• Title/Summary/Keyword: sensitively analysis

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Liquid Chromatographic Determination of Etofenprox Residues in Foods with Mass-Spectrometric Confirmation

  • Lee, Young-Deuk;Kwon, Chan-Hyeok;Kwon, Ki-Sung
    • Korean Journal of Environmental Agriculture
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    • v.30 no.4
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    • pp.432-439
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    • 2011
  • BACKGROUND: An official analytical method was developed to determine etofenprox residues in agricultural commodities using high-performance liquid chromatography (HPLC). METHODS AND RESULTS: The etofenprox residue was extracted with acetone from representative samples of five raw products which comprised rice grain, apple, mandarin, cabbage, and soybean. The extract was then serially purified by liquid-liquid partition and Florisil column chromatography. For rice and soybean samples, acetonitrile/n-hexane partition was additionally coupled to remove nonpolar lipids. Reversed phase HPLC using an octadecylsilyl column was successfully applied to separate etofenprox from co-extractives. Intact etofenprox was sensitively detected by ultraviolet absorption at 225 nm. Recovery experiment at the quantitation limit validated that the proposed method could apparently determine the etofenprox residue at 0.02 mg/kg. Mean recoveries from five crop samples fortified at three levels in triplicate were in the range of 93.6~106.4%. Relative standard deviations of the analytical method were all less than 10%, irrespective of crop types. A selected-ion monitoring LC/mass spectrometry with positive atmospheric-pressure chemical ionization was also provided to confirm the suspected residue. CONCLUSION(s): The proposed method is simple, rapid and sensitive enough to be employed in routine inspection or monitoring of agricultural products for the etofenprox residue.

A Study on the Life Characteristics of Lightweight Bearings (경량 베어링 수명 특성에 관한 연구)

  • Lee, Choong-Sung;Park, Jong-Won;Lim, Sin-Yeol;Kang, Bo-Sik
    • Journal of the Korean Society of Industry Convergence
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    • v.24 no.6_2
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    • pp.819-825
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    • 2021
  • In the industry, the use of lightweight bearings is increasing to minimize motor power loss, and in particular, the application of next-generation systems such as robots and drones is increasing. Bearing manufacturers are producing lightweight bearings by changing the bearing material, but related researches is insufficient. In this paper, life test and structural analysis were performed for lightweight bearings, and shape parameters and scale parameters were derived based on the life test results. It was confirmed that the shape parameter was 2.52 and the scale parameter was 164 hours. As a result of calculating the dynamic load rating based on the B10 life, it was confirmed that the dynamic load rating of the lightweight bearing was 7% compared to the formula suggested by ISO 281. The reason is that the material of the retainer, which is a major failure part, is a polyamide 66 series that reacts sensitively to heat, so It is judged to show a lot of difference from the ISO 281 calculation formula.

Development of Colorimetric Paper Sensor for Pesticide Detection Using Competitive-inhibiting Reaction

  • Kim, Hyeok Jung;Kim, Yeji;Park, Su Jung;Kwon, Chanho;Noh, Hyeran
    • BioChip Journal
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    • v.12 no.4
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    • pp.326-331
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    • 2018
  • Contamination by pesticides is an everincreasing problem associated with fields of environmental management and healthcare. Accordingly, appropriate treatments are in demand. Pesticide detection methods have been researched extensively, aimed at making the detection convenient, fast, cost-effective, and easy to use. Among the various detecting strategies, paper-based assay is potent for real-time pesticide sensing due to its unique advantages including disposability, light weight, and low cost. In this study, a paper-based sensor for chlorpyrifos, an organophosphate pesticide, has been developed by layering three sheets of patterned plates. In colorimetric quantification of pesticides, the blue color produced by the interaction between acetylcholinesterase and indoxyl acetate is inhibited by the pesticide molecules present in the sample solutions. With the optimized paper-based sensor, the pesticide is sensitively detected (limit of detection =8.60 ppm) within 5min. Furthermore, the shelf life of the device is enhanced to 14 days after from the fabrication, by treating trehalose solution onto the deposited reagents. We expect the paper-based device to be utilized as a first-screening analytic device for water quality monitoring and food analysis.

