• Title/Summary/Keyword: sampling series

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A Study on the Performance Optimization of a Continuous Monitoring Method for Hazardous VOCs in the Ambient Atmosphere (환경대기 중 유해성 VOC에 대한 자동연속 측정방법의 성능 최적화에 관한 연구)

  • Son, Eun-Seong;Seo, Young-Kyo;Lee, Dong-Hyun;Lee, Min-Do;Han, Jin-Seok;Baek, Sung-Ok
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.6
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    • pp.523-538
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    • 2009
  • Recently, there has been a keen demand for real-time automatic monitoring of VOCs not only in Korea but other developed countries. We carried out this study to evaluate and to optimize the performance of a continuous automatic monitoring system for hazardous VOCs (HVOCs) in the ambient atmosphere, using an on-line GC system. The online system normally consisted of a Nafion dryer prior to a cold trap of an automatic thermal desorption apparatus and a GC system equipped with two detectors, i.e. PID and ECD. Preliminary tests conducted to check out any contamination of the system revealed an evidence of significant artifact formation of benzene, and it was found that the Nafion dryer (even brand new one) is the source of the benzene artifact. Thus, all the subsequent experiments in this study was carried out inevitably by removing the Nafion dryer. The on-line GC method was investigated with a variety of QC/QA performance criteria such as repeatability, linearity, lower detection limits, and accuracy. In order to find out the best operating condition for the on-line GC system, three different types (in terms of adsorption strength) of cold trap combinations were tested, i.e. (i) Tenax-TA and Carbopack-B combination (weak and hydrophobic); (ii) Tenax-TA, Carbopack-X and Carboxen-1000 combination (strong and hydrophilic); and (iii) Tenax-TA and Carbopack-X combination (medium and hydrophobic/hydrophilic). The USEPA TO-17 manual method was selected as a reference method to evaluate the performance of the on-line method. A series of experiments revealed that the system performance was superior to others when a cold trap packed with hydrophilic adsorbents (Tenax-TA/Carbopack-X/Carboxen-1000 combination) was used and operated at $25^{\circ}C$. However, the system with a cold trap packed with a combination of Tenax-TA and Carbopack-X is more recommended for field applications since the carboxen-1000 adsorbent is too sensitive to water vapor, and hence the performance of the system might be very unstable to humid samples or during rainy days. Furthermore, the precision and accuracy criteria of the Tenax-TA/ Carbopack-X combination were generally compatible with the triple adsorbents cold trap. The continuous automatic monitoring method is, thus, considered very useful to real-time monitoring to understand the variations of VOCs concentrations in ambient air, as it adopts much simpler procedures in sampling, analysis, and data integration steps than manual monitoring methods. However, it should be noted that there is a high possibility of benzene artifacts formation through the Nafion dryer, which is often installed to remove water vapor in air samples before being adsorbed onto the cold trap. Therefore, if a Nafion dryer is used in any studies of monitoring VOCs, the benzene contamination should be carefully examined before carrying out obtaining the data.

Treatment Outcome and Prognostic Factors of Cushing's Disease in Adults (성인 쿠싱병의 치료성적과 예후인자)

  • Park, Chul-Kee;Hwang, Sung Kyun;Gwak, Ho-Shin;Yoo, Heon;Chung, Young Seob;Paek, Sun Ha;Kim, Dong Gyu;Jung, Hee-Won;Kim, Seong Yeon;Hong, Seung Kuan
    • Journal of Korean Neurosurgical Society
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    • v.29 no.10
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    • pp.1316-1321
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    • 2000
  • Objectives : The authors analyzed the surgical series of Cushing's disease to evaluate the proper treatment policy and to verify the possible prognostic factors. Material and Methods : Of 50 patients diagnosed as Cushing's disease and operated at Department of Neurosurgery of our institute between 1988 and 1999, 48 patients with available medical records were analyzed retrospectively. Mean follow-up period was 48 months(3 to 109 months). Preoperative diagnosis was made after evaluating the patients with multiple-stage endocrinological studies and 31 selective patients were evaluated with inferior petrosal sinus sampling(IPSS). Magnetic resonance imaging(MRI) and/or high resolution computerized tomography(CT) was done in all patients. A total of 51 transsphenoidal adenomectomy(TSA) were performed including 3 revision for initial surgical failure cases. Remission was decided on the basis of both endocrinological criteria and clinical status. Radiation and/or ketoconazole therapy were applied to failed cases. For the verification of prognostic factors, the authors evaluated the statistical significance of multiple variables over remission rate by chi-square test. Result : Sensitivity of IPSS for central localization was 93.5% which was better than that of MRI(87.5%). But for lateralization, it was 72.4% for IPSS versus MRI 90.5%. Success rate of TSA was 82%(42/51) and recurrence rate was 9%(4/48). When including adjuvant treatments for surgically failed cases, overall success rate was 89.6% and all of 3 reoperated cases(TSA) due to recurrence were successful. Significant complication occurred in 7.8%(4/51) after TSA including hypopituitarism, diabetes insipidus, and visual loss. Non-existence of tumor in MRI and prolonged symptom duration(>3 years) were significant prognostic factors. Conclusion : TSA can be considered as initial treatment for Cushing's disease. In surgically failed cases, multiple treatment modality may improve the overall outcome and repeated TSA for recurrent cases seem to provide similar success.

