• Korean Journal of Microbiology
• /
• v.45 no.2
• /
• pp.133-139
• /
• 2009

A nutrient-concentrating system was operated to retrieve total phosphorus efficiently from a non-point pollution source. Attached bacteria were expected to play an important role in the system. Phosphorous was concentrated by formation of bacterial biofilms on rubberized coconut fiber media of the system. While concentration of total phosphorus (TP) ranged merely 0.12~0.35 mg/L in the stream water, TP levels in pore water and the media were 0.45~0.86 mg/L and 40.91~242.71 mg/kg, respectively. Total bacterial number (TBN) ranged $0.3\sim2.3\times10^6$ cells/ml in stream water, $0.4\sim4.4\times10^6$ cells/ml in pore water and $0.8\sim1.9\times10^9$ cells/g in media. There was a close correlation between TP and TBN. Based on band profiles in DGGE analyses, bacterial communities in the media were different from that in the stream water. Clostridium spp. were abundant in the stream water while Aquabacterium spp. were dominant species in early stages of biofilm formation in the media. The genera predominant in matured biofilms of the media were Clostridium and Enterococcus.

• KSBB Journal
• /
• v.19 no.3
• /
• pp.215-220
• /
• 2004

A variety of solid bases such as inorganic bases, basic anion exchange resins, and resin-bound bases were tested as a catalyst for racemization of (S)-naproxen 2,2,2-trifluoroethyl thioester in isooctane at 45$^{\circ}C$. Among the various bases, DIAIOM WA30, which is a weakly basic anion exchange resin with a tertiary amine based on a highly porous type styrene-divinylbenzene copolymer, showed the highest catalytic activity. The second-order interconversion constant of DIAION WA30 was 8.6${\times}$10$\^$-4/ mM$\^$-1/h$\^$-1/ and about 3 times higher than that of trioctylamine under the same conditions. The rate of DIAION WA30-catalyzed racemization decreased with increasing an amount of water added to the reaction medium. Lipase-catalyzed kinetic resolution of racemic naproxen 2,2,2-trifluoroethyl thioester was successfully carried out under in situ racemization of substrate with DIAION WA30 in isooctane at 45$^{\circ}C$. More than 60% conversion and 99% enantiomeric excess for the desired (S)-naproxen product were obtained. Furthermore, such a solid base catalyst could be easily separated and reused in contrast to trioctylamine.

• Tunnel and Underground Space
• /
• v.11 no.1
• /
• pp.42-58
• /
• 2001

In order to protect the environment from waste disposal activities, the prediction of the flux and flow paths of the contaminants from underground facilities should be assessed as accurately as possible. Especially, the prediction of the pathways and travel times of the nuclides from high level radioactive wastes in a deep repository to biosphere is one of the primary tasks for assessing the ultimate safety and performance of the repository. Since the contaminants are mainly transported with groundwater along the discontinuities developed within rock mass, the characteristics of groundwater flow through discontinuities is important for the prediction of contaminant fates as well as safety assessment of a repository. In this study, the actual fracture network could be effectively generated based on in situ data by separating geometric parameter and hydraulic parameter. The calculated anisotropic hydraulic conductivity was applied to a 3D porous medium model to calculate the path flow and travel time of the large studied area with the consideration of the complex topology in the area. Using the model, the pathways and travel times for groundwater were analyzed. From this study, it was concluded that the suggested techniques and procedures for predicting the pathways and travel times of groundwater from underground facilities to biosphere is acceptable and those can be applied to the safety assessment of a repository for radioactive wastes.

