• Title/Summary/Keyword: relaxation parameters

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Stress Relaxation and Nonlinear Viscoelastic Model of PAN-PVC Copolymers (PAN-PVC 공중합체의 응력완화와 비선형 점탄성 모델)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.250-255
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    • 2010
  • From the three element non-Newtonian model of one non-Newtonian viscoelastic Maxwell elements and a elastic spring, the stress relaxation equation was derived. The various model parameters of this equation were evaluated by appling the experimental results of stress relaxation to the stress relaxation equation. The theoretical curves calculated from this model parameters agreed with the experimental stress relaxation curves. From the parameters of nonlinear viscoelastic model, the hole volume, fine structure, viscoelastic properties and mechanical properties of polymer fibers were studied. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The stress relaxation curves of the two types polyacrylonitrile-polyvinylchloride copolymer and another two types PVC monofilament fibers were obtained in air and water of various temperatures.

Self Diffusion Coefficients and Free Hole Volumes of Poly(acrylonitrile)-poly(vinyl chloride) Copolymers (Poly(acrylonitrile)-poly(vinyl chloride) 공중합체의 자체 확산 계수와 유동 자유 홀부피)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.245-250
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    • 2011
  • The self diffusions and hole volumes of amorphous region of poly(acrylonitrile)-poly(vinyl chloride) fibers were investigated by experiments of stress relaxation. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The flow parameters of filament fibers were obtained by applying the experimental stress relaxation curves to the theoretical equation of stress relaxation. From the flow parameters, the hole volumes, self diffusions, viscosities and thermodynamic parameters of solid polymers were calculated. It was observed that the flow parameters of these samples are directly related to the hole volumes, self diffusions and flow activation energies of flow segments.

Static Dielectric Constant and Relaxation Time for the Binary Mixture of Water, Ethanol, N. N-Dimethylformamide, Dimethylsulphoxide, and N, M-Dimethylacetamide with 20Hethoxyethanol

  • Ajay Chaudgari;N. M. More;S. C. Mehrotra
    • Bulletin of the Korean Chemical Society
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    • v.22 no.4
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    • pp.357-361
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    • 2001
  • Frequency spectra of the complex permittivity of 2-methoxyethanol (2-ME) with water, ethanol, dimethylsulphoxide (DMSO), N,N-dimethylformamide (DMF) and N,N-dimethylacatamide (DMA) have been determined over the frequency range of 10 MHz to 20 GHz at 25 $^{\circ}C$, using the Time domain reflectometry method, for 11 concentrations for each system. The static dielectric constant, dielectric constant at microwave frequency, relaxation time, excess dielectric parameters, and Kirkwood correlation factor have been determined. The relaxation in these systems within the frequency range can be described by a single relaxation time constant, using the Debye model. The parameters show a systematic change with the concentration.

PRECONDITIONED KACZMARZ-EXTENDED ALGORITHM WITH RELAXATION PARAMETERS

  • Popa, Constantin
    • Journal of applied mathematics & informatics
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    • v.6 no.3
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    • pp.757-770
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    • 1999
  • We analyse in this paper the possibility of using preconditioning techniques as for square non-singular systems, also in the case of inconsistent least-squares problems. We find conditions in which the minimal norm solution of the preconditioned least-wquares problem equals that of the original prblem. We also find conditions such that thd Kaczmarz-Extendid algorithm with relaxation parameters (analysed by the author in [4]), cna be adapted to the preconditioned least-squares problem. In the last section of the paper we present numerical experiments, with two variants of preconditioning, applied to an inconsistent linear least-squares model probelm.

Stress Relaxation of Poly(methyl acrylate)-Poly(acrylonitrile) Copolymers (Poly(methyl acrylate)-Poly(acrylonitrile) 공중합체의 응력완화)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.223-230
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    • 2012
  • The rheological parameters of poly(methyl acrylate)-poly(acrylonitrile) copolymers were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The experimentals of stress relaxation were carried out using the tensile tester with the solvent chamber. The determination of rheological parameters was performed from computer calculation. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusions and viscosities and activation energies of flow segments.

