• 청정기술
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• 제14권3호
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• pp.160-165
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• 2008

Semi-batch 고압반응기에서 구리촉매를 이용한 디메틸카보네이트(DMC) 합성에 대하여 연구하였다. DMC는 메탄올을 일산화탄소와 산소로 직접 산화성 카르보닐화하여 합성되었다. 부식속도는 반응기에 스테인레스스틸 시험 조각을 미리 넣어서 반응하는 동안 그 무게 변화를 측정하여 구하였다. DMC의 수율을 크게 낮추지 않고 부식속도를 낮추기 위하여 아민, 올레핀, 다른 금속염과 같은 첨가제를 사용하였다. 1-메틸이미다졸을 첨가제로 사용하면 부식 없이 18.6%의 DMC 수율을 얻을 수 있었다. DMC의 사용량을 줄이면 0.5%의 낮은 부식속도로 33.2%의 DMC 높은 수율을 얻을 수 있었다.

• 전기화학회지
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• 제18권2호
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• pp.58-67
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• 2015

음극 표면에 solid electrolyte interphase (SEI)를 형성하는 전해질 첨가제인 lithium bis(oxalate) borate (LiBOB), fluoroethylene carbonate (FEC), vinylene carbonate (VC), 2-(triphenylphosphoranylidene) succinic anhydride (TPSA)를 $Li(Ni_{1/3}Co_{1/3}Mn_{1/3})O_2$ (NCM)/graphite 전지에 도입하여 고온 저장 특성을 비교하였다. 각 전지를 50%의 충전상태(stage of charge, SOC)에서, 고온 저장($60^{\circ}C$, 20일) 시킨 이후의 용량 유지율을 확인한 결과, LiBOB 1 wt.%가 가장 우수한 용량 유지 특성(초기 방전용량 대비 86.7%)을 나타내었다. LiBOB 1 wt.%의 경우 고온 저장 전후의 전지 저항 증가 및 SEI 두께 변화가 가장 적었고, 이는 음극 SEI에 포함된 다량의 semi-carbonate 물질과 연관성이 높다고 판단된다. 또한, LiBOB 1 wt.%가 포함된 NCM/graphite 전지의 상온($25^{\circ}C$) 및 고온수명($60^{\circ}C$) 특성도 기준 전해액(1.15 M lithium hexafluorophosphate (LiPF6) in ethylene carbonate/ethyl methyl carbonate (EC/EMC, 3/7 by volume))보다 각각 6%와 9% 향상된 결과를 보여주었다. 따라서, LiBOB이 상온 성능을 동등 이상으로 유지하면서도 고온 특성을 개선할 수 있는 우수한 전해액 첨가제로 판단된다.

• Advances in nano research
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• 제14권4호
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• pp.375-389
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• 2023

In this study, free vibration analysis of functionally graded (FG) porous truncated conical shell panels reinforced by graphene platelets (GPLs) has been investigated for the first time. Additionally, the effect of three different types of porosity distribution and five different types of GPLs patterns on dynamic response of the shell are also studied. Halpin-Tsai micromechanical model and Voigt's rule are used to determine Young modulus, shear modulus and Poisson's ratio with mass densities of the shell, respectively. The main novelties of present study are: applying 3D elasticity theory and the finite element method in conjunction with Rayleigh-Ritz method to give more accurate results unlike other simplified shell theories, and also presenting a general 3D solution in cylindrical coordinate system that can be used for analyses of different structures such as circular, annular and annular sector plates, cylindrical shells and panels, and conical shells and panels. A convergence study is performed to justify the correctness of the obtained solution and numerical results. The impact of porosity and GPLs patterns, the volume of voids, the weight fraction of graphene nanofillers, semi vertex and span angles of the cone, and various boundary conditions on natural frequencies of the functionally graded panel have been comprehensively studied and discussed. The results show that the most important parameter on dynamic response of FG porous truncated conical panel is the weight fraction of nanofiller and adding 1% weight fraction of nanofiller could increase 57% approximately the amounts of natural frequencies of the shell. Moreover, the porosity distribution has great effect on the value of natural frequency of structure rather than the porosity coefficient.

• 융합보안논문지
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• 제23권2호
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• pp.95-102
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• 2023

본 연구의 목적은 최근의 장교 지원율 하락에 따른 장교획득 수준의 시대적 심각성을 반영하여 장교 양성과정에서 핵심적인 역할을 수행하고 있는 일반대학 군사학과의 운영 수준을 상대적인 평가, 분석을 바탕으로 실증적 연구를 통하여 확인해 보고 개선을 위한 의미있는 결과를 확인하였다. 육군과 협약, 준협약을 통하여 운영되고 있는 일반대학 군사학과는 11개이며 대학별 군사학과 운영을 위해 투입되는 자원입력과 성과관점에서 자료포락분석법(DEA, Data Envelopment Analysis)을 적용하여 상대적인 효율성을 분석하고 개선을 위한 구체적인 방향을 확인하였다. 운영 효율성 분석결과, 11개 DMU 중에서 BCC모델의 경우 6개 대학이 효율적인 것으로 나타났고 자료포락분석 방법을 통하여 효율적, 비효율적인 집단에 대한 구분을 통해 평가결과를 확인해 볼 수 있었다. 본 연구는 상대적인 효율성을 평가하는데 여러 개의 평가요소를 한꺼번에 반영하여 초과, 부족한 부분을 나타내는 DEA-Additive 모델을 통해 비교대상 대학 군사학과들의 상대적인 측면에서 효율성을 확인하고 발전을 위한 구체적인 정보를 확인한다는 점에서 실용적 가치가 있을 수 있다.