• The Journal of Engineering Geology
• /
• v.9 no.3
• /
• pp.187-206
• /
• 1999

A computer program to numerically predict the permeability tensor of fractured rocks is developed using information on discontinuities which Borehole Televiewer and Borehole Image Processing System (BIPS) provide. It uses orientation and thickness of a large number of discontinuities as input data, and calculates relative values of the 9 elements consisting of the permeability tensor by the formulation based on the EPM model, which regards a fractured rock as a homogeneous, anisotropic porous medium. In order to assess feasibility of the program on field sites, the numerically calculated tensor was obtained using BIPS logs and compared to the results of pumping test conducted in the boreholes of the study area. The degree of horizontal anisotropy and the direction of maximum horizontal permeability are 2.8 and $N77^{\circ}CE$, respectively, determined from the pumping test data, while 3.0 and $N63^{\circ}CE$ from the numerical analysis by the developed program. Disagreement between two analyses, especially for the principal direction of anisotropy, seems to be caused by problems in analyzing the pumping test data, in applicability of the EPM model and the cubic law, and in simplified relationship between the crack size and aperture. Aside from these problems, consideration of hydraulic parameters characterizing roughness of cracks and infilling materials seems to be required to improve feasibility of the proposed program. Three-dimensional assessment of its feasibility on field sites can be accomplished by conducting a series of cross-hole packer tests consisting of an injecting well and a monitoring well at close distance.

• Membrane Journal
• /
• v.15 no.4
• /
• pp.272-280
• /
• 2005

In this study, asymmetric polysulfone membranes were prepared by the phase inversion method and the casting solutions were containing N-methyl-2-pyrrolidone (NMP) as a solvent. Deionized water and various alcohols(methanol, ethanol, and propanol) were used as a coagulation medium in preparing asymmetric polysulfone membranes. This study investigates the effect of alcohol coagulants having different solubility parameters as a pore-former on the construction of porous structures and their pure water permeation properties. Asymmetric polysulfone membranes immersed in the pure alcohol coagulation bath solution showed the typical sponge-like structures and the reduced water permeability as compared with those of polysulfone membranes precipitated in the pure water coagulation bath solution. In the water/alcohol mixtures, asymmetric polysulfone membranes showed the finger-like structures with the sponge-like structures. Therefore, the sponge-like structure of polysulfone membrane was formed under the delayed demixing systems while the porosity of membrane was decreased significantly. The water permeability of polysulfone membrane precipitated in the pure water coagulant showed 164 [$L/m^2hr$] at 14.7 psi. In case of polysulfone membranes prepared in the pure methanol and ethanol coagulant, they showed the water permeability of 56 and 30 [$L/m^2hr$], respectively.

• Journal of the Korean Institute of Gas
• /
• v.19 no.5
• /
• pp.69-74
• /
• 2015

The study investigated numerically the heat transfer and chemical reaction characteristics of a methane-steam reforming by using a 3-dimensional computational fluid dynamics (CFD) code (Fluent ver. 16.1). The fuel temperature and its species mole fractions were estimated for various Reynolds number in the reformer tube at different burner temperatures. The catalysts were modeled as the porous medium of nicrome in the reformer tube. We considered radiation effect as well as conduction and convective heat transfer because the methane-steam was reformed at very high temperature condition above 1000 K. For two different Reynolds numbers of 49,000 and 88,000 and the burner temperatures were in the range from 1,100 K to 1,300 K. At a low Reynolds number, the fuel temperature increased, leading to increase in hydrogen reforming. However, fuel temperature and hydrogen reforming decreased because of higher convective heat transfer from relatively low fuel temperature. Moreover, the hydrogen reforming also increased with burner temperature.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.38 no.11
• /
• pp.915-924
• /
• 2014

In an aero gas-turbine engine, a surface air-oil heat exchanger (SAOHE) is used to cool the oil system for the gearboxes and electric generators. The SAOHE is installed inside the fan casing of the engine in order to dissipate the heat from the oil system into the bypass duct stream. The purpose of this study was to develop an effective numerical method for designing an SAOHE for an aero gas-turbine engine. A two-dimensional model using a porous medium was developed to evaluate the aero-thermal performance of the fins of the heat exchanger, and a one-dimensional flow and thermal network program was developed to save time and cost in the evaluation of the heat exchanger performance. Using this network program, the pressure drop and heat transfer performance of the heat exchanger were predicted, and the results were compared with two-dimensional computational fluid dynamics results and experiment data for validation.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.43 no.5
• /
• pp.555-566
• /
• 2023

