• Title/Summary/Keyword: primary phase

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Preparation and Characterization of Fine $TiO_2$ Powders by Vapor-Phase Hydrolysis of TiCl4 (사염화티타늄의 기상가수분해반응에 의한 $TiO_2$ 미분의 제조 및 입자특성)

  • 염선민;김광호;신동원;박찬경
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.525-532
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    • 1992
  • TiO2 fine powder was synthesized in the gas phase by chemical vapor deposition using hydrolysis of TiCl4. Content of rutile phase in the powder was investigated. Powder characteristics such as size, crystallinity and morphology were also studied by means of TEM, SEM and XRD. Rutile phase in TiO2 powder started to be formed from 100$0^{\circ}C$ and the content increased with the reaction temperature and TiCl4 concentration. As the temperature increased from 80$0^{\circ}C$ to 140$0^{\circ}C$, the primary particle size increased while secondary particle size decreased. Spherical secondary particle with fine primary crystals agglomerated was produced at low temperature of 80$0^{\circ}C$ whereas the grown primary particle being final particle size was produced at higher temperature of 140$0^{\circ}C$. Other effects of TiCl4 and H2O partial pressures on particle size were also reported in this study.

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Analysis of Phase Separation by Thermal Aging in Duplex Stainless Steels by Magnetic Methods

  • Kim, Sunki;Wonmok Jae;Kim, Yongsoo
    • Nuclear Engineering and Technology
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    • v.29 no.5
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    • pp.361-367
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    • 1997
  • The phase separation in ferrite phase of duplex stainless steel is the primary cause of thermal aging embrittlement of the LWR primary pressure boundary components. In this study the phase separation of simulated duplex stainless steel was detected by Mossbauer spectroscopy and magnetic property analysis by VSM(Vibrating Specimen Magnetometer). The simulated duplex stainless steels, Fe-Cr binary, Fe-Cr-Ni ternary, and Fe-Cr-Ni-Si quarternary allots, were aged at 370 and 40$0^{\circ}C$ up to 5,340 hours. It was observed from Mossbauer spectra analysis that internal magnetic field increases with aging time and from VSM that the specific saturation magnetization and Curie temperature increase with aging time. These result are indicative that phase separation into Fe-rich region and Cr-rich region is caused by thermal aging in the temperature range of 370~40$0^{\circ}C$ In cases of specimens containing Ni, the increase of specific saturation magnetization is much higher. This implies that Ni seems to promote Fe-Cr interdiffusion, which accelerates the phase separation into Fe-rich $\alpha$ phase and Cr-rich $\alpha$' phase.

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An Analysis of Concerns of Primary School Teachers on Transitional Education from Early Childhood Phase to Primary Education (초등학교 입학 초기 적응 교육에 관한 교사들의 관심도 분석)

  • Park, So-Young
    • Journal of Fisheries and Marine Sciences Education
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    • v.23 no.3
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    • pp.533-548
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    • 2011
  • This study examined the concern levels of primary school teachers regarding transitional education from early childhood phase to primary education. Concern Based Adoption Model (CBAM) instrument of Hall and Hord (2006) was used to survey 104 primary school teachers. The results indicated that the majority of respondents' concern level was at 'informational' level (stage 1). And first peak of concern level was at 'unconcerned' level (stage 0). The first-second peak analysis of stage 0 (unconcerned) group indicated that there were 5 types of groups and each had distinguished features. Finally there were statistical differences at the unconcerned stage by in-service training and career of the first-year class. A discussion of the limitations of this study and implications for teacher education programs and operational support systems were suggested.

Single-Stage Quasi Resonant Type PSR(Primary Side Regulation) PWM Converter for the LED Drive in TRIAC Phase Controlled Dimmer (TRIAC위상 제어 조광기에서의 LED구동을 위한 Single-Stage 준 공진형 PSR(Primary Side Regulation) PWM 컨버터)

  • Han, Jae-Hyun;Lim, Young-Cheol;Jung, Young-Gook
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.2
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    • pp.84-94
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    • 2013
  • In case when the existing TRIAC phase controlled dimmer is drove for the LED lighting equipments, there are many problems such as the LED flicker in low phase-angles, the acoustic noise and elements damage by increase of the peak voltage in the input filter capacitor, mulfunction by insufficiency of the TRIAC holding current, and the abnormal oscillation by LC resonant. In this paper, we proposes the single-stage quasi-resonant PSR(Primary Side Regulation) PWM converter, and the design, the simulation and experiment are performed. As a result, it could confirm that the proposed PWM converter is the lighting equipments for LED drive which can alternate the existing 60W class incandescent bulbs and it has the high drive performance of the efficiency 80% and over, the power factor 0.95 and over under the normal voltage 220V. Finally, total harmonic distortion(THD) is gratified with a standard[1] of the lighting equipments and the durability is evaluated as the high reliablilty of 150,000 hours and over.

