• Title/Summary/Keyword: reaction direction

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Numerical Analysis of Molten Carbonate Fuel Cell Stack Using Computational Fluid Dynamics (CFD를 이용한 용융탄산염 연료전지 스택의 수치모사)

  • Lee, Kab-Soo;Cho, Hyun-Ho
    • Journal of the Korean Electrochemical Society
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    • v.8 no.4
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    • pp.155-161
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    • 2005
  • In this paper, commercial CFD program FLUENT v5.3 is used for simulation of MCFC stack. Besides using conservation equations included in FLUENT by default, mass change, mole fraction change and heat added or removed due to electrochemical reactions and water gas shift reaction are considered by adding several equations using user defined function. The stacks calculated are 6 and 25 kW class coflow stack which are composed of 20 and 40 unit cells respectively. Simulation results showed that pressure drop took place in the direction of gas flow, and the pressure drop of cathode side is more larger than that of anode side. And the velocity of cathode gas decreased along with the gas flow direction, but the velocity of anode gas increased because of the mass and volume changes by the chemical reactions in each electrodes. Simulated temperature profile of the stack tended to increase along with the gas flow direction and it showed similar results with the experimental data. Water gas shift reaction was endothermic at the gas inlet side but it was exothermic at the outlet side of electrode respectively. Therefore water gas shift reaction played a role in increasing temperature difference between inlet and outlet side of stack. This results suggests that the simulation of large scale commercial stacks need to consider water gas shift reaction.

Attitude and Direction Control of the Unicycle Robot Using Fuzzy-Sliding Mode Control (퍼지-슬라이딩모드 제어기를 이용한 외바퀴 로봇의 자세제어 및 방향제어)

  • Lee, Jae-Oh;Han, Seong-Ik;Han, In-Woo;Lee, Seok-In;Lee, Jang-Myung
    • Journal of Institute of Control, Robotics and Systems
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    • v.18 no.3
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    • pp.275-284
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    • 2012
  • This paper proposes an attitude and direction control of a single wheel balanced robot. A unicycle robot is controlled by two independent control laws: the mobile inverted pendulum control method for pitch axis and the reaction wheel pendulum control method for roll axis. It is assumed that both roll dynamics and pitch dynamics are decoupled. Therefore the roll and pitch dynamics are obtained independently considering the interaction as disturbances to each other. Each control law is implemented by a controller separately. The unicycle robot has two DC motors to drive the disk for roll and to drive the wheel for pitch. Since there is no force to change the yaw direction, the present paper proposes a method for changing the yaw direction. The angle data are obtained by a fusion of a gyro sensor and an accelerometer. Experimental results show the performance of the controller and verify the effectiveness of the proposed control algorithm.

Analysis of the Behavior of Tubular-Type Equipment for Nuclear Waste Treatment : Sensitivities of the Parameters Affecting Mass Transfer Yield (방사성폐기물의 화학처리공정에 사용되는 유동관식 장치의 해석 : 물질전달 수율에 미치는 매개변수들의 민감도)

  • Yoo, Jae-Hyung;Lee, Byung-Jik;Shim, Joon-Bo;Kim, Eung-Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.91-99
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    • 2007
  • It was intended in this study to investigate the effects of various parameters on the chemical reaction or mass transfer yield in a tubular-type nuclear waste treatment equipment. Since such equipments, as a tubular reactor, multistage solvent extractor, and adsorption column, accompany chemical reaction or mass transfer along the fluid-flowing direction, mathematical modeling for each equipment was carried out first. Then their behaviors of the chemical reaction or mass transfer were predicted through computer simulations. The inherent major parameters for each equipment were chosen and their sensitivities. affecting the reaction or mass transfer yield were analyzed. For the tubular reactor, the effects of axial diffusion coefficient and reaction rate constant on the reaction yield were investigated. As for the multistage solvent extractor, the backmixing of continuous phase and the distribution coefficient between fluid and solvent were considered as the major parameters affecting the extraction yield as well as concentration profiles throughout the axial direction of the extractor. For the adsorption column, the equilibrium constant between fluid and adsorbent surface, and the overall mass transfer coefficient between the two phases were taken as the major factors that affect the adsorption rate.

