• Title/Summary/Keyword: reaction network

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The use of artificial neural networks in predicting ASR of concrete containing nano-silica

  • Tabatabaei, Ramin;Sanjaria, Hamid Reza;Shamsadini, Mohsen
    • Computers and Concrete
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    • v.13 no.6
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    • pp.739-748
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    • 2014
  • In this article, by using experimental studies and artificial neural network has been tried to investigate the use of nano-silica as concrete admixture to reduce alkali-silica reaction. If there are reactive aggregates and alkali of cement with enough moisture in concrete, a gel will be formed. Then with high reactivity between alkali of cement and existence of silica in aggregates, this gel will expand by absorption of water, and causes expansive pressure and cracks be formed. At the time passes, this gel will reduce both durability and strength of the concrete. By reducing the size of silicate to nano, specific surface area of particles and number of atoms on the surface will be increased, which causes more pozzolanic activity of them. Nano-silica can react with calcium hydroxide ($Ca(OH)_2$) and produces C-S-H gel. In this study, accelerated mortar bar specimens according to ASTM C 1260 and ASTM C 1567, with different mix proportions were prepared using aggregates of Kerman, such as: none admixture and plasticizer, different proportions of nano-silica separately. By opening the moulds after 24 hour and curing in water at $80^{\circ}C$ for 24 hour, then curing in (1N NaOH) at $80^{\circ}C$ for 14 days, length expansion of mortar bars were measured and compared. It was noted that, the lowest length expansion of a specimens shows the best proportion of admixture based on alkali-silica reactivity. Then, prediction of alkali-silica reaction of concrete has been investigated by using artificial neural network. In this study the backpropagation network has been used and compared with different algorithms to train network. Finally, the best amount of nano silica for adding to mix proportion, also the best algorithm and number of neurons in hidden layer of artificial neural network have been offered.

Study of in Silico Simulation Method for Dynamic Network Model in Lactic Acid Bacteria (Lactic Acid Bacteria의 동역학 네트워크 모델을 이용한 in Silico 모사방법 연구)

  • Jung, Ui-Sub;Lee, Hye-Won;Lee, Jin-Won
    • Journal of Institute of Control, Robotics and Systems
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    • v.11 no.10
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    • pp.823-829
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    • 2005
  • We have newly constructed an in silico model of fermentative metabolism for Lactococcus lactis in order to analyze the characteristics of metabolite flux for dynamic network. A rigorous mathematical model for metabolic flux has been developed and simulation researches have been performed by using GEPASI program. In this simulation task, we were able to predict the whole flux distribution trend for lactate metabolism and analyze the flux ratio on the pyruvate branch point by using metabolic flux analysis(MFA). And we have studied flux control coefficients of key reaction steps in the model by using metabolic control analysis(MCA). The role of pyruvate branch seems to be essential for the secretion of lactate and other organic byproducts. Then we have made an effort to elucidate its metabolic regulation characteristics and key reaction steps, and find an optimal condition for the production of lactate.

The Properties of ORMOSIL with Adding Organic Silanol in TEOS System(II) (고분자 Silanol을 첨가한 TEOS계의 ORMOSIL 특성(II))

  • 이동아;김구대;김현민
    • Journal of the Korean Ceramic Society
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    • v.30 no.1
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    • pp.34-40
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    • 1993
  • ORMOSIL was synthesized with inorganic precursor, TEOS and organic precursor, PDMS, and the variation of composite properties according to the concentration of HCl, solvent content and reaction time were studied. As the concentration of HCl increased, condensation reaction was well proceeded and more regularly distributed network was observed. Increase in reactivity was found with the amount of solvent, and composite had a tendency of forming more porous microstructure as reaction time was increased, which had no influence on the bonding degree.

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Preparation of Smectic Layered Polymer Networks Using Side Chain Liquid Crystalline Polymers Having Latent Reactive Monomeric Units

  • Oh, Young-Taek;Kim, Woo-Jin;Seo, Sang-Hyuk;Chang, Ji-Young
    • Macromolecular Research
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    • v.17 no.2
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    • pp.84-90
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    • 2009
  • We prepared side-chain liquid crystalline polymers comprising two monomeric units, one having a mesogenic side group that could form a smectic mesophase and the other having a phenolic group attached to the polymer backbone via a thermally reversible urethane bond. The urethane linkage between the isocyanate and phenol groups was stable at room temperature, but it cleaved to generate an isocyanate group when the temperature was increased. When annealed, the copolymers in their smectic mesophases became insoluble in common organic solvents, suggesting the formation of network structures. XRD analysis showed that the annealed polymers maintained their smectic LC structures. The crosslinking process probably proceeded via the reaction of the dissociated isocyanate groups. Some of the isocyanate groups would have first reacted with moisture in the atmosphere to yield amino groups, which underwent further reaction with other isocyanate groups, resulting in the formation of urea bonds. We presume that only polymer chains in the same layer were crosslinked by the reaction of the isocyanate groups, resulting in the formation of a layered polymer network structure. Reactions between the layers did not occur because of the wide layer spacing.

