• Title/Summary/Keyword: salicylic acid

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Efficient Photocatalytic Degradation of Salicylic Acid by Bactericidal ZnO

  • Karunakaran, Chockalingam;Naufal, Binu;Gomathisankar, Paramasivan
    • Journal of the Korean Chemical Society
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    • v.56 no.1
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    • pp.108-114
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    • 2012
  • Salicylic acid degrades at different rates under UV-A light on $TiO_2$, ZnO, CuO, $Fe_2O_3$, $Fe_3O_4$ and $ZrO_2$ nanocrystals and all the oxides exhibit sustainable photocatalysis. While ZnO-photocatalysis displays Langmuir-Hinshelwood kinetics the others follow first order on [salicylic acid]. The degradation on all the oxides enhance with illumination intensity. Dissolved oxygen is essential for the photodegradation. ZnO is the most efficient photocatalyst to degrade salicylic acid. Besides serving as the effective photocatalyst to degrade salicylic acid it also acts as a bactericide and inactivates E.coli even in absence of direct light.

A Spectroscopic Study of Hydrogen Bonding between Riboflavin and Salicylic Acid Derivatives

  • Huh, Jae-Wook;Yu, Byung-Sul
    • YAKHAK HOEJI
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    • v.20 no.3
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    • pp.130-137
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    • 1976
  • Specific association phenomena of riboflayin-2',3',4',5',- tetraacetate and salicylic acid derivatives, such as salicylic acid, aspirin and salicylamide have been measured by infrared and fluorescence spectroscopy. Salicylic acid and riboflavin tetraacetate oxyl group of the former. Asprin and riboflavin tetraacetate form the 1:1 cyclic hydrogen bonded dimer by the same mode. Salicylamide froms the 1:1 cyclic hydrogen bonded dimer with riboflavin tetraacetate by using its amide group and carbonyl group. Salicylic acid derivatives are effective quenchers of the fluorescence of riboflavin tetraacetate. It is appeared that salifylamide is the strongest quencher among them. The quenching effect is attributed to the formation of association dimer.

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Alleviating Effect of Salicylic Acid Pre-treatment on Soil Moisture Stress of Waxy Corn

  • Seo, Youngho;Ryu, Sihwan;Park, Jongyeol;Choi, Jaekeun;Park, Kijin;Kim, Kyunghi
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.3
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    • pp.213-217
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    • 2015
  • Soil moisture shortage can reduce yield of waxy corn because maize is one of the sensitive crops to the drought stress. Farmers cannot irrigate due to limited water resource and irrigating facilities although applying water is the most effective practice to solve the drought problem. The study was conducted to investigate the pre-treatment effect of salicylic acid on reducing drought damage of waxy corn (Zea mays L.). Salicylic acid at concentration of 0.2 mM was applied at seven-leaf stage or ten-leaf stage three times. Drought stress was imposed by withholding irrigation from 11 days before anthesis to 10 days after anthesis. Application of salicylic acid significantly increased ear length by 11.0~12.3% and yield by 8.8~11.3% compared with non-treated control, indicating that the drought injuries of waxy corn can be alleviated through pre-treatment of salicylic acid at the vegetative stage.

Alterations of Glutathione Peroxidase Patterns by Stressor Treatment in Rice Seedling Roots (스트레스 물질에 의한 벼 glutathione peroxidase 활성패턴 변화)