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Characteristics of Methanol-O2 Catalytic Burner according to Oxidant Supply Method (산화제 공급 방법에 따른 메탄올-산소 촉매연소기 특성)

  • JI, HYUNJIN;LEE, JUNGHUN;CHOI, EUNYEONG;YANG, SUNGHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.1
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    • pp.82-88
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    • 2020
  • Recently, a fuel reforming plant for supplying high purity hydrogen has been studied to increase the operation time of underwater weapon systems. Since steam reforming is an endothermic reaction, it is necessary to continuously supply heat to the reactor. A fuel reforming plant needs a methanol-O2 catalytic burner to obtain heat and supply heat to the reformer. In this study, two types of designs of a catalytic burner are presented and the results are analyzed through the experiments. The design of the catalytic burner is divided into that the O2 supply direction is perpendicular to the methanol flow direction (Design 1) and the same as the methanol flow direction (Design 2). In case of Design 1, backfire and flame combustion occurred in the mixing space in front of the catalyst, and in the absence of the mixing space, combustion reaction occurred only in a part of the catalyst. For above reasons, Design 1 could not increase the exhaust gas temperature to 750℃. In Design 2, no flashback and flame combustion were observed, the exhaust gas could be maintained up to 750℃. However, the O2 distributor was exposed to high temperatures, resulting in thermal damage.

Geometric Characteristics of Methane Steam Reforming with Low Temperature Heat Source (중저온 열원에 의한 메탄 수증기 개질의 형상 인자에 따른 특성)

  • Shin, Gahui;Yun, Jinwon;Yu, Sangseok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.12
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    • pp.793-799
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    • 2016
  • In a hybrid fuel cell system, low-temperature reforming technology, which uses waste heat as a heat source, is applied to improve system efficiency. A low temperature reformer is required to optimize geometry in low thermal conditions so that the reformer can achieve the proper methane conversion rate. This study analyzed internal temperature distributions and the reaction patterns of a reformer by considering the change of the shape factor on the limited heat supply condition. Unlike the case of a high temperature reformer, analysis showed that the reaction of a low temperature reformer takes place primarily in the high temperature region of the reactor exit. In addition, it was confirmed that the efficiency can be improved by reducing the GHSV (gas hourly space velocity) or increasing the heat transfer area in the radial direction. Through reacting characteristic analysis, according to change of the aspect ratio, it was confirmed that a low temperature reformer can improve the efficiency by increasing the heat transfer in the radial direction, rather than in the longitudinal direction.

Electrical Conduction in Y2O3-doped SrZrO3-metal Electrode System (Y2O3가 도핑된 SrZrO3-금속전극계의 전기전도 특성)

  • Baek, Hyun-Deok;Lee, Poong-Hun
    • Journal of the Korean Ceramic Society
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    • v.39 no.4
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    • pp.367-376
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    • 2002
  • Electrical conduction in $SrZr_{1-x}Y_xO_{3-\delta}$((x=0.05, 0.10)-metal electrode system was investigated by impedance spectroscopy and two-probe d.c. conductivity measurement. Electrode conductivity in anodic direction varies with $P_W^{1/2}$( and that in cathodic direction with $P_{O2}^{1/4}$ in oxidizing atmosphere. In hydrogen atmosphere, the addition of water vapor increased the electrode conductivity both in anodic and cathodic direction. Increasing dopant concentration from 5 to 10% showed a more than four times increase in anodic conduction as well as bulk conduction of the solid electrolyte. This observation implies that unfilled oxygen vacancy concentration increases rapidly as the dopant content increases in humid atmosphere. The activation energy of cathodic conduction in Pt and Ag electrode was nearly same below $800^{\circ}C$ which means the rate of cathodic reaction is determined by the reaction in the electrolyte surface rather than on the metal electrodes.

Design of a Novel 3D Printed Harmonic Drive and Analysis of its Application (3D 프린팅 기법을 이용한 하모닉 드라이브(Harmonic Drive) 설계 및 응용 분석)

  • Kim, Sang-Hyun;Byeon, Chang-Sup;Lee, Chul-Hee
    • Tribology and Lubricants
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    • v.38 no.1
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    • pp.27-31
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    • 2022
  • Harmonic drives have attracted increasing attention with the development of materials, parts, and related equipment. Harmonic drives exhibit high deceleration, high accuracy, and light weight. The stiffness of flexible splines according to the radial load is studied using a commercial FEM program to design the structure of the flexible spline and finite element to improve the weight and price competitiveness of harmonic drives. In addition, several studies have measured and compared friction coefficients based on 3D printed tread patterns. However, owing to the characteristics of plastic materials, a decrease in stiffness in the radial direction is inevitable. To prevent a decrease in stiffness in the radial direction, we designed and manufactured flex splines with a wrinkle shape. Through structural analysis, the reaction force and stiffness in the radial direction were determined. In addition, the maximum angle of the mound was derived by theoretical calculations, and the performance of the harmonic drive was compared with the results obtained in the mound experiment. Structural analysis shows that the shape of wrinkles decreased the stress and reaction force and increased the safety factor in comparison with that of the circular shape. During performance verification through continuous experiments, the developed harmonic drive showed continuous performance similar to that of an actual tank model. It is expected that the flex spline with a compliant spring and wrinkle shape will prevent a decrease in the radial stiffness.

