• Title/Summary/Keyword: second harmonic generation

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How Do Liquid Crystal Molecules Align on Treated Surfaces?

  • Okada, Yoshinori;Shioda, Tatsutoshi;Chung, Doo-Han;Park, Byoung-Choo;Takezoe, Hideo
    • Journal of Information Display
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    • v.4 no.2
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    • pp.29-34
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    • 2003
  • We have studied liquid crystal (LC) molecular alignment on rubbed and photoaligned surfaces. Particular attention was paid to the intermolecular liquid crystalline interaction. We will first show that uniform molecular orientation on a rubbed surface does not mean spatially uniform interaction between the surface and LC molecules. Rather LCs tend to align themselves through LC interaction. The existence of nonuniformity of rubbing was successfully visualized by double surface treatment. The importance of intermolecular LC interaction was also found in the orientation formation process in 5CB evaporated on rubbed and photoaligned surfaces. By simultaneously analyzing polarized UVNIS absorption and second-harmonic generation (SHG) using the maximum entropy method, we succeeded in obtaining the temporal variation of the orientational distribution functions in the film forming process. The distribution anisotropy and pretilt are found to be generated under the influence of intermolecular LC interaction.

A Novel Fast Open-loop Phase Locking Scheme Based on Synchronous Reference Frame for Three-phase Non-ideal Power Grids

  • Xiong, Liansong;Zhuo, Fang;Wang, Feng;Liu, Xiaokang;Zhu, Minghua;Yi, Hao
    • Journal of Power Electronics
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    • v.16 no.4
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    • pp.1513-1525
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    • 2016
  • Rapid and accurate phase synchronization is critical for the reliable control of grid-tied inverters. However, the commonly used software phase-locked loop methods do not always satisfy the need for high-speed and accurate phase synchronization under severe grid imbalance conditions. To address this problem, this study develops a novel open-loop phase locking scheme based on a synchronous reference frame. The proposed scheme is characterized by remarkable response speed, high accuracy, and easy implementation. It comprises three functional cascaded blocks: fast orthogonal signal generation block, fast fundamental-frequency positive sequence component construction block, and fast phase calculation block. The developed virtual orthogonal signal generation method in the first block, which is characterized by noise immunity and high accuracy, can effectively avoid approximation errors and noise amplification in a wide range of sampling frequencies. In the second block, which is the foundation for achieving fast phase synchronization within 3 ms, the fundamental-frequency positive sequence components of unsymmetrical grid voltages can be achieved with the developed orthogonal signal construction strategy and the symmetrical component method. The real-time grid phase can be consequently obtained in the third block, which is free from self-tuning closed-loop control and thus improves the dynamic performance of the proposed scheme. The proposed scheme is adaptive to severe unsymmetrical grid voltages with sudden changes in magnitude, phase, and/or frequency. Moreover, this scheme is able to eliminate phase errors induced by harmonics and random noise. The validity and utility of the proposed scheme are verified by the experimental results.

Computer Simulation on the Poling Mechanism for the Control of 2nd Order Optical Nonlinearity in Silica Glass (2차 비선형 광특성의 제어를 위한 실리카 유리의 전기분극 기구 전산모사)

  • Yu, Ung-Hyeon;Lee, Seung-Gyu;Sin, Dong-Uk;Jeong, Yong-Jae
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.207-214
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    • 2001
  • Silica glass is a core material for optical fiber in optical telecommunications, but its centrosymmetry eliminates the second order nonlinearity. But it is experimentally well known that the space charge polarization induces the Second Harmonic Generation (SHG) when a strong DC voltage is applied to silica glass for a long period of time with metal blocking electrodes. In this report, the results of a theoretical calculation of the nonlinear optical property caused by the space charge polarization, and a model of a numerical analysis to predict the small chance in nonlinear optical property as functions of time and space are provided. Assuming that amorphous silica is a solid state electrolyte and sodium ion is the only mobile charge carrier, 'Finite Difference Method' was employed for modeling of numerical analysis. The distributions of the concentration of sodium ion and electric field as functions of a normalized length of the specimen and a normalized applied voltage were simulated.

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Double-pass Second Harmonics Generation of Tunable CW Infrared Laser Beam of DOFA System in Periodically Poled LiNbO3 (PPLN 비선형 결정과 이중통과법을 이용한 DOFA 시스템에서 증폭된 연속발진형 파장가변 적외선 레이저광의 제 2고조파 발생)

