• 대한기계학회논문집B
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• 제26권8호
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• pp.1172-1182
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• 2002

In the present study a general criterion for local thermal equilibrium is presented in terms of parameters of engineering importance which include the Darcy number, the effective Prandtl number of fluid, and the Reynolds number. For this, an order of magnitude analysis is performed for the case when the effect of convection heat transfer is dominant in a porous structure. The criterion proposed in this study is more general than the previous criterion suggested by Carbonell and Whitaker, because the latter is applicable only when conduction is the dominant heat transfer mode in a porous medium while the former can be applied even when convection heat transfer prevails. In order to check the validity of the proposed criterion for local thermal equilibrium, the forced convection phenomena in a porous medium with a microchanneled structure subject to an impinging jet are studied using a similarity transformation. The proposed criterion is also validated with the existing experimental and numerical results for convection heat transfer in various porous materials that include some of the parameters used in the criterion such as a microchannel heat sink with a parallel flow, a packed bed, a cellular ceramic, and a sintered metal. It is shown that the criterion presented in this work well-predicts the validity of the assumption of local thermal equilibrium in a porous medium.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2013년도 춘계학술대회 논문집
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• pp.971-972
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• 2013

• Bulletin of the Korean Chemical Society
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• 제35권12호
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• pp.3465-3474
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• 2014

Porous silica particles are the most prevailing raw material for stationary phases of liquid chromatography. During a long period of time, various methodologies for production of porous silica particles have been proposed, such as crashing and sieving of xerogel, traditional dry or wet process preparation of conventional spherical particles, preparation of hierarchical mesoporous particles by template-mediated pore formation, repeated formation of a thin layer of porous silica upon nonporous silica core (core-shell particles), and formation of specific silica monolith followed by grinding and calcination. Recent developments and applications of useful porous silica particles will be covered in this review. Discussion on sub-$3{\mu}m$ silica particles including nonporous silica particles, carbon or metal oxide clad silica particles, and molecularly imprinted silica particles, will also be included. Next, the individual preparation methods and their feasibilities will be collectively and critically compared and evaluated, being followed by conclusive remarks and future perspectives.

• 한국분말재료학회지
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• 제18권4호
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• pp.327-331
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• 2011

In order to fabricate the porous metal with controlled pore characteristics, unique processing by using metal oxide powder as the source and camphene as the sublimable material is introduced. CuO powder was selected as the source for the formation of Cu metal via hydrogen reduction. Camphene-based CuO slurry, prepared by milling at $47^{\circ}C$ with a small amount of dispersant, was frozen at $-25^{\circ}C$. Pores were generated subsequently by sublimation of the camphene. The green body was hydrogen-reduced at $200^{\circ}C$ for 30 min, and sintered at $500-700^{\circ}C$ for 1 h. Microstructural analysis revealed that the sintered Cu showed aligned large pore channels parallel to the camphene growth direction, and fine pores are formed around the large pore. Also, it showed that the pore size was controllable by the slurry concentration.

• 한국세라믹학회지
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• 제31권11호
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• pp.1337-1345
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• 1994

Glasses in the system of 45CaO-25TiO2-30P2O5 containing 1 mole% of M2O(M=Li, Na, K) were melted and crystallized. And their crystal phases were Ca3(PO4)2, CaTi4(PO4)6, and TiO2. Porous glass-ceramics with skeleton of two crystal phase CaTi4(PO4)6 and TiO2 were prepared by selective leaching of Ca3(PO4)2 with 0.1 N-HCl. Glass transition temperature(Tg) and crystallization temperature(Tc) were decreased by addition of 1 mole% alkali metal oxide. Pore size of porous glass-ceramics was increased with increasing heat treatment temperature and its dependence on heat treatment temperature was decreased with addition of Na2O and K2O. It was found that porous glass-ceramics of parent glass and containing 1mole% M2O(M=Li, Na, K) composition had maximum specific surface area, porosity and maximum of crystallzed phase by heat treatment at 80$0^{\circ}C$, 76$0^{\circ}C$, 78$0^{\circ}C$, 80$0^{\circ}C$ respectively.

• Advances in nano research
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• 제16권1호
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• pp.11-26
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• 2024

In this study, free vibration analysis of FG porous spherical cap reinforced by graphene platelets resting on Winkler-type elastic foundation has been surveyed for the first time. Three different types of porosity patterns are considered for the spherical cap whose two types of porosity patterns in the metal matrix are symmetric and the other one is uniform. Besides, five GPL patterns are assumed for dispersing of GPLs in the metal matrix. Tsai-Halpin and extended rule of the mixture are used to determine the Young modulus and mass density of the shell, respectively. Employing 3D FEM elasticity in conjunction with Hamilton's Principle, the governing motion equations of the structure are obtained and solved. The impact of various parameters including porosity coefficient, various porosity distributions in conjunction with different GPL patterns, the weight fraction of graphene Nano fillers, polar angles and stiffness coefficient of elastic foundation on natural frequencies of FG porous spherical cap reinforced by GPLs have been reported for the first time.

• 한국분말재료학회지
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• 제10권5호
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• pp.310-317
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• 2003

Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.225-228
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• 2000

Addition effects of metal oxide on the characteristics of infrared radiator of porous cordierite have been investigated. The porosity was increased with adding the graphite for 2MgO $.$ 2A1$_2$O$_3$$.$5SiO$_2$. The microstructure and the spectral emissivity were investigated as a function of metal oxide additives. The prosity and the emissivity were decreased with increasing amounts of CuO additives. The prosity and the emissivity were increased with increasing amounts of CoO, MnO$_2$ additives. The infrared radiator of cordierite system which spectral emissivity was 0.927 and 0.928 at from 5$\mu\textrm{m}$ to 20$\mu\textrm{m}$ wavelength as a 9wt% of CoO and MnO$_2$ additives.

• Advances in aircraft and spacecraft science
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• 제6권4호
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• pp.297-314
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• 2019

Dynamic stability of a porous metal foam nano-dimension plate on elastic substrate exposed to bi-axial time-dependent forces has been studied via a novel 3-variable plate theory. Various pore contents based on uniform and non-uniform models have been introduced. The presented plate model contains smaller number of field variables with shear deformation verification. Hamilton's principle will be utilized to deduce the governing equations. Next, the equations have been defined in the context of Mathieu-Hill equation. Correctness of presented methodology has been verified by comparison of derived results with previous data. Impacts of static and dynamical force coefficients, non-local coefficient, foundation coefficients, pore distributions and boundary edges on stability regions of metal foam nanoscale plates will be studied.

• Structural Monitoring and Maintenance
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• 제6권2호
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• pp.147-159
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• 2019

In present article, a size-dependent refined thick beam element has been established based upon nonlocal elasticity theory. Next, it is used to explore vibration response of porous metal foam nanobeams on elastic medium. The established beam element introduces ten degrees of freedom. Different porosity distributions called uniform, symmetric and asymmetric will be employed. Herein, introduced thick beam element contains shear deformations without using correction factors. Convergence and verification studies of obtained results from finite element method are also provided. The impacts of nonlocality factor, foundation factors, shear deformation, slenderness ratio, porosity kinds and porosity factor on vibration frequencies of metal foam nano-sized beams have been explored.