Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

A Cloud Point Extraction-Spectrofluorimetric Method for Determination of Thiamine in Urine

  • Tabrizi, Ahad Bavili (Department of Medicinal Chemistry, Faculty of Pharmacy, Tabriz University of Medical Sciences)
  • Published : 2006.10.20
Download PDF
⟨ Previous Next ⟩

Abstract

A simple and efficient cloud point extraction-spectrofluorimetric method for the determination of thiamine in human urine is proposed. The procedure is based on the oxidation of thiamine with ferricyanide to form thiochrome, its extraction to Triton X-114 micelles and spectrofluorimetric determination. The variables affecting oxidation of thiamine, extraction and phase separation were studied and optimized. Under the experimental conditions used, the calibration graphs were linear over the range 2.5-1000 ng $mL^{-1}$. The limit of detection was 0.78 ng $mL^{-1}$ of thiamine and the relative standard deviation for 5 replicate determinations of thiamine at 400 ng $mL^{-1}$ concentration level was 2.42%. Average recoveries between 93-107% were obtained for spiked samples. The proposed method was applied to the determination of thiamine in human urine.

Keywords

References

  1. Du, J.; Li, Y.; Lu, J. Talanta 2002, 57, 661 https://doi.org/10.1016/S0039-9140(02)00079-6
  2. Vinas, P.; López-Erroz, C.; Balsalobre, N.; Hernandez-Cordoba, M. J. Chromatogr. B 2001, 757, 301 https://doi.org/10.1016/S0378-4347(01)00163-3
  3. Batifoulier, F.; Verny, M.-A.; Besson, C.; Demigné, C.; Remesy, C. J. Chromatogr. B 2005, 816, 67 https://doi.org/10.1016/j.jchromb.2004.11.004
  4. Losa, R.; Sierra, M. I.; Fernandez, A.; Blanco, D.; Buesa, J. M. J. Pharm. Biomed. Anal. 2005, 37, 1025 https://doi.org/10.1016/j.jpba.2004.08.038
  5. Bohrer, D.; Cícero do Nascimento, P.; Ramirez, A. G.; Karlo, J.; Mendonça, A.; de Carvalho, L. M.; Cristina, G.; Pomblum, S. Microchem. J. 2004, 78, 71 https://doi.org/10.1016/j.microc.2004.03.013
  6. Lynch, P. L. M.; Trimble, E. R.; Young, I. S. J. Chromatogr. B 1997, 701, 120 https://doi.org/10.1016/S0378-4347(97)00353-8
  7. Vinas, P.; Lopez-Erroz, C.; Balsalobre, N.; Hernandez-Cordoba, M. J. Chromatogr. A 2003, 1007, 77 https://doi.org/10.1016/S0021-9673(03)00977-4
  8. Mrestani, Y.; Neubert, R. H. H. J. Chromatogr. A 2000, 871, 351 https://doi.org/10.1016/S0021-9673(99)01017-1
  9. Pérez-Ruiz, T.; Martínez-Lozano, C.; Sanz, A.; Guillén, A. J. Pharm. Biomed. Anal. 2004, 34, 551 https://doi.org/10.1016/S0731-7085(03)00606-X
  10. Vinas, P.; Lopez-Erroz, C.; Cerdan, F. J.; Campillo, N.; Hernandez- Cordoba, M. Mikrochim. Acta 2000, 134, 83 https://doi.org/10.1007/s006040070058
  11. Rocha, F. R. P.; Fatibello Filho, O.; Reis, B. F. Talanta 2003, 59, 191 https://doi.org/10.1016/S0039-9140(02)00477-0
  12. Song, Z.; Hou, S. J. Pharm. Biomed. Anal. 2002, 28, 683 https://doi.org/10.1016/S0731-7085(01)00655-0
  13. Ortega Barrales, P.; Dominguez Vidal, A.; Fernandez de Cordova, M. L.; Molina Díaz, A. J. Pharm. Biomed. Anal. 2001, 25, 619 https://doi.org/10.1016/S0731-7085(00)00590-2
  14. Aboul-Kasim, E. J. Pharm. Biomed. Anal. 2000, 22, 1047 https://doi.org/10.1016/S0731-7085(99)00154-5
  15. Oliveira Costa-Neto, C.; Vicente Pereira, A.; Aniceto, C.; Fatibello-Filho, O. Talanta 1999, 48, 659 https://doi.org/10.1016/S0039-9140(98)00293-8
  16. Lynch, P. L. M.; Young, I. S. J. Chromatogr. A 2000, 881, 267 https://doi.org/10.1016/S0021-9673(00)00089-3
  17. Burguera, J. L.; Burguera, M. Talanta 2004, 64, 1099 https://doi.org/10.1016/j.talanta.2004.02.046
  18. Paleologos, E. K.; Giokas, D. L.; Karayannis, M. I. Trends Anal. Chem. 2005, 24, 426 https://doi.org/10.1016/j.trac.2005.01.013
  19. Sosa Ferrera, Z.; Padron Sanz, C.; Mahugo Santana, C.; Santana Rodríguez, J. J. Trends Anal. Chem. in press
  20. Shen, J.; Shao, X. Anal. Chim. Acta 2006, 561, 83 https://doi.org/10.1016/j.aca.2006.01.002
  21. Giokas, D. L.; Sakkas, V. A.; Albanis, T. A.; Lampropoulou, D. A. J. Chromatogr. A 2005, 1077, 19 https://doi.org/10.1016/j.chroma.2005.04.074
  22. Shi, Z.; He, J.; Chang, W. Talanta 2004, 64, 401 https://doi.org/10.1016/j.talanta.2004.03.001
  23. Delgado, B.; Pino, V.; Ayala, J. H.; González, V.; Afonso, A. M. Anal. Chim. Acta 2004, 518, 165 https://doi.org/10.1016/j.aca.2004.05.005
  24. Shemirani, F.; Baghdadi, M.; Ramezani, M.; Reza Jamali, M. Anal. Chim. Acta 2005, 534, 163 https://doi.org/10.1016/j.aca.2004.06.036
  25. Bavili Tabrizi, A. Food Chem. 2007, 100, 1698 https://doi.org/10.1016/j.foodchem.2005.10.015
  26. Manzoori, J. L.; Bavili-Tabrizi, A. Michrochim. Acta 2003, 141, 201 https://doi.org/10.1007/s00604-002-0945-1
  27. Rukhadze, M. D.; Tsagareli, S. K.; Sidamonidze, N. S.; Meyer, V. R. Anal. Biochem. 2000, 287, 279 https://doi.org/10.1006/abio.2000.4863
  28. Ohashi, A.; Ogiwara, M.; Ikeda, R.; Okada, H.; Ohashi, K. Anal. Sci. 2004, 20, 1353 https://doi.org/10.2116/analsci.20.1353
  29. Perez-Ruiz, T.; Martinez-Lozano, C.; Tomas, V.; Ibarra, I. Talanta 1992, 39, 907 https://doi.org/10.1016/0039-9140(92)80270-N
  30. Lopez-Flores, J.; Fernandez-De Cordova, M. L.; Molina-Diaz, A. Anal. Chim. Acta 2005, 535, 161 https://doi.org/10.1016/j.aca.2004.12.023