  • Kim, Yoon-Kyoung;Lee, Mi-Young
    • Applied Biological Chemistry
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    • v.48 no.1
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    • pp.53-59
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    • 2005
  • The effect of various stressors such as reductant ascorbic acid, signalling molecules (salicylic acid and methyl jasmonic acid), heavy metals $(NiCl_2,\;and\;MnSO_4)$ and NaCl on the glutathione peroxidase (GPX) activities and isoenzyme expression patterns were investigated in rice seedling roots. Total GPX activity increased according to the increase of ascorbic acid concentration. Prominent enhancement of GPX1 isozyme due to ascorbic acid contributed to the increase of total GPX activity. GPX showed different reactivity toward salicylic acid and methyl jasmonic acid. GPX activity increased at 0.1 mM salicylic acid, and then decreased thereafter. However, GPX increased gradually in a methyl jasmonic acid concentration-dependent manner, and 3 fold increase of GPX activity was found at 1 mM methyl jasmonic acid. Moreover, GPX1 isozyme increased according to the increase of salicylic acid, while GPX1 isozyme decreased according to the increase of methyl jasmonic acid. When metal ions were treated, GPX activity increased considerably according to the increase of $NiCl_2$ concentration, however, GPX activity increased about 2 fold at 0.5 mM $CuSO_4$ and then decreased. Enhancement of GPX1 isozyme contributed to the increase of total GPX activities in $NiCl_2-treated$ and $MnSO_4-treated$ rice seedlings. Total GPX activity increased 1.7 fold in response to 300 mM NaCl. Especially GPX2 isozyme showed gradual increase according to the increase of NaCl concentration.

Removal of Chloramphenicol, Salicylic Acid and Ketoprofen using Various Oxidation Processes : Oxidation Kinetic Evaluation (다양한 산화공정을 이용한 수중의 Chloramphenicol, Salicylic Acid 및 Ketoprofen 의약물질 제거 : 산화 동력학 평가)

  • Son, Hee-Jong
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.2
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    • pp.219-226
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    • 2010
  • In order to evaluate a removal characteristic of chloramphenicol, salicylic acid and ketoprofen according to dose of oxidants, $Cl_2$, $O_3$ and $O_3/H_2O_2$ are used as oxidants in this study. In case of that $Cl_2$ is used for oxidizing harmaceuticals, chloramphenicol, salicylic acid and ketoprofen is not removed entirely at $Cl_2$ dose rang of 0.5~5.0 mg/L for 60 min. However, removal tendency of salicylic acid is so obviously at $Cl_2$ dose higher than 1.0 mg/L. In addition, as $Cl_2$ dose and contact time increase, the removal rate of salicylic acid is enhanced. When $O_3$ is used as oxidant, chloramphenicol and ketoprofen is not eliminated at $O_3$ dose range of 0.2~2.0 mg/L. On the contrary, 30~70% of salicylic acid is removed at $O_3$ dose of 1.0~5.0 mg/L. Only 30% removal of salicylic acid is achieved at contact time of 5 min, however, the removal rate is enhanced remarkably at contact time over 10 min. In experiments using $O_3/H_2O_2$ as an oxidant, we can find that $O_3/H_2O_2$ is much more effective than $O_3$ only for removal of 3 pharmaceuticals, and the efficiency is raised according to increase of $H_2O_2$ dose. On reaction rate constant and half-life of 3 pharmaceuticals depending on $Cl_2$, $O_3$ and $O_3/H_2O_2$ dose, experiments using $O_3/H_2O_2$ show that oxidation of pharmaceuticals is less effective as the $H_2O_2/O_3$ ratio increases to above pproximately 1.0 related to reaction rate constant. An oxidation of salicylic acid by $Cl_2$ and $O_3$ particularly has a comparatively high reaction rate constant comparing $O_3/H_2O_2$, and thus salicylic acid is easily eliminated in oxidation processes.

Effects of Controlling the Pine Needie Gall Midaes by Salicylic Acid Content in Needles of Some Pinus spp. (소나무류(類) 침엽내(針葉內)의 salicylic acid에 의한 솔잎혹파리의 방제효과(防除效果))