A Reaction Scheme supporting the Reliable Service in Mobile Networks (이동망에서 서비스 보장을 위한 대응방안)

  • 박상준
    • Journal of the Korea Society for Simulation
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    • v.13 no.2
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    • pp.65-73
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    • 2004
  • The capability to provide the network service must survive even if a significant network system element is disrupted. To sustain the network service under the system failure, network survivability mechanisms minimizing the impact of failures are needed. Also, since the mobile network has its unique characteristic, the survivability scheme for the vulnerability of the mobile network is required. This paper proposes a survivability scheme to support the reliable service of the wireless access point level (BS-base station system). By the survivability scheme, the mobile network can use an overlap BS of the cellular network architecture after a BS system failure. We analyze the performance of the proposed scheme using Markov model. Also, a computer simulation is used for the scheme analysis. The proposed scheme shows that the service of the mobile network can be provided under the BS system failure.

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Morphology Formation and Application of Interpenetrating Polymer Network (IPN) Materials (Interpenetrating Polymer Network(IPN)의 모폴로지 형성과 그 응용)

  • Kim, Sung-Chul
    • Polymer(Korea)
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    • v.29 no.1
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    • pp.1-7
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    • 2005
  • Interpenetrating polymer network (PN) is a mixture of network polymers. The characteristics of IPN material is the control of morphology during the IPN synthesis. By controlling the relative kinetics of chemical reaction (as well as gellation) and phase separation, the morphology of IPN can be controlled to obtain materials with nano-scale domain and also the co-continuous phase. Other important advantage is the fact that the morphology is permanent due to the presence of the physical interlocking between the networks. The combination of hydrophilic polyurethane and hydrophobic polystyrene in IPN form provides enhanced blood compatibility due to the co-existence of the hydrophilic and hydrophobic domains in nano-scale on the surface. The reaction temperature, reaction pressure and the degree of crosslinking were varied during the IPN synthesis and the morphology and blood compatibility of the resulting IPN materials were studied.

Linear and Hyperbranched Polymers via Electrophilic Substitution Reaction in Polyphosphoric $Acid/P_{2}O_{5}$

  • Choi, Ja-Young;Jeon, In-Yeop;Tan, Loon-Seng;Baek, Jong-Beom
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.195-195
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    • 2006
  • A superior electrophilic substitution reaction medium that is non-toxic, relatively less corrosive, and non-volatile electrophilic substitution reaction to afford high molecular weight linear and hyperbranched polyetherketones (PEK' s) was developed. The system has very strong driving force to give extra ordinary high molecular weight linear and hyperbranched PEK' s. The reaction medium was further extended to prepare various types of copolymers and covalently grafted polymers onto carbon nanotube (CNT) or carbon nanofiber (CNF). By using characteristic hydrophilic nature of the reaction medium, hyperbranched PEK' s could be synthesized from commercially available $A_3\;+\;B_2$ monomers without network formation via selective solubility of the monomers.

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Object Tracking Algorithm for Intelligent Robot using Sound Source Tracking Sensor Network (음원 센서네트워크를 이용한 지능형 로봇의 목표물 추적 알고리즘)

  • Jang, In-Hun;Park, Kyoung-Jin;Yang, Hyun-Chang;Lee, Jong-Chang;Sim, Kwee-Bo
    • Journal of Institute of Control, Robotics and Systems
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    • v.13 no.10
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    • pp.983-989
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    • 2007
  • Most of life thing including human being have tendency of reaction with inherently their own pattern against environmental change caused by such as light, sound, smell etc. Especially, a sense of direction often works as a very important factor in such reaction. Actually, human or animal lift that can react instantly to a stimulus determine their action with a sense of direction to a stimulant. In this paper, we try to propose how to give a sense of direction to a robot using sound being representative stimulant, and tracking sensors being able to detect the direction of such sound source. We also try to propose how to determine the relative directions among devices or robots using the digital compass and the RSSI on wireless network.

Response Analysis Model of Social Networks Using Fuzzy Sets and Feedback-Based System Dynamics (퍼지집합과 피드백 기반의 시스템 다이나믹스를 이용한 소셜네트웍의 반응 분석 모델)

  • Cho, Min-Ho
    • The Journal of the Korea institute of electronic communication sciences
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    • v.12 no.5
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    • pp.797-804
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    • 2017
  • A social network is a typical social science environment with both network and iteration characteristics. This research presents a reaction analysis model of how each node responds to social networks when given input such as promotions or incentives. In addition, the setting value of a specific node is changed while examining the response of each node. And we try to understand the reactions of the nodes involved. The reaction analysis model is constructed by applying various techniques such as unidirectional, fuzzy set, weighting, and cyclic feedback, so it can accommodate the complicated environment of practice. Finally, the implementation model is implemented using Vensim rather than NetLogo because it requires repetitive input, change of setting value in real time, and analysis of association between nodes.