An Array Antenna Calibration Algorithm Using LTE Downlink Zadoff-Chu Sequence (LTE 하향링크의 Zadoff-Chu 시퀀스를 이용한 배열 안테나 Calibration 알고리즘)

  • Sun, Tiefeng;Jang, Jae Hyun;Yang, Hyun Wook;Choi, Seung Won
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.9 no.4
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    • pp.51-57
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    • 2013
  • Research on calibration of array antenna has become a hot spot in the area of signal processing and it is necessary to obtain the phase mismatch of each antenna channel. This paper presents a new calibration method for an array antenna system. In order to calibrate the phase mismatch of each antenna channel, we used primary synchronization signal (PSS) which exists in LTE downlink frame. Primary synchronization signal (PSS) is based on a Zadoff-Chu sequence which has a good correlation characteristic. By using correlation calculation, we can extract primary synchronization signal (PSS). After extracting primary synchronization signal (PSS), we use it to calibrate and reduce the phase errors of each antenna channel. In order to verify the new array antenna calibration algorithm which is proposed in this paper, we have simulated the proposed algorithm by using MATLAB. The array antenna system consists of two antenna elements. The phase mismatch of first antenna and second antenna is calculated accurately by proposed algorithm in the experiment test. Theory analysis and MATLAB simulation results are shown to verify the calibration algorithm.

Heart Rate Variability (HRV) Characteristics of Patients with Primary Dysmenorrhea at the Menstrual Phase: A Literature Review and Meta-Analysis (원발성 월경통 환자의 월경기 HRV 특성에 대한 문헌고찰 및 메타분석)

  • Cho, Si-Yoon;Lee, Ji-Yeon
    • The Journal of Korean Obstetrics and Gynecology
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    • v.35 no.3
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    • pp.122-136
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    • 2022
  • Objectives: The aim of this study is to investigate Heart Rate Variability (HRV) characteristics of patients with primary dysmenorrhea at the menstrual phase. Methods: 7 databases (Pubmed, Cochrane library, CNKI, RISS, KISS, OASIS, ScienceON) were searched for eligible studies published before 2021 December. The studies comparing HRV between patients with primary dysmenorrhea and controls were included. A random-effects model was used to evaluate differences of HRV parameters between patients with primary dysmenorrhea and controls. Results: 4 articles were included in this review based on inclusion and exclusion criteria. SDNN (Standard deviation of NN intervals), RMSSD (Square root of the mean squared difference of successive NN intervals), mean PR (Mean of pulse rate), LF (Low frequency), HF (High frequency), was the most frequently used as HRV parameters. RMSSD was significantly lower in patients with primary dysmenorrhea than controls. There was no statistically significant difference of other HRV parameters between patients with primary dysmenorrhea and controls. Conclusions: This study suggests that parasympathetic activity and overall functions of autonomic nervous system might be decreased in patients with primary dysmenorrhea at the menstrual phase. In the future, well-designed clinical studies using HRV and additional meta-analysis should be conducted to obtain a wealth of information about HRV characteristics of patients with primary dysmenorrhea.

Removal study of As (V), Pb (II), and Cd (II) metal ions from aqueous solution by emulsion liquid membrane

  • Dohare, Rajeev K.;Agarwal, Vishal;Choudhary, Naresh K.;Imdad, Sameer;Singh, Kailash;Agarwal, Madhu
    • Membrane and Water Treatment
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    • v.13 no.4
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    • pp.201-208
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    • 2022
  • Emulsion Liquid Membrane (ELM) is a prominent technique for the separation of heavy metal ions from wastewater due to the fast extraction and is a single-stage operation of stripping-extraction. The selection of the components (Surfactant and Carrier) of ELM is a very significant step for its preparation. In the ELM technique, the primary water- in-oil (W/O) emulsion is emulsified in water to produce water-in-oil-in-water (W/O/W) emulsion. The water in oil emulsion was prepared by mixing the membrane phase and internal phase. To prepare the membrane phase, the extractant D2EHPA (di-2-ethylhexylphosphoric acid) was used as a mobile carrier, Span-80 as a surfactant, and Paraffin as a diluent. Moreover, the internal (receiving) phase was prepared by dissolving sulphuric acid in water. Di-(2- ethylhexyl) phosphoric acid such as surfactant concentration, carrier concentration, sulphuric acid concentration in the receiving (internal) phase, agitation time (emulsion phase and feed phase), the volume ratio of the membrane phase to the receiving phase, the volume ratio of the external feed phase to the primary water-in-oil emulsion and pH of feed were studied on the percentage extraction of metal ions at 20℃. The results show that it is possible to remove 78% for As(V), 98% for Cd(II), and 99% for Pb(II). Emulsion Liquid Membrane (ELM) is a well-known technique for separating heavy metal ions from wastewater due to the fast extraction and is a single-stage operation of stripping-extraction. The selection of ELM components (Surfactant and Carrier) is a very significant step in its preparation. In the ELM technique, the primary water-in-oil (W/O) emulsion is emulsified to produce water-in-oil-in-water (W/O/W) emulsion. The water in the oil emulsion was prepared by mixing the membrane and internal phases. The extractant D2EHPA (di-2-ethylhexylphosphoric acid) was used as a mobile carrier, Span-80 as a surfactant, and Paraffin as a diluent. Moreover, the internal (receiving) phase was prepared by dissolving sulphuric acid in water. Di-(2-ethylhexyl) phosphoric acid such as surfactant concentration, carrier concentration, sulphuric acid concentration in the receiving (internal) phase, agitation time (emulsion phase and feed phase), the volume ratio of the membrane phase to the receiving phase, the volume ratio of the external feed phase to the primary water-in-oil emulsion and pH of feed were studied on the percentage extraction of metal ions at 20℃. The results show that it is possible to remove 78% for As(V), 98% for Cd(II), and 99% for Pb(II).