  • Yoo, Kil-Sang;Jo, Jae-Heung;Ko, Kwang-Hoon;Lim, Gwon;Jeong, Do-Young
    • Korean Journal of Optics and Photonics
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    • v.19 no.3
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    • pp.229-236
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    • 2008
  • The optimum conditions of second harmonic generation (SHG) can be successfully achieved experimentally using single pass and double pass methods of a pumping beam. The beam has a power of several Watts radiated by a DOFA (Diode Laser Oscillator & Fiber Amplifier) system, which is a high power CW wavelength tunable infrared laser system, in a PPLN (Periodically Poled MgO doped Lithium Niobate) nonlinear crystal. In the case of a single pass method, the parameters are the wavelength of 535 nm for SHG and the output power of 245 mW generated from the pumping input beam with wavelength of 1070 nm and the power of 2.45 W at phase matching temperature of $108.9^{\circ}C$. The conversion efficiency of SHG was 10%. In order to enhance the output of SHG, the double pass method of the SHG system of a PPLN using a concave mirror for the retroreflection and a pair of wedged flat windows for phase compensation was also presented. In this double pass system, we obtained the SHG output beam with the wavelength of 535 nm and the maximum power of 383 mW at optimum phase matching temperature of $108.5^{\circ}C$ by using an incident pumping beam with wavelength of 1070 nm and the power of 2.45 W. The maximum conversion efficiency is 15.6%, which is more than that of the single pass method.

Second Order Nonlinear Optical Polyimides Containing Organic Chromophores with an Oxadiazole Segment (옥사디아졸 결합의 유기 발색단이 도입된 이차비선형 광학 이미드 고분자)

  • Do, Jung Yun;Kim, Bong Gun;Kwon, Ji-Yun
    • Applied Chemistry for Engineering
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    • v.18 no.1
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    • pp.77-83
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    • 2007
  • It is essential that second order nonlinear optical materials have low optical propagation losses in the wavelengths of second harmonic generation for practical applications in waveguides. Three dipolar chromophores substituted with nitro, cyano, and alkyl sulfone as an electron withdrawing group were prepared. The UV-Vis absorption spectra of the cyano and alkylsulfone chromophores showed a blue-shift compared to the nitro chromophore. The introduction of oxadiazole segment in the chromophore structure led to similar spectral shift. The blue-shift can produce low optical loses at second harmonics. The chromophores were successfully attached to a polyimide, yielding side chain polymers. The nonlinear optical property of the prepared optical polymers was determined by measuring electro-optic coefficient at 1.55 mm. The polymers exhibited high glass transition temperature of over $185^{\circ}C$ and thermal stability to $300^{\circ}C$ through differential scanning calorimeter analysis and thermal gravimetric analysis.

Precise Estimation of Nonlinear Parameter in Pulse-Like Ultrasonic Signal (펄스형 초음파 신호에서 비선형 파라미터의 정밀 추정)

  • Ha, Job;Jhang, Kyung-Young;Sasaki, Kimio;Tanaka, Hiroaki
    • Journal of the Korean Society for Nondestructive Testing
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    • v.26 no.2
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    • pp.77-83
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    • 2006
  • Ultrasonic nonlinearity has been considered as a solution for the detection of microcracks or interfacial delamination in a layered structure. The distinguished phenomenon in nonlinear ultrasonics is the generation of higher-order harmonic waves during the propagation. Therefore, in order to quantify the nonlinearity, the conventional method measures a parameter defined as the amplitude ratio of a second-order harmonic component and a fundamental frequency component included in the propagated ultrasonic wave signal. However, its application In field inspection is not easy at the present stage because no standard methodology has yet been made to accurately estimate this parameter. Thus, the aim of this paper is to propose an advanced signal processing technique for the precise estimation of a nonlinear ultrasonic parameter, which is based on power spectral and bispectral analysis. The method of estimating power spectrum and bispectrum of the pulse-like ultrasonic wave signal used in the commercial SAM (scanning acoustic microscopy) equipment is especially considered in this study The usefulness of the proposed method Is confirmed by experiments for a Newton ring with a continuous air gap between two glasses and a real semiconductor sample with local delaminations. The results show that the nonlinear parameter obtained tv the proposed method had a good correlation with the delamination.

Phase Transitions of Template Synthesized $PbTiO_{3}$ Nano-structures (형판 합성된 $PbTiO_{3}$ 나노-구조의 상전이)

  • Chang, Ki-Seog;Bu, Sang-Don;Hernandez Bernadez A.;Fisher Ellen R.;Dorbout Peter K.
    • Korean Journal of Crystallography
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    • v.16 no.2
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    • pp.128-137
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    • 2005
  • We report on the phase transitions of the perovskite nanostructures made by sol-gel template synthesis. The lead titanate ($PbTiO_{3}$) nanostructures were prepared with a chelate sol-gel of titanium tetrabutoxide ($Ti(O^{i}Pr){4}$) and lead acetate ($Pb(OAc)_{2}-3H_{2}O$). $Whatman^{\circledr}$ anodisc membranes (with about 200 nm pore size) served as the template. The template was dipped into the sol, allowed to air dry, and then calcined at $650^{\circ}C$. We have characterized the temperatures of the phase transitions in the $PbTiO_{3}$ nano-structures using DSC, DTA, and second harmonic generation (SHG).