• International Journal of Precision Engineering and Manufacturing
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• 제9권3호
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• pp.22-26
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• 2008

The use of electrical discharge machining (EDM) for micro-machining applications requires particular attention to the machined surface roughness and discharge gap distance, as these factors affect the geometrical accuracy of micro-parts. Previous studies of conventional EDM have shown that selected types of semi-conductive and non-conductive powder suspended in the dielectric reduced the surface roughness while ensuring a limited increase in the gap distance. Based on this, an extension of the technique to micro-EDM was studied Such work is necessary since the introduction of nanopowders suspended in the dielectric is not well understood. The experimental results showed that a statistically significant reduction in the surface roughness value was achieved at particular concentrations of the powder additives, depending on the powder material and the machining input energy setting. The average reduction in surface roughness using a powder suspended dielectric was between 14-24% of the average surface roughness generated using a pure dielectric. Furthermore, when these additive concentrations were used for machining, no adverse increase in the gap distance was observed.

• KSBB Journal
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• 제31권3호
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• pp.186-191
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• 2016

A liquid chromatographic method for the enantiomer separation of fluoxetine was performed using covalently bonded and coated type polysaccharide-derived chiral stationary phases (CSPs). The degree of enantioseparation is affected by the used CSPs and mobile phases. The performance of Chiralpak IC was superior to the other CSPs used in this study. Out of various solvent composition and additives, the greatest separation and resolution was observed using Chiralpak IC with mobile phase of 2-propanol in hexane with diethylamine as an additive. Semi-preparative separation of fluoxetine was performed on the analytical Chiralpak IC column to obtain (R)- and (S)-fluoxetine enantiomer with high chemical and optical purity. From the overall study, the developed liquid chromatographic method on polysaccharide-derived CSPs is expected to be very useful for the enantiomer separation of fluoxetine.

• 한국해안해양공학회지
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• 제10권2호
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• pp.73-82
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• 1998

연안에서 표층 방류된 온수의 확산-이송을 모의하고자 배출구 인근의 근역에서는 반능동적 입자추적의 원리가 적용된 부작위행보모형과 원역에서는 Eulerian-Lagrangian 농도가 결합된 2차원 모형이 개발되었다. 근역에서 표층으로 부상되는 온수괴는 부력을 갖는 다수의 입자군으로 변환되어 초기 평면확산의 증가를 나타내고, 이러한 부력확산의 영향이 무작위행보의 기본식에 도입되었다. 개발된 모형의 초기평가는 단순한 지형의 해역과 실제해역에서 수행되었다. 단순해역에서는 부력이 고려되지 않는 중립입자모형의 결과에 비하여 초기 확산이 크게 나타나고, 기존 근역모형CORMIX3과 유사하나 외해측으로 확장된 성향을 보인다. 천수만에서 실제적용 결과도 배출구 근처에서 관측치에 유사한 퍼짐 효과가 나타나며 모형의 적용성이 인정된다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2002년도 추계학술대회 논문집
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• pp.544-547
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• 2002

According to the rising of national economic level. domestic consumption of vegetables having high additive values is increased continuously due to increased consumption of meat in last decade. These vegetables are produced almost in this country and are limited to import from neighbor countries in due of high transportation expenses for storing in refrigerated container. It is very important to mechanize the harvest work, forming more than 30% for their production cost, in order to cultivate variable vegetables at the same time according to their harvesting seasons. In this state its former harvest methods, with using of human power or semi-automatic harvest, caused to increase their production cost due to high labor cost and low working efficiency. The former onion harvest being operated almost by semi-automatic plant distributer mechanism have many limit and troublesome for cultivation spaces, vinyle mulched ridge, gravel mixture in soil. Therefore, it is necessary to develope a fully automatic and self-running situation and overcome above handicaps, even in the farm covered with vinyle house or mulch sheets. This newly developed onion harvest can be applied to plant various young trees and will be able to export together with onion haying their competition in the worldwide market in which the culinary vegetable method or farm conditions is similar to our country.

• 한국세라믹학회지
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• 제29권12호
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• pp.981-989
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• 1992

This is a study on the effects of cristobalite transition of quartz in semi-vitrious whiteware body, as addition of alkali and alkali earth oxides, prepared by pottery stone, feldspar, kaolin and clay minerals. The amounts of ${\alpha}$-quartz to ${\alpha}$-cristobalite transition, F.O.C. (fraction of cristobalite), were increased with firing temperature. In MgO added body, ${\alpha}$-quartz was decreased and the formation of cristobalite was increased. Effects of K2O addition was remarkably decreased the formation of cristobalite. Additive effects of MgO and K2O were confirmed that it was very different to variation of transition temperature of metakaolinite to Si-Al spinel structure in thermal reaction of kaolinite minerals. Result CaO addition was ineffective to transition temperature, and the transition temperature in Na2O added body was decreased, but relative intensity of quartz and cristobalite crystal in XRD results was decreased. This was characterized by the effects on the formation of liquid phase much more.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2003년도 춘계학술대회 논문집
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• pp.45-49
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• 2003

According to the rising of national economic level, domestic consumption of vegetables having high additive values is increased continuously due to increased consumption of meat in last decade. These vegetables are produced almost in this country and are limited to import from neighbor countries in due of high transportation expenses for storing in refrigerated container. It is very important to mechanize the harvest work, forming more than 30% for their production cost, in order to cultivate variable vegetables at the same time according to their harvesting seasons. In this state its former harvest methods, with using of human power or semi-automatic harvest, caused to increase their production cost due to high labor cost and low working efficiency.