Cited by

  1. Applying cloud point extraction technique for the extraction of oxazepam from human urine as a colour or fluorescent derivative prior to spectroscopic analysis methods vol.4, pp.2, 2012, https://doi.org/10.1002/dta.259
  2. Serial Evaluation of Children With ALF With Advanced MRI, Serum Proinflammatory Cytokines, Thiamine, and Cognition Assessment vol.55, pp.5, 2012, https://doi.org/10.1097/MPG.0b013e31825f4c3e
  3. Drug screening in human plasma by cloud-point extraction and HPLC vol.11, pp.1, 2013, https://doi.org/10.2478/s11532-012-0134-y
  4. Application of micelle-mediated extraction in preparation of body fluids for HPLC-DAD screening of acidic and neutral drugs vol.25, pp.1, 2013, https://doi.org/10.1556/AChrom.25.2013.1.5
  5. Sensitive and highly selective determination of vitamin B1 in the presence of other vitamin B complexes using functionalized gold nanoparticles as fluorophore vol.5, pp.62, 2015, https://doi.org/10.1039/C5RA09165A
  6. Simultaneous Determination of Vitamins B1 and B2 in Food Samples by Modified Cloud Point Extraction Method and HPLC-DAD vol.11, pp.1, 2018, https://doi.org/10.1007/s12161-017-0996-x
  7. Stability-Indicating Photochemical Method for the Assay of Thiamine by Spectrophotometry vol.2018, pp.2314-4939, 2018, https://doi.org/10.1155/2018/3178518
  8. using horseradish peroxidase as catalyst in the presence of hydrogen peroxide vol.24, pp.2, 2009, https://doi.org/10.1002/bio.1067
  9. Determination of Mefenamic Acid in Human Urine by Means of Two Spectroscopic Methods by Using Cloud Point Extraction Methodology as a Tool for Treatment of Samples vol.27, pp.11, 2006, https://doi.org/10.5012/bkcs.2006.27.11.1780
  10. Microwave-assisted and cloud-point extraction in determination of drugs and other bioactive compounds vol.28, pp.4, 2006, https://doi.org/10.1016/j.trac.2009.02.002
  11. Thiamine deficiency related microstructural brain changes in acute and acute-on-chronic liver failure of non-alcoholic etiology vol.31, pp.3, 2012, https://doi.org/10.1016/j.clnu.2011.11.018
  12. Coacervative extraction as a green technique for sample preparation for the analysis of organic compounds vol.1339, pp.None, 2006, https://doi.org/10.1016/j.chroma.2014.02.082