• Membrane Journal
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• v.32 no.1
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• pp.74-82
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• 2022

The objective of this work was to investigate the gas permeation properties of CO₂ and CH₄ for PEBAX^®/TS-530 hybrid membranes and compare with pure PEBAX^®-1657 membrane. With FTIR and XRD it was possible to confirm that TS-530 was dispersed well in PEBAX^® matrix. Compared with pure PEBAX^® membrane, ideal separation factor for PEBAX^®/TS-530 (10 wt%) hybrid membrane was enhanced a little. As the amount of TS-530 was increased, the gas permeability coefficients of both CO₂ and CH₄ were increased, while the ideal separation factor was decreased. This results were explained by the reduction of crystallinity of polyamide block and interchain distance caused by introduction of inorganic nanoparticles. And fumed silica might tend to agglomerate, resulting in forming nonselective nanogaps in the hybrid materials, thus the diffusivity would be enhanced at the expense of diffusivity selectivity.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1284-1284
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• 2001

The transesterification of molten ethylene/vinylacetate (EVA) copolymers by octanol as a reagent and sodium methoxide as a catalyst in an extruder has been monitored by on-line near infrared (NIR) spectroscopy. A total of 60 NIR spectra were acquired for 37 minutes with the last spectrum recorded 31 minutes after the addition of octanol and catalyst was stopped. The experimental spectra show strong baseline fluctuations which are corrected for by multiplicative scatter correction (MSC). The chemometric methods of orthogonal projection approach (OPA) and multivariate curve resolution (MCR) were used to resolve the spectra and to derive concentration profiles of the species. The detailed analysis reveals the absence of completely pure variables that leads to small errors in the calculation of pure spectra. The initial estimation of a concentration that is necessary as an input parameter for MCR also presents a non-trivial task. We obtained results that were not ideal but applicable for practical concentration control. They enable a fast monitoring of the process in real-time and resolve the spectra of the EVA copolymer and the ethylene/vinyl alcohol (EVAL) copolymer to be very close to the reference spectra. The chemometric methods used and the decomposed spectra are discussed in detail.

• Advances in nano research
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• v.5 no.3
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• pp.203-214
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• 2017

In this study we present the reaction mechanism of $Cu_2ZnSnSe_4$ (CZTSe) nanoparticles synthesized by microwave-assisted chemical synthesis. We performed reactions every 10 minutes in order to identify different phases during quaternary CZTSe formation. The powder samples were analyzed by x-ray diffraction (XRD), Raman spectroscopy, energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The results showed that in the first minutes copper phases are predominant, then copper and tin secondary phases react to form ternary phase. The quaternary phase is formed at 50 minutes while ternary and secondary phases are consumed. At 60 minutes pure quaternary CZTSe phase is present. After 60 minutes the quaternary phase decomposes in the previous ternary and secondary phases, which indicates that 60 minutes is ideal reaction time. The EDS analysis of pure quaternary nanocrystals (CZTSe) showed stoichiometric relations similar to the reported research in the literature, which falls in the range of Cu/(Zn+Sn): 0.8-1.0, Zn/Sn: 1.0-1.20. In conclusion, the evolution pathway of CZTSe synthesized by this novel method is similar to other synthesis methods reported before. Nanoparticles synthesized in this study present desirable properties in order to use them in solar cell and photoelectrochemical cell applications.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.2
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• pp.122-133
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• 2001

Pool boiling heat transfer coefficients(HTCs) of HFC32/HFC134a, HFC125/HFC134a, HFC32/HFC125 and HFC32/HFC125/HFC134a were measured on a horizontal smooth tube. The experimental apparatus was specially designed to simulate the real heat transfer tube with the use of the secondary fluid of water. Data were taken in the order of decreasing heat flux starting at 80kW/$m^2\; and\; ending\; at\; 5kW/m^2$ in the pool temperature at $7^{\circ}C$. Test results showed that HTCs of these mixtures were 11~38% lower than those of ideal HTCs calculated by a linear mixing rule with pure fluids、 HTCs. Experimental data were compared with Stephan & Korner, Thome, Schlunder, Thome & Shakir、s correlations only to find that those correlations were not satisfactory for all fluids. Hence, a new correlation based on the present data was proposed which could be applied even to the ternary mixture. The correlation predicts the degradation of HTCs of mixtures well, showing a mean deviation of less than 15% for all the mixture data.