Study on the Rational Analysis Methods and Seismic Responses of Curved Bridges (곡선교의 합리적인 지진해석기법 및 지진응답특성에 관한 연구)

  • Kim, Sang Hyo;Cho, Kwang Il;Park, Byung Kyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6A
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    • pp.955-963
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    • 2006
  • As the geometrical characteristic of the curved bridge, the seismic response of curved bridges are different from straight bridges. This study analyzed the seismic response of the curved bridges considering diverse factors such as radius of curvature, direction of seismic load and support condition. The improved simple modeling of the curved bridge for seismic analysis is proposed, and it is compared with the detail modeling in order to verify the simple modeling. Three simply supported curved bridges and six 3-span continuous bridges are selected for seismic analysis. The behavior of curved bridges are evaluated in terms of the displacement and the force at supports and piers under seismic load applied in various directions. The results of this study show that upward reaction force may appear in simply supported curved bridge under seismic load. And continuous curved bridges are affected by the direction of the seismic load.

Effects of Reagent Rotation on Stereodynamics Information of the Reaction O(1D)+H2 (v = 0, j = 0-5) → OH+H: A Theoretical Study

  • Kuang, Da;Chen, Tianyun;Zhang, Weiping;Zhao, Ningjiu;Wang, Dongjun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2841-2848
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    • 2010
  • Quasiclassical trajectory (QCT) method has been used to investigate stereodynamics information of the reaction $O(^1D)+H_2{\rightarrow}\;OH$+H on the DK (Dobbyn and Knowles) potential energy surface (PES) at a collision energy of 23.06 kcal/mol, with the initial quantum state of reactant $H_2$ being set for v = 0 (vibration quantum number) and j = 0-5 (rotation quantum number). The PDDCSs (polarization dependent differential cross sections) and the distributions of P($\theta_r$), P($\phi_r$), P($\theta_r$, $\phi_r$) have been presented in this work. The results demonstrate that the products are both forward and backward scattered. As j increases, the backward scattering becomes weaker while the forward scattering becomes slightly stronger. The distribution of P($\theta_r$) indicates that the product rotational angular momentum j' tends to align along the direction perpendicular to the reagent relative velocity vector k, but this kind of product alignment is found to be rather insensitive to j. Furthermore, the distribution of P($\phi_r$) indicates that the rotational angular momentum vector of the OH product is preferentially oriented along the positive direction of y-axis, and such product orientation becomes stronger with increasing j.

Ground Reaction Force Characteristics During Forward and Backward Walking Over 20 Degree Ramp (20° 경사로 앞.뒤 보행 동작 시 지면반력의 형태 비교 분석)

  • Chae, Woen-Sik
    • Korean Journal of Applied Biomechanics
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    • v.18 no.3
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    • pp.71-82
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    • 2008
  • W. S. CHAE, Ground Reaction Force Charateristics During Forward and Backward Walking Over 20 Degree Ramp. Korean Journal of Sport Biomechanics, Vol. 18, No. 3, pp. 71-82, 2008. The purpose of this study was to compare GRF characteristics during forward and backward walking over 20 degree ramp. Temporal parameters, GRFs, displacement of center of pressure (DCP), and loading and decay rates were determined for each trial. The results showed that the vertical GRF in BD during RTO was significantly greater than those found in FU. This reults indicated that GRF patterns may be changed by different walking conditions and altering position of ankle, knee, and center of mass throughout the walking cycle. The DCP during $RHC_2$-LHC in antero-posterior direction for downward was smaller than the corresponding value for upward condition. It' seems that the ankle and knee joints are locked in an awkward fashion at the toe contact to compensate for imbalance. Reducing the magnitude of loading rate can be achieved by walking in the backward direction. Accordingly, the results can be a benefit if one is suffering from an impact-type injury.