A Study of Metallurgical Phenomena in Austenitic Stainless Steel Fusion Welds (I) -Weldability of Commercial Austenitic Stainless Steels- (오스테나이트계 스테인리스강 용접부의 금속학적 현상에 관한 연구(I) - 시판 오스테나이트계 스테인리스강의 용접성 -)

  • 이종섭;김숙환
    • Journal of Welding and Joining
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    • v.16 no.3
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    • pp.111-120
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    • 1998
  • To predict and evaluate metallurgical and mechanical behavior of th welds, it is essential to understand solidification behavior and microstructural evolution experienced in the welds, neither of which follows the equilibrium phase diagram because of rapid heating and cooling conditions. Metallurgical phenomena in austenitic stainless steel fusion welds, types 304, 309S, 316L, 321 and 304N, were investigated in this study. Autogenous GTA welding was performed on weld coupons, and primary solidification mode and phase distribution were investigated from the welds. Varestraint test was employed to evaluate solidification cracking susceptibilities of the alloys. GTA weld fusion zones in type 304, 321 and 304N stainless steels experienced primary ferrite solidification while those in type 309S primary austenite solidification. Type 316L exhibited a mixed type of primary ferrite and primary austenite solidification. The primary solidification mode strongly depended on $Cr_{eq}/Ni_{eq}$ ratio. In terms of solidification cracking susceptibility, type 309S that solidified as primary austenite exhibited high cracking susceptibility while the alloys experienced primary ferrite solidification showed low cracking susceptibility. The relative ranking in solidification cracking susceptibility was type 304=type 304N < type 321 < type 316L < type 309S.

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The Grain Size Control of A356 Aluminum Alloy by Electromagnetic Stirring (수평식 전자교반을 이용한 A356 합금의 결정립 제어)

  • Ko J. H.;Seo P. K.;Choi W. S.;Kang C. G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.111-114
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    • 2004
  • It is many devices to obtain the globular structure because the globularity of the structure is the key to the low apparent viscosity and also to good rheological properties. In this study, the morphology of the change of primary Al phase in A356 alloy by electro magnetic stirrer was investigated to obtain the globular structure. The parameters are the current, stirring time, pouring temperature individually. The greater current and longer stirring time was to get the finer the primary however in case of over the 80A of current and 60sec of stirring time, the primary Al was merged together and was increased. The effect of pouring temperature has an important effect on the size of primary phase. About the $675^{\circ}C$, the primary Al was very fined.

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Calculation of Two-Phase Turbulent Jet with a Two-Equation Model (2-方程式 모델 에 의한 二相亂流 제트流動 의 數値解析)

  • 양선규;최영돈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.6
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    • pp.714-724
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    • 1985
  • Two-phase(air-solid, air-liquid droplet) turbulent round jet has been analyzed numerically using two equation turbulence model. The mean motion of suspending particles in air has been treated as the secondary fluid with virtual density and eddy viscosity. In this paper, the local mean velocity of secondary fluid is not assumed to be the same as that of the primary one. Dissipation rate of turbulent kinetic energy which arises because the particles can not catch up with the turbulent fluctuations of the primary fluid has been modelled by using the concept of Kolmogorov's spectral energy transfer. Numerical computations were performed for flows with different volume fraction of the dispersed phase and the diameter of particle. Results show that the total rate of turbulent energy dissipation, turbulent intensities and spreading rate of jets are reduced by the increase of volume fraction of dispersed phase. However it does not show consistent tendency with increasing the particle diameter. This investigation also shows that presence of particles in the fluid modifies the structure of the primary fluid flow significantly. Predicted velocity profiles and turbulence properties qualitatively agree with available data.