• Journal of the Korean Society of Safety
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• v.20 no.2 s.70
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• pp.162-168
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• 2005

The lower flash points for the n-propanol+n-decane flammable mixture were measured by the Tag open-cup apparatus(ASTM D 1310). The experimental results of mixture exhibited the lower flash point than those of pure component in the flash point versus composition curve. The experimental value of the minimum flash point is $27^{\circ}C$ at a mole fraction of n-propanol of 0.71, and the flash point of n-propanol was $28^{\circ}C$. The experimentally obtained data were compared with the values that had been calculated by use of the prediction model, which assumes an ideal solution, and the flash point prediction models based on the van Laar equation were used to estimate the activity coefficients. The predictive curve based on an ideal solution deviated from the experimental data for this system. The experimental results demonstrate a close agreement with the predicted curves, which used the van Laar equation. The average absolute deviation(A.A.D.) from using the van Lau equation is $0.83^{\circ}C$. The methodology proposed here in this paper can thus be applied to incorporate an inherently safer design for chemical processes, such as determining safe storage and handling conditions for flammable solutions.

• Journal of Korean Academy of Nursing
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• v.25 no.1
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• pp.88-98
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• 1995

The Fluid and electrolytes balance in the body is of critical importance in maintaining good health. When the fluid and electrolyte imbalance is present, patients are in great danger. They must be assessed immediately by a nurse so that appropriate treatment can be started as soon as possible. Patients' fluid intake and output records contain highly important information for the diagnosis and treatment of fluid imbalance, but, these records are often inaccurate and the method of recording the fluid intake is not universal for every hospital. Be-cause they are few quantitative measurements of a patient's hydration, the need to improve the accuracy of fluid intake records is very important. However, very few studies have been done to investigate the accuracy of measurements of patients' fluid intake and output. The purpose of this study was to investigate the methods used for calculation of fluid intake which is most similar to fluid output in normal adults and hospitalized patients. This study focused on three different calculation methods for fluid intake and compared these to fluid output and developed suggestions as to the ideal way to record fluid in-take. Data for 43 hospitalized patients and 37 normal adults were analyzed. The findings of this study are as follows ; 1) In normal adults, the daily intake of water which enteres by the oral route was 2415m1 (the first method of calculation). The daily intake of water in the form of pure water or some other beverage was 1365m1 (the third method of calculation) The daily intake of water including fresh fruits and vegetables, rice, porridges, and Me m which have water content more than 80% were 2186m1 (the second method of calculation). 2) The urine output of the normal adults was 1350m1. This apprroximates the amount of fluid an adult takes in the form of pure water. 3) In patient group, the total intake of water was 2550m1 (the first method of calculation). The in-take of water in the form of pure water or as some other beverage and IV fluid was 1661m1 (the third method of calculation). The daily in-take of water including foods which have high water content was 2356m1 (the second method of calculation). 4) The urine output of the patient's group was 1728m1. This approximates the amount of fluid an adult takes in the form of pure water. 5) Investigation of the method of calculation of the patient fluid intake showed that among the 31 hospitals studied, only eight use the third method of calculation which reflects the most close value to urine output. From the results obtained in this study, it was indicated that the amount of fluid taken in the form of pure water reflects the most close value to urine output. Therefore, it can be suggested that the third method of calculation which includes water in-take only in the form of pure water or beverage should be used as patients' fluid intake record.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.26 no.7
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• pp.315-321
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• 2014