Self Diffusions and Rheological Properties of Polyamide Polymer Materials in Various Solvents (용매 환경에서의 폴리아미드 고분자 재료의 자체확산과 유변학적인 특성)

  • Kim, Nam Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1050-1059
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    • 2019
  • The self diffusion, hole volume, and flow thermodynamic parameters of polyamide fibers were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. The stress relaxation of polyamide filament fibers were carried out in air and various solvents at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model. It was observed that the rheological parameters of these polyamide filament fibers are directly related to the relaxation spectra, self diffusion, viscosities, and activation energies of flow segments.

Electron spin relaxation control in single electron QDs

  • Mashayekhi, M.Z.;Abbasian, K.;Shoar-Ghaffari, S.
    • Advances in nano research
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    • v.1 no.4
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    • pp.203-210
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    • 2013
  • So far, all reviews and control approaches of spin relaxation have been done on lateral single electron quantum dots. In such structures, many efforts have been done, in order to eliminate spin-lattice relaxation, to obtain equal Rashba and linear Dresselhaus parameters. But, ratio of these parameters can be adjustable up to 0.7 in a material like GaAs under high-electric field magnitudes. In this article we have proposed a single electron QD structure, where confinements in all of three directions are considered to be almost identical. In this case the effect of cubic Dresselhaus interaction will have a significant amount, which undermines the linear effect of Dresselhaus while it was destructive in lateral QDs. Then it enhances the ratio of the Rashba and Dresselhaus parameters in the proposed structure as much as required and decreases the spin states up and down mixing and the deviation angle from the net spin-down As a result to the least possible value.

ACCELERATION OF ONE-PARAMETER RELAXATION METHODS FOR SINGULAR SADDLE POINT PROBLEMS

  • Yun, Jae Heon
    • Journal of the Korean Mathematical Society
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    • v.53 no.3
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    • pp.691-707
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    • 2016
  • In this paper, we first introduce two one-parameter relaxation (OPR) iterative methods for solving singular saddle point problems whose semi-convergence rate can be accelerated by using scaled preconditioners. Next we present formulas for finding their optimal parameters which yield the best semi-convergence rate. Lastly, numerical experiments are provided to examine the efficiency of the OPR methods with scaled preconditioners by comparing their performance with the parameterized Uzawa method with optimal parameters.

Solvent Effect on Stress Relaxation of PET Filament Fibers and Self Diffusion of Crystallites

  • Nam Jeong Kim;Eung Ryul Kim;Sang Joon Hahn
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.468-473
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    • 1991
  • Viscoelastic properties of PET filament fibers on stress relaxation were investigated in the solvents of $H_2$O, 0.05% NaOH and 50% DMF using an Instron (UTM4-100 Tensilon) with solvent chamber. The theoretical stress relaxation equation derived by applying the Ree-Eyring's hyperbolic sine law to dashpot of three element non-Newtonian model was applied to the experimental stress relaxation curves, and the model parameters $G_1,G_2$, ${\alpha}$ and ${\beta}$ were obtained. By analyzing temperature dependency of the relaxation time, the values of activation entropy, activation enthalpy and activation free energy for flow in PET filament fiber were evaluated, the activation free energy being about 25.7 kcal/mol. The self diffusion coefficient and hole distance were obtained from parameters ${\alpha}$, ${\beta}$ and crystallite size in order to study the self diffusion and the orientation of crystallites in amorphous region and the effect of solvent.

Tempereture Dependent Dielectric Relaxation Study of Aniline in Dimethylsulphoxide and Dimethlformamide Using Time Domain Technique (시간분해기법을 이용한 디메틸 술폭사이드와 디메틸 포름아미드-아닐린용액에서 온도의존 유전이완에 관한 연구)

  • Chaudhari, Ajay;Patil, C.S.;Shankarwar, A.G.; Arbad, B.R.;Mehrotra, S.C.
    • Journal of the Korean Chemical Society
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    • v.45 no.3
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    • pp.201-207
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    • 2001
  • The dielectric relaxation study for aniline-dimethylsulphoxide (DMSO) and aniline-dim.ethylformamide(DMF) has been carried out using the Time domain reflectometry (TDR) technique, at different temperature and concentrations, in the frequency range of 10 MHz to 10 GHz. The dielectric parameters viz. static permittivity, relaxation time, the Kirkwood correlation factor, excess permittivity, excess inverse relaxation time and thermodynamic parameters have been obtained. The calibration method based on least squares fit method has been used. The dielectric parameters show systematic change with temperature and concentrations.

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