• Title/Summary/Keyword: process byproduct

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Colorants Characteristics and Fastness Analysis of Lotus Seedpods (Lotus seedpods의 색소 특성과 견뢰도 분석)

  • Lim, Jee-Young;Jang, Jeong-Dae
    • Fashion & Textile Research Journal
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    • v.16 no.3
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    • pp.492-498
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    • 2014
  • Lotus(Nelumbo nucifera gaertn) is intimate plant to many people that it has clean and noble characteristics despite growth in the mud. Especially Lotus seedpods, byproduct of lotus, are rich in oligometric procyanidins and could be a new source of procyanidins. Procyanidins, also known as condensed tannins, are a class of polyphenols. In other words lotus seedpod contains plenty of tannins. Commonly tannins colorants could increase adsorption and fastness properties in fabric dyeing. This study was made to investigate colorants characteristics of lotus seedpod and various colorfastness properties of dyed silk fabrics. The wavelength of maximum absorption of lotus seedpod solution appeared at 273.5 nm from UV-vis spectrophotometer. From the results of FT-IR spectra measurements, IR absorption band of lotus seedpod colorants appeared at $3415cm^{-1}$, $2900cm^{-1}$ and $1620cm^{-1}$ by tannin structure. And tannin ingredient contents was the highest at pH 9 and flavonoid at pH 11. Lotus seedpod colorants showed relatively good affinity at pH 3 on silk fabrics and optimum dyeing temperature and time for silk was for 50 min, at $80^{\circ}C$. K/s of Light fastness according to different washing method was the highest at process including ironing and ${\Delta}E$ was the lowest. All of fastness(Light rubbing laundering perspiration dry cleaning) showed excellent results over 4 or 4-5 grades.

Size, Shape, and Crystal Structure-dependent Toxicity of Major Metal Oxide Particles Generated as Byproducts in Semiconductor Fabrication Facility (반도체 가공 작업환경에서 부산물로 발생되는 주요 금속산화물의 입자 크기, 형상, 결정구조에 따른 독성 고찰)

  • Choi, Kwang-Min
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.26 no.2
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    • pp.119-138
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    • 2016
  • Objectives: The purpose of this study is to review size, shape, and crystal structure-dependent toxicity of major metal oxide particles such as silicon dioxide, tungsten trioxide, aluminum oxide, and titanium dioxide as byproducts generated in semiconductor fabrication facility. Methods: To review the toxicity of major metal oxide particles, we used various reported research and review papers. The papers were searched by using websites such as Google Scholar and PubMed. Keyword search terms included '$SiO_2$(or $WO_3$ or $Al_2O_3$ or $TiO_2$) toxicity', 'health effects $SiO_2$(or $WO_3$ or $Al_2O_3$ or $TiO_2$). Additional papers were identified in references cited in the searched papers. Results: In various cell lines and organs of human and animals, cytotoxicity, genotoxicity, hepatoxicity, fetotoxicity, neurotoxicity, and histopathological changes were induced by silicon dioxide, tungsten trioxide, aluminium oxide, and titanium dioxide particles. Differences in toxicity were dependent on the cell lines, organs, doses, as well as the chemical composition, size, surface area, shape, and crystal structure of the particles. However, the doses used in the reported papers were higher than the possible exposure level in general work environment. Oxidative stress induced by the metal oxide particles plays a significant role in the expression of toxicity. Conclusions: The results cannot guarantee human toxicity of the metal oxide particles, because there is still a lack of available information about health effects on humans. In addition, toxicological studies under the exposure conditions in the actual work environment are needed.

Study on the Application of Inorganic Byproduct from Fertilizer Manufacture Process as an Alternative Filler (폐기 무기 부산물의 제지용 충전제로의 활용성 평가 연구)

  • Lee, Ji-Young;Lee, Eun-Kyu;Lee, Do-Yeob;Yun, Kyeong-Tae;Sung, Yong-Joo;Choi, Jae-Sung;Kim, Da-Mi;Kim, Beong-Ho;Lim, Gi-Baek
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.1
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    • pp.52-57
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    • 2012
  • In this study, we investigated the possible use of a new inorganic material as alternative filler in the paper industry. The inorganic material is a mineral composed of calcium sulfate, that is generated when manufacturing phosphate fertilizer. The inorganic material was dehydrated by the thermal treatment to $200^{\circ}C$, $500^{\circ}C$, $700^{\circ}C$, and $900^{\circ}C$ to prepare white filler powders. Their basic properties, including color, particle shape, elements, and average particle size were identified. To determine the effect of new inorganic filler on paper's physical properties and strength, handsheets were prepared from HwBKP, SwBKP, and thermal treated inorganic fillers. Handsheets' ISO brightness, opacity, bulk, breaking length, and stiffness were measured. Results confirmed that thermal treated inorganic filler could be beneficial to the bulk and opacity of paper while maintaining higher level of breaking length and stiffness that is achieved using talc.