Influence of Deposition Method on Refractive Index of SiO2 and TiO2 Thin Films for Anti-reflective Multilayers

  • Song, Myung-Keun;Yang, Woo-Seok;Kwon, Soon-Woo;Song, Yo-Seung;Cho, Nam-Ihn;Lee, Deuk-Yong
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.524-530
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    • 2008
  • Anti-Reflective (AR) thin film coatings of $SiO_2$ (n= 1.48) and $TiO_2$ (n=2.17) were deposited by ion-beam assisted deposition (IBAD) with End-Hall ion source and conventional electron beam (e-beam) evaporation to investigate the effect of deposition method on the refractive indicies (n) of the fIlms. Green-light generation using a GaAs laser diode was achieved via excitation of the second harmonic. The latter resulted from the transmission of the fundamental guided-mode wave of 1064 nm through periodically poled $LiNbO_3$. Large differences in the refractive indicies of each of the layers in the multilayer coating may improve AR performance. IBAD of $SiO_2$ reduced its refractive index from 1.45 to 1.34 at 1064 nm. Conversely, e-beam evaporation of $TiO_2$ increased its refractive index from 1.80 to 2.11. In addition, no fluctuations in absorption at the wavelength of 1064 nm were found. The results suggest that films prepared by different deposition methods can increase the effectiveness of multilayer AR coatings.

Ferroelectric and Antiferroelectric Behavior in Chiral Bent-shaped Molecules with an Asymmetric Central Naphthalene Core

  • Lee, Seng-Kue;Tokita, Masatoshi;Shimbo, Yoshio;Kang, Kyung-Tae;Takezoe, Hideo;Watanabe, Junji
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2241-2247
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    • 2007
  • A new series of chiral bent-shaped liquid crystals with an asymmetric central core based on 1,6- dihydroxynaphthalene and chiral terminal chain prepared from (S)-(?)-2-methyl-1-butanol, 1,6-naphthalene bis[4-(4-alkoxyphenyliminomethyl)]benzoates [N(1,6)-n-O-PIMB(n-2)*-(n-4)O (n = 8-11)] were synthesized. Their mesomorphic properties and phase structures were investigated by means of electro-optical, polarization reversal current, and second harmonic generation measurements in order to confirm the relationship between the molecular structure and phase structure. All odd n (n = 9 and 11) compounds, N(1,6)-9-O-PIMB7*-5O and N(1,6)-11-O-PIMB9*-7O exhibit antiferroelectric phase, whereas even n (n = 8 and 10) compounds was flexible, N(1,6)-10-O-PIMB8*-6O exhibits the ferroelectric phase but N(1,6)-8-O-PIMB6*-4O exhibits the antiferroelectric phase. These results come from the decrease of the closed packing efficiency within a layer and the lack of uniform interlayer interaction between adjacent layers, which were caused by the asymmetrical naphthalene central core. Thus, we concluded that the structure of central core as well as the terminal chain plays an important role for the emergence of particular polar ordering in phase structures.

Multimodal Nonlinear Optical Microscopy for Simultaneous 3-D Label-Free and Immunofluorescence Imaging of Biological Samples

  • Park, Joo Hyun;Lee, Eun-Soo;Lee, Jae Yong;Lee, Eun Seong;Lee, Tae Geol;Kim, Se-Hwa;Lee, Sang-Won
    • Journal of the Optical Society of Korea
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    • v.18 no.5
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    • pp.551-557
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    • 2014
  • In this study, we demonstrated multimodal nonlinear optical (NLO) microscopy integrated simultaneously with two-photon excitation fluorescence (TPEF), second-harmonic generation (SHG), and coherent anti-Stokes Raman scattering (CARS) in order to obtain targeted cellular and label-free images in an immunofluorescence assay of the atherosclerotic aorta from apolipoprotein E-deficient mice. The multimodal NLO microscope used two laser systems: picosecond (ps) and femtosecond (fs) pulsed lasers. A pair of ps-pulsed lights served for CARS (817 nm and 1064 nm) and SHG (817 nm) images; light from the fs-pulsed laser with the center wavelength of 720 nm was incident into the sample to obtain autofluorescence and targeted molecular TPEF images for high efficiency of fluorescence intensity without cross-talk. For multicolor-targeted TPEF imaging, we stained smooth-muscle cells and macrophages with fluorescent dyes (Alexa Fluor 350 and Alexa Fluor 594) for an immunofluorescence assay. Each depth-sectioned image consisted of $512{\times}512$ pixels with a field of view of $250{\times}250{\mu}m^2$, a lateral resolution of $0.4{\mu}m$, and an axial resolution of $1.3{\mu}m$. We obtained composite multicolor images with conventional label-free NLO images and targeted TPEF images in atherosclerotic-plaque samples. Multicolor 3-D imaging of atherosclerotic-plaque structural and functional composition will be helpful for understanding the pathogenesis of cardiovascular disease.