In this study, a composite phase change material (CPCM) produced using the SOL-GEL technique was developed as a thermal energy storage medium for low-temperature applications. Tetradecane and activated carbon (AC) were used as the core and supporting materials, respectively. The tetradecane phase change material (PCM) was impregnated into the porous structure of AC using the vacuum impregnation method, and a thin layer of silica gel was coated on the prepared composite using the SOL-GEL process, where tetraethyl orthosilicate (TEOS) was used as the silica source. The thermal performance of the CPCM was analysed using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). DSC results showed that the pure tetradecane PCM had melting and freezing temperatures of 6.4℃ and 1.3℃ and corresponding enthalpies 226 J/g and 223.8 J/g, respectively. The CPCM exhibited enthalpy of 32.98 J/g and 27.7 J/g during the melting and freezing processes at 7.1℃ and 2.4℃, respectively. TGA test results revealed that the AC is thermally stable up to 500℃, which is much higher than the decomposition temperature of the pure tetradecane, which is around 120℃. Moreover, in the case of AC-PCM and CPCM thermal degradation started at 80℃ and 100℃, respectively. The chemical stability of the CPCM was studied using Fourier-transform infrared (FT-IR) spectroscopy, and the results confirmed that the developed composite is chemically stable. Finally, the surface morphology of the AC and CPCM was analysed using scanning electron microscopy (SEM), which confirmed the presence of a thin layer of silica gel on the AC surface after the SOL-GEL process.

• Journal of the Korean Geotechnical Society
• /
• v.24 no.2
• /
• pp.67-75
• /
• 2008

It is interesting to note that distinct element method has been used extensively to model the response of micro and discontinuous behavior in geomechanics. Impressive advances related to response of distinct particles have been conducted and there were difficulties in considering fluid effect simultaneously. Current distinct element methods are progressively developed to solve particle-fluid coupling focused on fluid flow through soil, rock or porous medium. In this research, numerical simulations of fluid injection into particulate materials were conducted to observe cavity initiation and propagation using distinct element method. After generation of initial particles and wall elements, confining stress was applied by servo-control method. The fluid scheme solves the continuity and Navior-Stokes equations numerically, then derives pressure and velocity vectors for fixed grid by considering the existence of particles within the fluid cell. Fluid was injected as 7-step into the assembly in the x-direction from the inlet located at the center of the left boundary under confining stress condition, $0.1MP{\alpha}\;and\;0.5MP{\alpha}$, respectively. For each simulation, movement of particles, flow rate, fluid velocity, pressure history, wall stress including cavity initiation and propagation by interaction of flulid-paricles were analyzed.

• Journal of The Geomorphological Association of Korea
• /
• v.28 no.3
• /
• pp.13-26
• /
• 2021

In mountain gully, channelized debris flow is an important phenomenon in the process of topographical change. Social infrastructure as roads may be damaged by channelized debris flows, but there has been little information about their occurrence and movement to prepare for the risk of the debris flow. Most of the channelized debris flows occur during heavy rains in mountainous valleys that are difficult to access, so there are not many field data. In this study, the topographical characteristics of the catchment, the rainfall and runoff related to the debris flow, the sedimentary pattern and the cross-sectional change of the channel bed, and the underflow velocity of the gravel bed have been investigated and analyzed in the Singi gully where the channelized debris flows occurred. In the catchment, there was almost no sediment runoff because the vegetation combine with the debris landforms and covered the surface. Therefore, the obvious cause of the channelized debris flows is the collapse of the slope and bed of the gully. Even if the gravel, cobbles, and boulders of the channel bed were lost by debris flow, the thalweg change due to debris flow may not be significant because they are supplied from the gully side slope normally. After the gabion structures were installed, the debris flow increased the thalweg change, bed erosion and side slope of the gully. Various sedimentary structures in the gully were classified according to the factors supporting the sedimentation. The hypsometric curve of the gully reflects the debris landforms and vegetation characteristics of the watershed and the sediment runoff due to debris flow, etc. The relationship between the flow velocity and the hydraulic gradient was non-linear under the condition that the porous medium with gully bed gravels is saturated with water. These results may be used as basic data for channelized debris flow research.