• Title/Summary/Keyword: polyvinyl alcohol(PVA)

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Effect of Micro Organic-inorganic Complex on the Hydration of Portland Cement(II) (Mcchanical and rheological properties of PVA-montmorillonite complex cemenrt system) (마이크로 유기-무기 복합체가 포오틀랜드 시멘트 수화에 미치는 영향(II) (PVA-점토 복합체-시멘트 계의 기계적 유동학적 특징))

  • 김창은;김배연;최진호;이형복
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.15-20
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    • 1985
  • In the course of cement hydration it was found that the addition of polyvinyl alcohol(contracted as PVA. here after) only in the cement paste could more influence on the set-retardation the depression of heat evol-ution rate than that of montmorillonit only or PVA-montmorillonie intercalation complex (PMIC) due to the effective adsorption of PVA on cement particles. The improved mechanical strength by addition of montmorillonite and PMIC was observed remarkably up to 0.05wt% due to the decrease of macro-pores caused by lowed viscosity or the acceleration of hydration reaction.

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Mixing and Compressive Strength Characteristics of Steel Cord and PVA Hybrid Fiber Reinforced Cement-Based Composites (Steel Cord와 PVA 혼합섬유 보강 고인성 시멘트 복합체의 비빔 및 압축강도 특성)

  • Yun Hyun Do;Yang Il Seung;Han Byung Chan;Hiroshi Fukuyama;Cheon Esther;Moon Youn Joon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.28-31
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    • 2004
  • This paper discusses the role of micro and macrofibers in the workability, compressive strength, and failure of cementitious composites. Workability(flow), compressive strength, splitting strength and fracture mechanism of hybrid fiber reinforced cement composites(HFRCC) have been investigated by means of Korean Standard (KS). The specific blend pursued in this investigation is a combination of polyvinyl alcohol(PVA) and steel cord. It was demonstrated that a hybrid combination of steel and PVA enhances fiber dispersion compared to only steel cord reinforced cement composites and that the brittle and wide cracking was much reduced in HFRCC as expected because in the matrix containing the PVA fiber around the steel cord, a multiple microcracking occurred and the steel cord could sufficiently work for bridging the cracked surface.

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Axial Behavior of High Performance Fiber Reinforced Cementitious Composite Columns with PVA Fibers (PVA섬유를 사용한 고인성 시멘트 복합체 기둥의 압축거동)

  • Byun Jang-Bae;Jeon Su-Man;Jeon Esther;Kim Sun-Woo;Hwang Sun-Kyung;Yun Hyun-Do;Lim Byung-Hun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.29-32
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    • 2005
  • An experimental investigation on the strength and behavior of High Performance Fiber Reinforced Cement Composite(HPFRCC) column with Polyvinyl alcohol(PVA) fibers under axial load have been carried out. The columns were subjected to monotonic axial compression until failure. The variables in this study are the combination ratio of PVA, and the volumetric ratio of transverse reinforcement. Test results showed that the fibers, when used in PVA2.0, could result in superior composite performance compared to their individual fiber reinforced cement composites.

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Growth Characteristics and Optimal Culture Conditions of PVA-Degrading Strains (Polyvinyl Alcohol분해자화균의 성장특성과 최적 배양조건)

  • 김정목;조무환조윤래정선용
    • KSBB Journal
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    • v.6 no.4
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    • pp.363-368
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    • 1991
  • PVA degrading bacteria were isolated from water system, and identified as Pseudomonas cepacia and Pseudmonas pseudomallei, which were named as Pseudomonas sp. G5Y and Pseudomonas sp. PW. It was found out that those two kinds of bacteria have a symbiotic relationship to degrade PVA. For the mixed culture of these bacteria, the optimal conditions of pH, temperature, nitrogen source, and polymerization degree of PVA were found to be 7.5, $35^{\circ}C$, ammonium sulfate, and 500, respectively. Also, the growth of these bacteria was promoted by trace elements such as vitamin B1, B12, pyridoxine, and p-aminobenzoate, respectively. The specific growth rate of mixed bacteria was inhibited when the concentration of PVA was more than 20g/l. The substrate inhibition kinetics of the mixed culture was $${\mu}=\frac{0.065S}{2.56+S+(S^2/156}hr^{-1}$

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Effect of PVA Brush Contamination on Post-CMP Cleaning Performance (Post-CMP Cleaning에서 PVA 브러시 오염이 세정 효율에 미치는 영향)

  • Cho, Han-Chul;Yuh, Min-Jong;Kim, Suk-Joo;Jeong, Hae-Do
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.2
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    • pp.114-118
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    • 2009
  • PVA (polyvinyl alcohol) brush cleaning method is a typical cleaning method for semiconductor cleaning process especially post-CMP cleaning. PVA brush contacts with the wafer surface and abrasive particle, generating the contact rotational torque of the brush, which is the removal mechanism. The brush rotational torque can overcome theoretically the adhesion force generated between the abrasive particle and wafer by zeta potential. However, after CMP (chemical mechanical polishing) process, many particles remained on the wafer because the brush was contaminated in previous post-CMP cleaning step. The abrasive particle on the brush redeposits to the wafer. The level of the brush contamination increased according to the cleaning run time. After cleaning the brush, the level of wafer contamination dramatically decreased. Therefore, the brush cleanliness effect on the cleaning performance and it is important for the brush to be maintained clearly.