Decomposition of Hexahydro-1,3,5-trinitro-1,3,5-triazine by Gamma Ray Irradiation (감마선 조사에 의한 hexahydro-1,3,5-trinitro-1,3,5-triazine(RDX)의 분해)

  • Lee, Byungjin;Lee, Myunjoo;Kim, Yuri
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.6
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    • pp.731-741
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    • 2004
  • The purpose of this study was to evaluate the potential of a gamma ray irradiation to decompose hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in an aqueous solution. The decomposition reaction of RDX by gamma ray irradiation was a first-order kinetic over the applied initial concentrations (10-40mg/L). The dose constant was strongly dependent on the initial concentration of the RDX. The removal of RDX was more efficient at pH below 3 and at pH above 11 than at neutral pH (pH 5-9). The required irradiation dose to remove 99% of the RDX (40mg/L) was 4, 8 and 1 kGy, at pH 2, 7 and 13, respectively. The dose constant was increased by two folds and over twelve folds at pH 2 and 13, respectively, when compared with that at pH 7. When an irradiation dose of 20 kGy was applied, the removal efficiencies of TOC were 80, 57 and 91% at pH 2, 7 and 13, respectively. Ammonia and nitrate were detected as the main nitrogen byproducts of RDX and formic acid was detected as an organic byproduct. The results showed that a gamma ray irradiation was an attractive method for the decomposition of RDX in an aqueous solution and it was found that a strong alkaline pH over 12 should be applied to the decomposition reaction of RDX.

A Study on Adsorbent Munufacture for Removal of VOC by Recycling of Paper Sludge and Red mud (제지슬러지와 적니를 이용한 VOC 제거를 위한 흡착제 개발 연구)

  • Min, Byong-Hun;Kim, Jeong-Ho;Chung, Chan-Kyo;Suh, Sung-Sup;Kang, Sung-Won
    • Clean Technology
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    • v.8 no.2
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    • pp.61-66
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    • 2002
  • Recycling method of red mud, byproduct from the aluminium manufacturing process, and paper sludge was investigated in order for them to be utilized as the adsorbent for the removal of volatile organic components(VOCs). Either high density polyethylene(HDPE) or low density polyethylene(LDPE) was added to facilitate the manufacture of adsorbents. The utilization of HDPE in the adsorbents increased the adsorption capacity due to the good physical properties, such as, BET and true density, compared with LDPE. BET values of the manufactured adsorbents were much lower than the commercial activated carbon ($10^{-2}-10^{-3}$). It may be due to the fact that the time for decomposition of the paper sludge was not enough during the manufacturing of adsorbents. But the specific adsorption capacity of the manufactured adsorbents (mole adsorbed per unit surface area) had much higher value than the commercial activated carbon (10-100). Therefore, it is important that BET of manufactured adsorbents needs to be increased to obtain the same adsorption capacity as the commercial activated carbon.

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Evaluation of Durability Performance of Fly Ash Blended Concrete due to Fly Ash Replacement with Tire Derived Fuel Ash (타이어 고무 애쉬 치환에 따른 플라이애쉬 혼입 콘크리트의 내구성능 성능 평가)

  • Kwon, Seung-Jun;Yoon, Yong-Sik;Park, Sang-Min;Kim, Hyeok-Jung
    • Journal of the Korea Concrete Institute
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    • v.28 no.6
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    • pp.647-653
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    • 2016
  • In the paper, durability performance in FA (Fly Ash) blended concrete is evaluated considering replacement of FA with TDFA (Tire Derived Fuel Ash) from 3.0% to 12%. TDFA is a byproduct from combustion process in thermal power plant, where chopped rubber is mixed for boiling efficiency. This is the 1st study on application of TDFA to concrete as mineral admixture. For the work, concrete samples containing 0.5 of w/b (water to binder) ratio and 20% replacement ratio of FA are prepared. With replacing FA with TDFA to 12%, durability performance is evaluated regarding compressive strength, carbonation, chloride diffusion, and porosity. The results of compressive strength, carbonation, and porosity tests show reasonable improvement in durability performance to 12% replacement of TDFA. In particular, clear decreasing diffusion coefficient is observed with increasing TDFA replacement due to its packing effect. Concrete containing TDFA can be effective for durability improvement when workability is satisfied in mixing stage.

Surface Analysis of Fluorine-Plasma Etched Y-Si-Al-O-N Oxynitride Glasses

  • Lee, Jung-Ki;Hwang, Seong-Jin;Lee, Sung-Min;Kim, Hyung-Sun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.38.1-38.1
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    • 2009
  • Plasma etching is an essential process for electronic device industries and the particulate contamination during plasma etching has been interested as a big issue for the yield of productivity. The oxynitride glasses have a merit to prevent particulate contamination due to their amorphous structure and plasma etching resistance. The YSiAlON oxynitride glasses with increasing nitrogen content were manufactured. Each oxynitride glasses were fluorine-plasma etched and their plasma etching rate and surface roughness were compared with reference materials such as sapphire, alumina and quartz. The reinforcement mechanism of plasma etching resistance of the YSiAlON glasses studied by depth profiling at plasma etched surface using electron spectroscopy for chemical analysis. The plasma etching rate decreased with nitrogen content and there was no selective etching at the plasma etched surface of the oxynitride glasses. The concentration of silicon was very low due to the generation of SiF4 very volatile byproduct and the concentration of aluminum and yttrium was relatively constant. The elimination of silicon atoms during plasma etching was reduced with increasing nitrogen content because the content of the nitrogen was constant. And besides, the concentration of oxygen was very low on the plasma etched surface. From the study, the plasma etching resistance of the glasses may be improved by the generation of nitrogen related structural groups and those are proved by chemical composition analysis at plasma etched surface of the YSiAlON oxynitride glasses.