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An Analytical Review of the Methods Computing Age at First Marriage (평균초혼연령 측정방법에 관한 소고)

  • 김남일;이지현
    • Korea journal of population studies
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    • v.18 no.2
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    • pp.1-22
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    • 1995
  • In this paper, the methods to measure the mean age at first marriage is examined, and by analysing data of Korean women for the period 1970-1990, the differences that each methods make on measurements of the mean age at first marriage are presented. The main findings were : The Hajnal's SMAM, the most used index in studies of the pattern of marriage in Korea, was not a measure based on the marriages for a specific period. The resulting biases, in cases of 1970-1990 Korean women, were below 0.3 year in age, which can be considered small, if the changes in the pattern of marriage in these periods took into account. But the possibility of bringing larger bias cannot be excluded. Also the direction of biases was toward raising the mean age when marriage was in upward tendency. Considering the availability of data in Korea, the utilization of the simple mean or the measure from Agarwala method according to the purpose is recommendable. The mean age at first marriage by Agarwala(ASMAM) meets with the one computed from a gross nuptiality table based on the cohort's marriage rates for a specific period. The time series of the proportion single by age groups obtained from the population censuses showed high consistency. However when they were compaired with those computed from sample surveys at a same point of time, significant differences(at $\alpha$=0.05) were found in some major age groups. It was also pointed out that these differences were not caused by the problems related with the sampling frame for surveys or the survey questions.

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A 10b 100MS/s 27.2mW $0.8mm^2$ 0.18um CMOS Pipeline ADC with Various Circuit Sharing Schemes (다양한 회로 공유기법을 사용하는 10비트 100MS/s 27.2mW $0.8mm^2$ 0.18um CMOS Pipeline ADC)

  • Yoon, Kun-Yong;Lee, Se-Won;Choi, Min-Ho;Lee, Seung-Hoon
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.4
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    • pp.53-63
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    • 2009
  • This work proposes a 10b 100MS/s 27.2mW $0.8mm^2$ 0.18um CMOS ADC for WLAN such as an IEEE 802.11n standard. The proposed ADC employs a three-stage pipeline architecture and minimizes power consumption and chip area by sharing as many circuits as possible. Two multiplying DACs share a single amplifier without MOS switches connected in series while the shared amplifier does not show a conventional memory effect. All three flash ADCs use only one resistor ladder while the second and third flash ADCs share all pre-amps to further reduce power consumption and chip area. The interpolation circuit employed in the flash ADCs halves the required number of pre-amps and an input-output isolated dynamic latch reduces the increased kickback noise caused by the pre-amp sharing. The prototype ADC implemented in a 0.18um n-well 1P6M CMOS process shows the DNL and INL within 0.83LSB and 1.52LSB at 10b, respectively. The ADC measures an SNDR of 52.1dB and an SFDR of 67.6dB at a sampling rate of 100MS/s. The ADC with an active die area of $0.8mm^2$ consumes 27.2mW at 1.8V and 100MS/s.