  • Son, Doo-Sik;Eom, Tae-Jin;Choi, Chang-Ok;Zhang, Ruo Ming
    • Journal of Korean Society of Forest Science
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    • v.88 no.1
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    • pp.31-37
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    • 1999
  • The frequency of gall formation by pine needle gall midges ranged from 35% to 40% in both P. densiflora and P. thunbergii species. However, there was no indication of gall development from larva on both P. virgiana and P. rigida species suggesting that some specific compounds might play role in preventing gall formation of larva. The susceptible species to pine needle gall midges including P. densiflora and P. thunbergii contained a little salicylic acid under the free phenolic compound conditions while the resistant species against such insects including P. virginiana and P. rigida species contained about 37ppm to 50ppm of salicylic acid. Thus, this compound might have important roles in insect resistance. The contents of internal salicylic acid in the needles of susceptible pines increased from 9.5ppm to 20.6ppm after direct external irrigation of salicylic acid solution and flour treatment on roots. As a result, the frequency of gall formation decreased dramatically 17~19 times lower when compared with that of control. According to our results, the application of salicylic acid for effective prevention against insect damages should be performed before hatching eggs. The frequency of gall formation in the hybrid pines of P. thunbergii(susceptible) and P. virginiana(resistant) showed approximately 24% as average value of those in both species. In the case of specific individuals, it ranged from 2.8% to 11.5% in hybrids of both species. Therefore, effective production of insect resistant pines can be obtained through hybrids by crossing between susceptible and resistant species including P. thunbergii and P. virginiana by increasing internal salicylic acid contents of the needles.

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Development of Transparent Cleansing Water with Salicylic Acid and Capryloyl Salicylic Acid (살리실릭애씨드 및 카프릴로일살리실릭애씨드가 적용된 투명 클렌징 워터의 개발)

  • Yeo, Hye Lim;Park, Injeong;Jung, So Young;Lee, So Min;Kim, Hyung mook;Lee, Mi-Gi;Kwak, Byeong-Mun;Bin, Bum-Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.2
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    • pp.87-95
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    • 2022
  • This study is about the development of transparent cleansing water with one of the beta-hydroxy acids (BHA), salicylic acid, and capryloyl salicylic acid, which is one of the lipo-hydroxy acids (LHA). Transparent appearance was stabilized by increasing the solubility of lipophilic salicylic acid and capryloyl salicylic acid in water using ethanol, polyol, and sodium hydroxide, and supplementing suspension and deposition using a double micelle structure of two types of PEG surfactants. Cleansing water applied with this technology was developed, and makeup removing ability and skin texture improvement ability were confirmed using an optical camera and an image analyzer. This solubilization technology is proposed as a new approach of LHA, which has been difficult to apply due to its low solubility in water, and is expected to help in the development of new chemical peeling products.

Continuous-Flow Analysis for Determination of Nitrate Using Hydrazine-Copper Method in Plan (Hydrazine-Copper 방법을 이용한 연속흐름제어장치를 통한 식물체의 nitrate 분석)

  • Park, Yang-Ho;Park, So-Hyeon;Lee, Ju-Young;Jang, Byoung-Choon;Lee, Ki-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.4
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    • pp.204-208
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    • 2006
  • This study is to describe continuous-flow analysis (CFA) for the determination of nitrate using hydrazine-copper in plant material and to test precision of this method compared with that of methods, which are RQflex method and salicylic acid method. Samples were leaves of watermelon, cucumber, melon and tomato. Nitrate values measured by the RQflex method were greater than those measured by CFA or salicylic acid method. The correlation of nitrate values between those measured by CFA and salicylic acid method was $R^2=0.9671$, and those measured by CFA between those measured by RQflex method was $R^2=0.9739$. Recovery rate of nitrate added to tissue extract by CFA method was $99.7{\pm}0.25%$.

GUS Expression Driven by Promoter of AtSAGT1 Gene Encoding a Salicylic Acid Glucosyltransferase 1 in Arabidopsis Plants

  • Sendon, Pamella Marie;Park, Jong-Beum;Park, Soon-Ki;Song, Jong Tae
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.2
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    • pp.83-87
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    • 2013
  • AtSAGT1 encodes a salicylic acid (SA) glucosyltransferase enzyme that catalyzes the formation of SA glucoside and SA glucose ester. Here, the AtSAGT1 gene expression patterns were determined in AtSAGT1 promoter::GUS transgenic Arabidopsis plants. As a result, the factors regulating the induction of AtSAGT1 were identified as pathogen defense response, wound response, exogenous application of SA, and jasmonic acid treatment.

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