate Project (IES), LRP, and distance from CBD. Land development pattern of each use between two periods are slightly different. So 6 equation is derived from appling backward method of regession. Adjusted multiple R squares of all is more than 0.5 and those equation is statistically significant and valuable to assist urban land use forecasting.

• Transactions of Materials Processing
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• v.24 no.1
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• pp.37-43
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• 2015

The purpose of the current study is to improve the clinching joint strength of aluminum and fiber metal laminates (FMLs) comprised of three layers. The joining of FML and Al 5052 by a conventional clinching joint has some disadvantages such as necking of the upper sheet, lack of interlocking, defects caused by the vertical load, and especially loss of strength of the composite material due to the low ductility. In the current study, a tapered-hole clinching method is proposed as an alternative for the joining of Al 5052 and FMLs. A hole with a tapered shape is formed before the joining process. The design parameters were evaluated using the Taguchi method for the geometry of the tapered hole in order to determine the maximum separation load. The diameter of the punch corner, clearance, punch stroke and the tapered length were used as the main variables in the Taguchi method. In conclusion, the contribution ratio for each of the fours variable examined was 35.07%, 22.44%, 21.32% and 14.11%, respectively. In addition, the appropriate combination of the design parameters can make a 5% improvement in the vertical direction joint strength.

• Steel and Composite Structures
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• v.39 no.5
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• pp.543-564
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• 2021

In this study free vibration analysis of a cracked Goland composite wing is investigated. The wing is modelled as a cantilevered beam based on Euler- Bernoulli equations. Also, composite material is modelled based on lamina fiber-reinforced. Edge crack is modelled by additional boundary conditions and local flexibility matrix in crack location, Castigliano's theorem and energy release rate formulation. Governing differential equations are extracted by Hamilton's principle. Using the separation of variables method, general solution in the normalized form for bending and torsion deflection is achieved then expressions for the cross-sectional rotation, the bending moment, the shear force and the torsional moment for the cantilevered beam are obtained. The cracked beam is modelled by separation of beam into two interconnected intact beams. Free vibration analysis of the beam is performed by applying boundary conditions at the fixed end, the free end, continuity conditions in the crack location of the beam and dynamic stiffness matrix determinant. Also, the effects of various parameters such as length and location of crack and fiber angle on natural frequencies and mode shapes are studied. Modal analysis results illustrate that natural frequencies and mode shapes are affected by depth and location of edge crack and coupling parameter.

• Journal of the Korean Society of Food Culture
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• v.12 no.3
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• pp.265-274
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• 1997

This study was conducted in ordor to find the most suitable conditions for producing the Doenjang with optimal odor compound contents. Three sample groups with the different preparing methods -Doenjang that has not gone through the soy sauce separation process (Doenjang A), Doenjang that has gone through the soy sauce separation process; Meju-20% salt water ratio of 1 : 4 (Doenjang B), and that with the ratio of 1.3 : 4 (Doenjang C)- were tested during different ripening periods. Odor compound contents were analyzed through Solvent Extraction Method and Simultaneous Steam Distillation Extraction (SDE). The number of odor compounds was greatest in Doenjang A and during the mid to late stage in each groups. In the sensory evaluation of Doenjang odors, Doenjang A received the highest scores in the categories of overall preferences, while Doenjang C got the lowest scores. Individual odor didn't vary significantly during ripening periods, but the overall odor and taste preference was highest in the samples ripened for 75 to 120 days. Stepwise multiple regression analysis of major odor compounds of Doenjang revealed that benzeneacetaldehyde is the major explanatory variable for offensive odor. Benzeneethanol, 3-methylthio-propanal and 4-methyl-phenol are the explanatory variables for salty odor, nutty odor and rancid odor, respectively. Odor compounds that contribute to the overall odor preference varied from the compounds that affect the taste preference.

• Advances in aircraft and spacecraft science
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• v.3 no.4
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• pp.379-397
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• 2016

In this manuscript, free vibrations of a unidirectional composite orthotropic Timoshenko beam based on finite strain have been studied. Using Green-Lagrange strain tensor and comprising all of the nonlinear terms of the tensor and also applying Hamilton's principle, equations of motion and boundary conditions of the beam are obtained. Using separation method in single-harmonic state, time and locative variables are separated from each other and finally, the equations of motion and boundary conditions are gained according to locative variable. To solve the equations, generalized differential quadrature method (GDQM) is applied and then, deflection and cross-section rotation of the beam in linear and nonlinear states are drawn and compared with each other. Also, frequencies of carbon/epoxy and glass/epoxy composite beams for different boundary conditions on the basis of the finite strain are calculated. The calculated frequencies of the nonlinear free vibration of the beam utilizing finite strain assumption for various geometries have been compared to von Karman one.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.12
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• pp.3991-4002
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• 1996

Thermally fully developed and thermally developing laminar flows of a Bingham plastic in a circular pipe have been studied analytically. For thermally fully developed flow, the Nusselt numbers and temperature profiles are presented in terms of the yield stress and Peclet number, proposing a correlation formula between the Nusselt number and the Peclet number. The solution to the Graetz problem has been obtained by using the method of separation of variables, where the resulting eigenvalue problem is solved approximately by using the method of weighted residuals. The effects of the yield stress, Peclet and Brinkman numbers on the Nusselt number are discussed.

• 한국전산유체공학회:학술대회논문집
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• 1998.05a
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• pp.43-48
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• 1998

The development of unsteady three-dimensional incompressible viscous solver based on unsteady physical curvilinear coordinate system is presented. A 12-point finite analytic scheme based on local uniform grid spacing is extended for nonuniform grid spacing. The formulation of a condition is suggested to avoid the oscillation of the series summations produced by the application of the method of separation of variables. SIMPLER and pressure Poisson equation techniques are used for solving a velocity-pressure coupled problem. The matrix is solved using the Generalized Minimal RESidual (GMRES) method to enhance the convergence rate of unsteady flow solver and the Kinematic boundary condition of a free surface flow. It is demonstrated that the numerical solutions of these equations are less mesh sensitive.