• 펄프종이기술
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• 제48권1호
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• pp.100-110
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• 2016

Alkaline Peroxide Mechanical Pulping (APMP) of Pinus densiflora harvested from domestic mountains was explored. APMP contributes to various advantages including pulp quality, elimination of the need for a bleaching process, and energy savings. Sequential treatment of impregnation of bleaching chemicals and refining not only overcome the concern of alkaline darkening of wood chips during chemical impregnation, but it also brightens the chips to the desired brightness levels suitable for writing and printing papers. APMP pulping from Pinus densiflora was greatly influenced by the dosage levels of hydrogen peroxide and sodium hydroxide. Alkaline peroxide treatment was carried out by applying one of three levels of hydrogen peroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips) and one of three levels of sodium hydroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips). Other chemicals including a peroxide stabilizers and metal chelation were constantly added for all treatments. Chemical treatment with a liquor-to-wood ration of 9:1 was carried out in a laboratory digestor. Compared to BTMP, APMP pulping displayed outstanding characteristics including the less requirement of refining energy, the better improvement of tensile strength, the more reduction of shives, and the greater increase of pulp brightness. In particular, when 4.5% of hydrogen peroxide with impregnation during 90 minutes was used, the brightness of APMP reached 64.9% ISO. Even though bulk of APMP was decreased with the increase of sodium hydroxide, a better and improved balance could be achieved between optical and strength properties. The spent liquor obtained from the discharge of the impregnation process at the dosage level of 4.5% hydrogen peroxide exhibited an equal level of residual peroxide with BTMP. In conclusion, APMP pulping showed successful results with Pinus densiflora due to its better response to the development of optical and physical properties compared to TMP pulping.

• 공업화학
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• 제9권4호
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• pp.529-535
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• 1998

탈묵공정에서 고지 배합처리, 온도, 양품 배합처리 등의 해리 공정조건 변동에 의한 탈묵펄프의 영향을 조사하였다. 실험계획법으로써 탈묵펄프에 주된 영향을 미치는 유의한 인자를 선정하였으며, 통계분석기법 중 하나인 분산분석 및 다중비교를 통해 공정조건의 최적수준조합을 결정하고 이에 따른 백색도 및 강도적 특성의 추정치 및 신뢰구간을 구하였다. 백색도는 $Na_2SiO_3$ 2.0%, $H_2O_2$ 0.5%, 고지 배합처리 (국내신문고지 : 수입신문고지 : 매거진 = 40 : 30 : 30 wt %)의 조건에서 가장 높은 추정치 50.5%와 90% 신뢰구간 (49.0, 52.0)을 얻을 수 있었다. 인장지수는 $H_2O_2$ 0.5%, 해리 온도 $50^{\circ}C$의 조건에서 가장 높은 추정치 $35.7N{\cdot}m/g$과 90% 신뢰구간 (34.6, 36.6)을 얻을 수 있었다. 파열지수는 계면활성제 0.1%, 해리 온도 $50^{\circ}C$의 조건에서 가장 높은 추정치 $0.129kPa{\cdot}m^2/g$과 90% 신뢰구간 (0.125, 0.133)을 얻을 수 있었다.

• Journal of the Korean Wood Science and Technology
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• 제17권2호
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• pp.84-94
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• 1989

• Journal of the Korean Wood Science and Technology
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• 제8권3호
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• pp.23-29
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• 1980

• Journal of the Korean Wood Science and Technology
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• 제10권4호
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• pp.76-88
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• 1982

• 보존과학회지
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• 제5권1호
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• pp.3-10
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• 1996

In this study, bast fibers, woody parts and whole woods were pulped separately by alkali, alkali-hydrogen peroxide and sulfomethylated processes and their papermaking characteristics for the special Hanji were evaluated. Also properties of new Hanji products obtained from mixed stocks of various ratios were discussed. Solfomethylated pulps were shown higher brightness and sheet strengths than those from alkali and alkali-peroxide pulps. On the mechanical properties of Hanjis mixed with bast-and woody-parts pulps, and with bast and whole stem pulps, handsheet strengths were decreased with the increasing contents of woody and whole stem pulps. Various Hanjis could make by various mixing of separated cooked Pulps. Especially an excellant Hwaseonji(calligrapy Paper) could be made by one stage cooking of whole stem of paper mulberry by sulfomethylated pulping method.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2011년도 추계학술발표회 논문집
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• pp.143-149
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• 2011

In recent, many forest residues have been generated by the National Forest Management Operation. Unfortunately, most of the forest residues are supposed to be used as raw materials for burning fuels like wood pellets. In this study, we investigated whether or not this forest biomass mixed in various ages and species could be used as raw materials for making kraft pulps in a view of optical properties.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2001년도 추계학술발표논문집
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• pp.3-8
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• 2001

• Journal of the Korean Wood Science and Technology
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• 제9권1호
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• pp.13-18
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• 1981

• 펄프종이기술
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• 제29권2호
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• pp.60-64
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• 1997