Experimental Evaluation of an Analytical Method for Chlorofluorocarbons (CFSs) in Air and Water Using Gas Chromatography (가스 크로마토그래피를 이용한 대기와 물시료의 CFCs(chlorofluorocarbons) 분석법의 실험적 평가)

  • Koh, Dong-Chan;Choi, Beom-Kyu;Kim, Yong-Je
    • Economic and Environmental Geology
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    • v.40 no.1 s.182
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    • pp.129-140
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    • 2007
  • CFC(CFC-12, CFC-11 and CFC-113) analytical system for air and water was constructed using a customized purge and trap extraction device and a gas chromatograph with an electron capture detector. Sampling methods of air and water for CFCs were also established. The analytical system was experimentally optimized to result in reproducibilities of triplicates less than 2% for current air samples and less than 5% for groundwater samples with CFC-12 concentration of 160 to 180 pg/kg, and verified with respect to the CFC system in USGS, which showed analytical results were in agreement within 10%. CFCs in air were monitored at three sites over 19-month period in the central part of South Korea, and the result indicates no significant local sources of CFCs in those areas. For groundwater in Jeju Island, CFCs were measured over a year with a two-month interval. The time-series data showed seasonal fluctuations which could be interpreted by the effect of recharge pulse derived from large amount of rainfall during monsoon period with a few month delay, which indicates high permeability of basaltic rocks in Jeju Island.

Application of Geophysical Techniques for Observing the Void Ratio Changes of Dredged Soils (준설토의 간극비 변화 관찰을 위한 물리탐사기법의 적용)

  • Hong, Young-Ho;Lee, Jong-Sub;Lee, Changho
    • Journal of the Korean Geotechnical Society
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    • v.30 no.9
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    • pp.19-28
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    • 2014
  • It is necessary to understand the behavior of the soils for the dredging constructions. The objective of this study is to estimate void ratio and density changes of the dredged soils by using the geophysical testing methods. A series of laboratory tests is performed to obtain geotechnical index properties of the specimen, retrieved from the west coastal of Korea. The sedimentation and self-weight consolidation tests are carried out with observing changes of the interfacial height and the elastic wave velocities. The same amounts of the soils are poured into the testing column at intervals of 12 hours until the interheight reaches to a certain level. After the completion of the sedimentatation and self-weight consolidation tests, downward permeability test is performed to assess a tidal influence in the nearshore. The mini resistance cone is penetrated into the specimen to measure the electrical resistivity with depth. All tests are completely finished, the weight of specimens are measured to calculate the void ratio with the depth. Experimental results show that the aspects of the self-weight consolidation are invisible during dredging process because of rapid sedimentation characteristics of ML. However, the elastic wave velocities increase with increasing in the effective stresses. During permeability test, measured permeability and the elastic wave velocities maintain almost identical values. Void ratio based on the elastic wave velocities changes linearly with time during the step dumpings. Void ratio estimated by the electrical resistivity represents the repeatedly layered depositions according to the step-by-step dumpings. Void ratio determined by soil sampling is similar to those of elastic waves and electrical resistivity profiles. This experimental study demonstrates that the geophysical testing methods may be an effective method for evaluating the behavior of dredged soils.

Characteristics and Fate of Stormwater Runoff Pollutants in Constructed Wetlands (도시지역에 적용가능한 인공습지에서의 강우유출수 함유 오염물질의 거동과 특성)

  • Alihan, Jawara Christian;Maniquiz-Redillas, Marla;Choi, Jiyeon;Flores, Precious Eureka;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.19 no.1
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    • pp.37-44
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    • 2017
  • Nonpoint source (NPS) pollution continues to degrade the water quality. NPS pollutants signals high concerns against a sustainable environment. Low impact development (LID) is the leading management practice which regulates and treats stormwater runoff especially in highly impervious urban areas. Constructed wetlands are known to have efficient removal capability of NPS pollutants. Likewise, these LID facilities were intended to maintain the predeveloped hydrologic regime through series of mechanisms such as particle settling, filtration, plant uptake, and etc. In this study, the objective was to investigate the characteristics, fate and treatment performance of the two in-campus constructed wetlands (SW1 and SW2) which were installed adjacent to impervious roads and parking lots to treat stormwater runoff. A total of 42 storm events were monitored starting from July 2010 until November 2015. Manual grab sampling was utilized at the inlet and outlet units of each LID facilities. Based on the results, the wetlands were found to be effective in reducing 37% and 41% of the total runoff volume and peak flows, respectively. Aside from this, outflow EMCs were generally lower than the inflow EMCs in most events suggesting that the two wetlands improved the water quality of stormwater runoff. The average removal efficiency of pollutants in facilities were 63~79% in TSS, 38~54% in TN, 54% in TP and 32%~81% in metals. The results of this study recommend the use of constructed wetlands as efficient treatment facility for urban areas for its satisfactory performance in runoff and pollutant reduction.

