• 한국대기환경학회지
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• 제17권1호
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• pp.97-104
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• 2001

Decomposition of trichloroethlyene(TCE) in electron beam irradiation was examined on order to obtain information on the treatment of VOC in air. Air containing vaporized TCE has been studied in a flow reactor with different reaction environments, at various initial TCE concentration and in the presence and absence of water vapor. Maximum decomposition was observed in oxygen reaction environment and the degree of decomposition was about 99% at 20kGy for 2,000ppm initial TCE. The concentration of TCE exponentially decreased with dose in air and pure oxygen. The effect of water vapor on TCE decomposition efficiency was examined. The decomposition rate of TCE in the presence of water vapor (5,600 ppm) was approximately 10% higher than that in the absence of water vapor. Dichloroacetic acid, dichloroacethyl chloride and dichloroethyl ester acid were identified as primary products of this reaction adn were decomposed and oxidized to yield CO and $CO_2$. Perchloroethylene, hexachloroethane, chloroform and carbon tetrachloride were also observed as highly chlorinat-ed by products.

• 한국추진공학회지
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• 제19권5호
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• pp.15-21
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• 2015

착화기의 1차 점화장약으로 널리 사용되어지고 있는 ZPP(Zirconium/Potassium perchlorate)의 열분해 특성을 differential scanning calorimetry(DSC)를 사용하여 평가하였다. ZPP의 열분해반응에 대한 속도론적 파라미터를 결정하기 위하여, 다른 가열 속도를 갖고 수행된 DSC 결과들을 AKTS사의 Thermokinetics software를 사용하여 분석하였다. 결정된 속도론적 파라미터를 사용하여 계산된 모사값들은 실험적 결과들과 잘 일치함으로써, ZPP의 열분해과정에 대한 속도론적 모사의 유효성을 검증할 수 있었다.

• Journal of the korean society of oceanography
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• 제39권1호
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• pp.14-19
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• 2004

Difference of Dissolved Inorganic Phosphorus (DIP), Dissolved Inorganic Nitrogen (DIN) and Dissolved Silicate (DSi) budgets in the Bohai Sea between 1982 and 1992 related the decrease of the Yellow River discharge is discussed on the basis of observed data. The estuarine circulation in the Bohai Sea had been weakened from 1982 to 1992 due to the decrease of the Yellow River discharge and the average residence time of fresh water had become longer. DIN concentration increased but DIP and DSi concentrations decreased from 1982 to 1992 in the Bohai Sea. Primary production was regulated mainly by water temperature and DIN concentration in 1982 but it was regulated mainly by DIP concentration in 1992. Primary production was larger than decomposition plus bottom release and nitrogen fixation was larger than denitrification in 1982. However, decomposition plus bottom release was larger than primary production and denitrification was larger than nitrogen fixation in 1992 in the Bohai Sea.

• 한국인터넷방송통신학회논문지
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• 제18권2호
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• pp.81-88
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• 2018

부사용자가 주사용자의 주파수 사용 상태를 판별하기 위해 인지 무선 시스템의 핵심 기술인 스펙트럼 센싱을 사용한다. 스펙트럼 센싱 기법 중 에너지 검출법은 할당 된 채널 신호의 강도에 따라서 주사용자의 주파수 사용 유무를 판별한다. 이 기법은 단순히 신호의 크기를 이용해 스펙트럼 센싱하기 때문에 SNR 대역이 낮아질수록 주사용자의 신호를 검출하기 어렵다는 단점이 있다. 본 논문은 낮은 SNR 대역에서의 성능 열화를 극복하기 위해 웨이블릿 패킷 분해를 사용한 서포트 벡터 머신을 스펙트럼 센싱과 융합하는 방식을 제안하였다. 이 방식은 센싱 신호를 웨이블릿 패킷 분해를 기반으로 특징 추출하여 Support Vector Machine의 훈련과 실험용 데이터로 사용한다. 제안한 방식의 실험 결과를 SNR대역에 대해 정확도와 ROC 커브 그래프의 AUC를 이용하여 에너지 검출법과 비교하였다. 실험 결과, 제안한 시스템은 낮은 SNR대역에서 에너지 검출법 보다 더 향상된 판별 성능을 보였다.

• 제어로봇시스템학회논문지
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• 제4권4호
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• pp.413-419
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• 1998

A novel order-reduction technique for model predictive control(MPC) is proposed based on the singular value decomposition(SVD) of a pulse response circulant matrix(PRCM) of a concerned system. It is first investigated that the PRCM (in the limit) contains a complete information of the frequency response of a system and its SVD decomposes the information into the respective principal directions at each frequency. This enables us to isolate the significant modes of the system and to devise the proposed order-reduction technique. Though the primary purpose of the proposed technique is to diminish the required computation in MPC, the clear frequency decomposition of the SVD of the PRCM also enables us to improve the robustness through selective excitation of frequency modes. Performance of the proposed technique is illustrated through two numerical examples.