Escape Behavior of Medaka (Oryzias latipes) in Response to Aerial Predators of Different Sizes and with Different Attack Speeds

  • Lee, Sang-Hee
    • Proceedings of the National Institute of Ecology of the Republic of Korea
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    • v.3 no.1
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    • pp.47-53
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    • 2022
  • The escape behavior of prey fish to predator attack is directly linked to the survival of the fish. In this study, I explored the escape behavior of Medaka fish to bird attacks. To simulate the attack, I designed a model triangular-shaped bird to slide along a fishing line connected between rods at both ends of the tank. The triangular shape was set to 10×15 (S=1), 15×20 (S=2), and 20×25 cm (S=3) with base×height. The slope (θ) of the fishing line, which determines the attack speed of the model bird, was set to values of 15° (θ=1), 30° (θ=2), and 45° (θ=3). The escape behavior was characterized using five variables: escape speed (ν), escape acceleration (α), responsiveness (γ), branch length similarity entropy (ε), and alignment (ϕ). The experimental results showed when (S, θ)=(fixed, varied), the change in values of the five variables were not significant. Thus, the fish respond more sensitively to S than to θ In contrast, when (S, θ)=(varied, fixed), ν, α, and γ showed increasing trends but ε and ϕ did not change much. This indicates the nature of fish escape behavior irrespective of the threat is inherent in ε and ϕ. I found that fish escape behavior can be divided into two types for the five physical quantities. In particular, the analysis showed that the type was mainly determined by the size of the model bird.

Analysis of Changes in Consumption Habits and Leisure life after Covid-19 using Big Data (빅데이터를 활용한 코로나 이후 소비습관과 여가생활의 변화 분석)

  • Kwon, Ki-Woong;Jeong, Myeong-Jin;Woo, Sung-Hee
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2022.05a
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    • pp.562-564
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    • 2022
  • Since the outbreak of COVID-19, a new consumption trend is being formed due to changes in the consumption habits and leisure life of citizens. Accordingly, the self-employed are experiencing a lot of confusion, and the self-employed who fail to respond sensitively to changes are forced to close their businesses. Therefore, this study analyzes changes in people's consumption habits and leisure life using public data, and based on this, suggests a way for the self-employed to predict consumers' consumption propensity and respond quickly.

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Study on Fluid Distribution in Slot-die Head Using CFD (CFD를 이용한 슬롯 다이 헤드 내부의 유체 분포 분석)

  • Yoo, Suho;Kim, Gieun;Shin, Youngkyun;Park, Jongwoon
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.39-44
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    • 2022
  • Using a CFD (computational fluid dynamics) simulation tool, we have offered a design guideline of a slot-die head having a simple T-shaped cavity through an analysis of the fluid dynamics in terms of cavity pressure and outlet velocity, which affect the uniformity of coated thin films. We have visualized the fluid flow with a transparent slot-die head where poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT:PSS) is injected. We have shown that the fluid dynamics inside the slot-die head depends sensitively on the cavity depth, cavity length, land length, and channel gap (i.e., shim thickness). Of those, the channel gap is the most critical parameter that determines the uniformity of the pressure and velocity distributions. A pressure drop inside the cavity is shown to be reduced with decreasing shim thickness. To quantify it, we have also calculated the coefficient of variation (CV). In accordance with Hagen-Poiseuille's laws and electron-hydraulic analogy, the CV value is decreased with increasing cavity depth, cavity length, and land length.

Implication of Social Rejection in Cognitive Bias Modification Interpretation Training in Adolescents With Eating Disorders

  • Youl-Ri Kim;Sohee Lee;Yeon-Sun Cho
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.35 no.2
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    • pp.101-106
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    • 2024
  • Objectives: Difficulties in interpersonal relationships intensify negative emotions and act as risk and maintenance factors for eating pathology in eating disorders. Rejection sensitivity refers to the tendency to react sensitively to a rejection. Patients with eating disorders experience difficulties in interpersonal relationships because of their high sensitivity to rejection. Cognitive bias modification interpretation (CBM-I) is a treatment developed to correct interpretation bias for social and emotional stimuli. In this review, we searched for research characteristics and trends through a systematic literature analysis of CBM-I for eating disorders. Methods: Five papers that met the selection and exclusion criteria were included in the final literature review and analyzed according to detailed topics (participant characteristics, design, and results). Results: The literature supports the efficacy of the CBM-I in reducing negative interpretation bias and eating disorder psychopathology in patients with eating disorders. CBM-I targets emotional dysregulation in adolescent patients with eating disorders and serves as an additional strengthening psychotherapy to alleviate eating disorder symptoms. Conclusion: The current findings highlight the potential of CBM-I as an individualized adjunctive treatment for adolescents with eating disorders and social functioning problems.