Performance of High Temperature Filter System for Radioactive Waste Vitrification Plant (방사성폐기물 유리화 플랜트 고온여과시스템의 성능 특성)

  • Seung-Chul, Park;Tae-Won, Hwang;Sang-Woon, Shin;Jong-Hyun, Ha;Hey-Suk, Kim;So-Jin, Park
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.201-209
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    • 2004
  • Important operation parameters and performance of a high temperature ceramic candle filter system were evaluated through a series of demonstration tests at a pilot-scale vitrification plant. At the initial period of each test, due to the growth of dust cake on the surface of ceramic candles, the pressure drop across the filter media increased sharply. After that it became stable to a certain range and varied continuously proportion to the face velocity of off-gas. On the contrary, at the initial period of each test, the permeability of filter element decreased rapidly and then it became stable. Back flushing of the filter system was effective under the back flushing air pressure range of 3∼5 bar. Based on the dust concentrations measured by iso-kinetic dust sampling at the inlet and outlet point of HTF, the dust collection efficiency of HTF evaluated. The result met the designed performance value of 99.9%. During the demonstration tests including a hundred hour long test, no specific failure or problem affecting the performance of HTF system were observed.

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Solid Chemical Material Site Analysis Research of Event Site (사건현장의 고체상 화학물질 현장분석 연구)

  • Kim, Sungbum;Noh, Hyeran;Lee, Jinseon;Kim, Jungmin;Cho, Munsik;Park, Choonhwa;Chun, Kwangsoo;Ahn, Seungyoung;Seok, Gwangseol
    • Journal of the Society of Disaster Information
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    • v.8 no.3
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    • pp.304-309
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    • 2012
  • National Institute of Environmental Research has Portable FT-IR(Fourier Transform Infrared Spectroscopy, A2 Technologies, U.S.A.) and Portable XRD(X-ray Diffraction, Olympus Innov-X co., U.S.A.) for the analysis of the solid sample rapidly on the spot where chemical terror accident took place and the portable equipments are operating now. However, we need a series of the analysis procedures for an efficient application of the equipments and getting the rapid analytical value about the investigation and sampling on the spot. And the accuracy of the portable equipments' analytical value is high but the application of them in an emergency is low because we are lack of the procedures about field-centered analysis and the usage. Therefore we would like to organize the result of this research about field analysis and the procedures of the solid portable equipments. And we also would like to apply it to the field of chemical terror accident.

Development of Western Cherry Fruit Fly, Rhagoletis indifferens Curran (Diptera: Tephritidae), after Overwintering in the Pacific North West Area of USA (미국 북서부지역에 발생하는 서부양벚과실파리의 발생 월동 후 발생 동태에 관한 연구)

  • Song, Yoo-Han;Ahn, Kwang-Bok
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.4
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    • pp.217-227
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    • 2007
  • The western cherry fruit fly, Rhagoletis indifferens Curran (Diptera:Tephritidae), is the most important pest of cultivated cherries in the Pacific Northwest area of the United States, being widely distributed throughout Oregon, Washington, Montana, Utah, Idaho, Colorado and parts of Nevada. The control of R. indifferens has been based on calendar sprays after its first emergence because of their zero tolerance for quarantine. Therefore, a good prediction model is needed for the spray timing. This study was conducted to obtain the empirical population dynamic information of R. indifferens after overwintering in the major cherry growing area of the Pacific Northwest of the United States, where the information is critically needed to develop and validate the prediction model of the fruit fly. Adult fly populations were monitored by using yellow sticky and emergence traps. Larvae growth and density in fruits were observed by fruit sampling and the pupal growth and density were monitored by pupal collection traps. The first adult was emerged around mid May and a large number of adults were caught in early June. A fruit had more than one larva from mid June to early July. A large number of pupae were caught in early July. The pupae were collected in various period of time to determine the effect of pupation timing and the soil moisture content during the winter. A series of population density data collected in each of the developmental stage were analyzed and organized to provide more reliable validation information for the population dynamic models.