• Nuclear Engineering and Technology
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• 제55권3호
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• pp.827-838
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• 2023

Centrifugal pump is a key part of nuclear power plant systems, and its health status is critical to the safety and reliability of nuclear power plants. Therefore, fault diagnosis is required for centrifugal pump. Traditional fault diagnosis methods have difficulty extracting fault features from nonlinear and non-stationary signals, resulting in low diagnostic accuracy. In this paper, a new fault diagnosis method is proposed based on the improved particle swarm optimization (IPSO) algorithm-based variational modal decomposition (VMD) and relevance vector machine (RVM). Firstly, a simulation test bench for rotor faults is built, in which vibration displacement signals of the rotor are also collected by eddy current sensors. Then, the improved particle swarm algorithm is used to optimize the VMD to achieve adaptive decomposition of vibration displacement signals. Meanwhile, a screening criterion based on the minimum Kullback-Leibler (K-L) divergence value is established to extract the primary intrinsic modal function (IMF) component. Eventually, the factors are obtained from the primary IMF component to form a fault feature vector, and fault patterns are recognized using the RVM model. The results show that the extraction of the fault information and fault diagnosis classification have been improved, and the average accuracy could reach 97.87%.

• 경영과학
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• 제12권2호
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• pp.63-75
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• 1995

The uncapacitated facility location problem considered here is to determine facility location sites, minimizing the total cost of establishing facilities and serving customer demand points which require primary and back-up services. To solve this problem effectively, we propose two things in this study. First, we propose an idea of Benders' decomposition approach as a solution method of the problem. Second, we implement the problem on GAMS. Using GAMS (general Algebraic Modeling System) can utilize an mixed-integer programming solver such as ZOOM/XMP and provide a completely general automated implementation with a proposed solution method.

• 한국수소및신에너지학회논문집
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• 제31권1호
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• pp.1-7
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• 2020

The synthesis and catalytic activities over vanadium carbides were examined for ammonia decomposition reaction to produce the hydrogen. In particular, the comparison of vanadium nitrides were made on the ammonia decomposition reaction. The experimental data exhibited that BET surface areas ranged from 5.2 ㎡/g to 25.6 ㎡/g and oxygen uptake values varied from 3.8 μmol/g to 31.3 μmol/g. It is general that vanadium carbides (VC) were observed to be superior to vanadium nitrides for ammonia decomposition reaction. The primary reason for these differences were thought to be related to the extent of electronegativity between these materials. Most of vanadium carbide crystallites were exceeded by Pt/C crystallite. We assumed that the activities for vanadium carbide crystallites (VC) were comparable to or even higher than that determined for the Pt/C crystallite.

• 한국환경과학회지
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• 제19권5호
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• pp.577-584
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• 2010

The generation of $TiO_2$ nanoparticles by a thermal decomposition of titanium tetraisopropoxide (TTIP) was carried out experimentally using a tubular electric furnace at various synthesis temperatures (700, 900, 1100 and $1300^{\circ}C$) and precursor heating temperatures (80, 95 and $110^{\circ}C$). Effects of degree of crystallinity, surface area and anatase mass fraction of those $TiO_2$ nanoparticles on photocatalytic properties such as decomposition of methylene blue was investigated. Results show that the primary particle diameter obtained from thermal decomposition of TTIP was considerably smaller than the commercial photocatalyst (Degussa, P25). Also, those specific surface areas were more than 134.4 $m^2$/g. Resultant $TiO_2$ nanoparticles showed improved photocatalytic activity compared with Deggusa P25. This is contributed to the higher degree of crystallinity, surface area and anatase mass fraction of $TiO_2$ nanoparticles compared with P25.

• 한국재료학회지
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• 제25권10호
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• pp.547-551
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• 2015

The present study prepared molybdenum trioxide ($MoO_3$), the most important intermediate of molybdenum metal, by using a fluidized bed reactor for the thermal decomposition of ammonium molybdate (AM) in the presence of an air flow. During the process of fluidizing the sample inside the reactor, the reaction time and temperature were optimized with a close analysis of the X-ray diffraction (XRD) data and with thermogravimetric analysis (TGA). In particular, the temperature level, at which the AM decomposition is completed, is very important as a primary operating parameter. The analysis of the XRD and TGA data showed that the AM decomposition is almost completed at ${\sim}350^{\circ}C$ with a reaction time of 30 min. A shorter reaction time of 10 min. required a higher reaction temperature of ${\sim}500^{\circ}C$ with the same air flow rate to complete the AM decomposition. A sharp rise in the decomposition efficiency at a temperature ranging between 320 and $350^{\circ}C$ indicated a threshold for the AM decomposition. The operating conditions determined in this study can be used for future scale-ups of the process.