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Mitochondrial Efficiency-Dependent Viability of Saccharomyces cerevisiae Mutants Carrying Individual Electron Transport Chain Component Deletions

  • Kwon, Young-Yon;Choi, Kyung-Mi;Cho, ChangYeon;Lee, Cheol-Koo
    • Molecules and Cells
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    • v.38 no.12
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    • pp.1054-1063
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    • 2015
  • Mitochondria play a crucial role in eukaryotic cells; the mitochondrial electron transport chain (ETC) generates adenosine triphosphate (ATP), which serves as an energy source for numerous critical cellular activities. However, the ETC also generates deleterious reactive oxygen species (ROS) as a natural byproduct of oxidative phosphorylation. ROS are considered the major cause of aging because they damage proteins, lipids, and DNA by oxidation. We analyzed the chronological life span, growth phenotype, mitochondrial membrane potential (MMP), and intracellular ATP and mitochondrial superoxide levels of 33 single ETC component-deleted strains during the chronological aging process. Among the ETC mutant strains, 14 ($sdh1{\Delta}$, $sdh2{\Delta}$, $sdh4{\Delta}$, $cor1{\Delta}$, $cyt1{\Delta}$, $qcr7{\Delta}$, $qcr8{\Delta}$, $rip1{\Delta}$, $cox6{\Delta}$, $cox7{\Delta}$, $cox9{\Delta}$, $atp4{\Delta}$, $atp7{\Delta}$, and $atp17{\Delta}$) showed a significantly shorter life span. The deleted genes encode important elements of the ETC components succinate dehydrogenase (complex II) and cytochrome c oxidase (complex IV), and some of the deletions lead to structural instability of the membrane-$F_1F_0$-ATP synthase due to mutations in the stator stalk (complex V). These short-lived strains generated higher superoxide levels and produced lower ATP levels without alteration of MMP. In summary, ETC mutations decreased the life span of yeast due to impaired mitochondrial efficiency.

Study of Non Sintered Cement Mortar Using Nanoslag and Alkali Activator (나노슬래그와 알칼리 자극제를 활용한 비소성 시멘트 모르타르에 관한 연구)

  • Jeong, Sung-Wook;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.6
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    • pp.61-66
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    • 2010
  • As global warming has had harmful effects on the environment, the construction industry has made efforts to reduce the amount of $CO_2$ generated in the process of cement production. There is an urgent need for an alternative material that can replace cement. To improve the initial strength and economical efficiency pointed out as problems, this research was conducted for Blast Furnace Slag (BFS), an industrial byproduct. Non-sintering cement (NSC) was used by minimizing the amount of high-priced alkali activators. By using Nano-technology, fineness has been maximized, to enhance the initial strength of BFS. This research is based on non-sintered cement replaced by nano-slag using alkali activators, and the fundamental properties and quality of the non-sintered cement were investigated. A variety of activators were used, up to 10 percent of the slag weight. This research aims to present fundamental data through a comparative analysis of flexural strength, compressive strength, time of setting, diabetic temperature, and rising heat.

Screening, Cloning, Expression and Characterization of New Alkaline Trehalose Synthase from Pseudomonas monteilii and Its Application for Trehalose Production

  • Trakarnpaiboon, Srisakul;Bunterngsook, Benjarat;Wansuksriand, Rungtiva;Champreda, Verawat
    • Journal of Microbiology and Biotechnology
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    • v.31 no.10
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    • pp.1455-1464
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    • 2021
  • Trehalose is a non-reducing disaccharide in increasing demand for applications in food, nutraceutical, and pharmaceutical industries. Single-step trehalose production by trehalose synthase (TreS) using maltose as a starting material is a promising alternative process for industrial application due to its simplicity and cost advantage. Pseudomonas monteilii TBRC 1196 was identified using the developed screening method as a potent strain for TreS production. The TreS gene from P. monteilii TBRC 1196 was first cloned and expressed in Escherichia coli. Purified recombinant trehalose synthase (PmTreS) had a molecular weight of 76 kDa and showed optimal pH and temperature at 9.0 and 40℃, respectively. The enzyme exhibited >90% residual activity under mesophilic condition under a broad pH range of 7-10 for 6 h. Maximum trehalose yield by PmTreS was 68.1% with low yield of glucose (4%) as a byproduct under optimal conditions, equivalent to productivity of 4.5 g/l/h using enzyme loading of 2 mg/g substrate and high concentration maltose solution (100 g/l) in a lab-scale bioreactor. The enzyme represents a potent biocatalyst for energy-saving trehalose production with potential for inhibiting microbial contamination by alkaline condition.