Thermodynamic Performance Analysis of Ammonia-Water Power Generation System Using Low-temperature Heat Source and Liquefied Natural Gas Cold Energy (저온 열원과 LNG 냉열을 이용하는 암모니아-물 동력 사이클의 열역학적 성능 해석)

  • Kim, Kyoung Hoon;Kim, Kyung Chun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.6
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    • pp.483-491
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    • 2014
  • In this study, a thermodynamic analysis was carried out for a combined power generation system using a low-temperature heat source in the form of sensitive energy and liquefied natural gas cold energy. An ammonia-water mixture, which is a zeotropic mixture, was used as the working fluid, and systems with and without a regenerator were comparatively analyzed. The effects of the mass fraction of ammonia and the condensation temperature of the working fluid on the system variables, including the net work production, exergy destruction, and thermal and exergy efficiencies, are analyzed and discussed. The results show that the performance characteristics of the system varied sensitively with the ammonia concentration or condensation temperature of the working fluid. The system without regeneration was found to be better in relation to the net work per unit mass of the source fluid, whereas the system with regeneration was better in relation to the thermal or exergy efficiency.

Seismic Performance Evaluation of Piping System Crossing the Isolation Interface in Seismically Isolated NPP (면진 원전 면진-비면진구간 연결 배관의 내진성능 평가)

  • Hahm, Daegi;Park, Junhee;Choi, In-Kil
    • Journal of the Earthquake Engineering Society of Korea
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    • v.18 no.3
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    • pp.141-150
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    • 2014
  • A methodology to evaluate the seismic performance of interface piping systems that cross the isolation interface in the seismically isolated nuclear power plant (NPP) was developed. The developed methodology was applied to the safety-related interface piping system to demonstrate the seismic performance of the target piping system. Not only the seismic performance for the design level earthquakes but also the performance for the beyond design level earthquakes were evaluated. Two artificial seismic ground input motions which were matched to the design response spectra and two historical earthquake ground motions were used for the seismic analysis of piping system. The preliminary performance evaluation results show that the excessive relative displacements can occur in the seismically isolated piping system. If the input ground motion contained relatively high energy in the low frequency region, we could find that the stress response of the piping system exceed the allowable stress level even though the intensity of the input ground motion is equal to the design level earthquake. The structural responses and seismic performances of piping system were varied sensitively with respect to the intensities and frequency contents of input ground motions. Therefore, for the application of isolation system to NPPs and the verification of the safety of piping system, the seismic performance of the piping system subjected to the earthquake at the target NPP site should be evaluated firstly.

An analysis of acoustic pressure in the center of double pipe inside of a cylindrical vibrator (원통형 진동자 내부의 이중관 중심에서의 음압해석)

  • Kim, Jungsoon;Kim, Moojoon
    • The Journal of the Acoustical Society of Korea
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    • v.36 no.3
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    • pp.165-171
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    • 2017
  • The effect of the concentric solid tube inserted inside the vibrator on the sound field distribution was analyzed for the sound waves focused on the center axis in the fluid - filled cylindrical piezoelectric transducer. The sound waves radiated from the inside of the cylindrical piezoelectric vibrator are transmitted through the fluid medium and are reflected or transmitted on the wall surface of the solid tube, and are focused on the central axis. At this time, the sound field distribution centered on the acoustic tube varies depending on the acoustic impedance and the thickness of the solid tube. In order to theoretically analyze this, the transfer matrix for each medium is derived, and the sound pressure level at the center axis is theoretically analyzed. For the acrylic tube with various thicknesses, the changing trend in the sound pressure level measured on the central axis agrees well with the result of the theoretical analysis, and it confirmed that the sound pressure formed at the center changes very sensitively with the thickness of the solid tube.