In this study, external condensation heat transfer coefficients (HTCs) of two non-azeotropic refrigerant mixtures of HFC32/HFC152a at various compositions were measured on both 26 fpi low-fin and Turbo-C enhanced tubes, of 19.0 mm outside diameter. All data were taken at the vapor temperature of $39^{\circ}C$, with a wall subcooling of 3~8 K. Test results showed that the HTCs of the tested mixtures on the enhanced tubes were much lower than the ideal values calculated by mass fraction weighting of the pure component HTCs. Also, the reduction of HTCs due to the diffusion vapor film was much larger than that of a plain tube. Unlike HTCs of pure fluids, HTCs of the mixtures measured on enhanced tubes increased, as the wall subcooling increased, which was due to the sudden break-up of the vapor diffusion film with an increase in wall subcooling. Finally, the heat transfer enhancement ratios for mixtures were found to be much lower, than those of pure fluids.

• Bulletin of the Korean Mathematical Society
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• v.56 no.2
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• pp.439-450
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• 2019

Let R be a ring with unity. Given modules $M_R$ and $_RN$, $M_R$ is said to be absolutely $_RN$-pure if $M{\otimes}N{\rightarrow}L{\otimes}N$ is a monomorphism for every extension $L_R$ of $M_R$. For a module $M_R$, the subpurity domain of $M_R$ is defined to be the collection of all modules $_RN$ such that $M_R$ is absolutely $_RN$-pure. Clearly $M_R$ is absolutely $_RF$-pure for every flat module $_RF$, and that $M_R$ is FP-injective if the subpurity domain of M is the entire class of left modules. As an opposite of FP-injective modules, $M_R$ is said to be a test for flatness by subpurity (or t.f.b.s. for short) if its subpurity domain is as small as possible, namely, consisting of exactly the flat left modules. Every ring has a right t.f.b.s. module. $R_R$ is t.f.b.s. and every finitely generated right ideal is finitely presented if and only if R is right semihereditary. A domain R is $Pr{\ddot{u}}fer$ if and only if R is t.f.b.s. The rings whose simple right modules are t.f.b.s. or injective are completely characterized. Some necessary conditions for the rings whose right modules are t.f.b.s. or injective are obtained.

• Journal of the Korean housing association
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• v.16 no.4
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• pp.91-100
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• 2005

This study aims to find the architectural concepts of Song-Sun and the spatial structure of the Myonangjong through kasa, sijo, and Chinese poems. He considered his place as a ideal place to dwell a secluded life which is surrounded by mountains, and opened to a field in front. That places is connected with geomancy or Feng Sui, and he attached great importance to placeness of the Myonangjong as a pavilion. As his place was called 'tyoro samgan', his place should be simple, and that was harmonized with nature. He regarded his place as a part of the outside space and its surrounding nature. As the pen name of Myonangjong shows that his way of life is very pure so he need not disgrace against the earth and the sky, he considered his building as a place of embodying the Confucian great law of heaven and earth. Myonangjong has a concentric circle structure of the scenery which is viewed panoramically along with the visual direction.

• Journal of the Korean Chemical Society
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• v.61 no.4
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• pp.139-142
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• 2017

Ethene ($C_2H_4$), which is produced in plants as they mature, was used to study its photoacoustic properties using photoacoustic spectroscopy. Detection of trace amounts, with $N_2$ gas, of $C_2H_4$ gas was also applied. The gas was tested in various conditions-temperature, concentration of the gas, gas cell length, and power of the laser- to determine their effect on the photoacoustic signal, the ideal conditions to detect trace gas amounts, and concentration of $C_2H_4$ produced by an avocado and a banana. A detection limit of 10 ppm was determined for pure $C_2H_4$. A detection of 5% and 13% (by volume) concentration of $C_2H_4$ was produced for a ripening avocado and banana, respectively, in closed space.