Reinforcing Efficiencies of Two Different Cellulose Nanocrystals in Polyvinyl Alcohol-Based Nanocomposites

  • Park, Byung-Dae;Causin, Valerio
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.4
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    • pp.250-255
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    • 2013
  • As a renewable nanomaterial, cellulose nanocrystal (CNC) isolated from wood grants excellent mechanical properties in developing high performance nanocomposites. This study was undertaken to compare the reinforcing efficiency of two different CNCs, i.e., cellulose nanowhiskers (CNWs) and cellulose nanofibrils (CNFs) from hardwood bleached kraft pulp (HW-BKP) as reinforcing agent in polyvinyl alcohol (PVA)-based nanocomposite. The CNWs were isolated by sulfuric acid hydrolysis while the CNFs were isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. Based on measurements using transmission electron microscopy, the individual CNWs were about $6.96{\pm}0.87nm$ wide and $178{\pm}55nm$ long, while CNFs were $7.07{\pm}0.99nm$ wide. The incorporation of CNWs and CNFs into the PVA matrix at 5% and 1% levels, respectively, resulted in the maximum tensile strength, indicating different efficiencies of these CNCs in the nanocomposites. Therefore, these results suggest a relationship between the reinforcing potential of CNCs and their physical characteristics, such as their morphology, dimensions, and aspect ratio.

Fabrication and Characteristics of Mesophase Pitch-Based Graphite Foams Prepared Using PVA-AAc Solution (PVA-AAc 용액을 사용한 메조페이스 핏치기반 그라파이트 폼의 제조 및 특성)

  • Kim, Ji-Hyun;Lee, Sangmin;Jeong, Euigyung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.26 no.6
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    • pp.706-713
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    • 2015
  • Graphite foams (GFs) were prepared by adding different amounts of mesophase pitch (MP) into polyvinyl alcohol-acrylic acid (PVA-AAc) solution followed by the heat treatment. It was confirmed that the pore diameters of GFs were controlled by the slurry concentration, which was the mesophase content added in polymer solution, and their thermal conductivity and compressive strength were also controlled by porosities of GFs formed at different conditions. The resulting GFs in this study had the highest thermal conductivity of $53.414{\pm}0.002W/mK$ and compressive strength of $1.348{\pm}0.864MPa$ at 0.69 in porosity. The thermal conductivity of MP based GFs increased approximately 23 times higher than that of using isotropic pitch based GFs due to the developed graphitic structure.

Basic Mixing and Mechanical Tests on High Ductile Fiber Reinforced Cementless Composites (고인성 섬유보강 무시멘트 복합체의 기초 배합 및 역학 실험)

  • Cho, Chang-Geun;Lim, Hyun-Jin;Yang, Keun-Hyeok;Song, Jin-Kyu;Lee, Bang-Yeon
    • Journal of the Korea Concrete Institute
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    • v.24 no.2
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    • pp.121-127
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    • 2012
  • Cement has been traditionally used as a main binding material of high ductile fiber reinforced cementitious composites. The purpose of this paper is to investigate the feasibility of using alkali-activated slag and polyvinyl alcohol (PVA) fibers for manufacturing high ductile fiber reinforced cementless composites. Two mixture proportions with proper flowability and mortar viscosity for easy fiber mixing and uniform fiber dispersion were selected based on alkali activators. Then, the slump flow, compression, uniaxial tension and bending tests were performed on the mixes to evaluate the basic properties of the composites. The cementless composites showed an average slump flow of 465 mm and tensile strain capacity of approximately 2% of due to formation of multiple micro-cracks. Test results demonstrated a feasibility of manufacturing high ductile fiber reinforced composites without using cement.

Chitosan, PVA, 그리고 Chitosan/PVA 피막의 특성과 사과 겹무늬썩음병균 Botryosphaeria dothidea의 포자분산 억제작용

  • Lee, Seung-Ji;Park, Dong-Chan;Kim, Eve;Uhm, Jae-Youl;Lee, Yong-Hyun
    • Microbiology and Biotechnology Letters
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    • v.24 no.5
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    • pp.546-552
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    • 1996
  • The applicability of chitosan, a biodegradable natural polymer, as the coating material to prevent the dispersal of the spores of the apple white rot agent Botryosphaeria dothidea, was investigated. The physical properties of mixed chitosan/polyvinyl alcohol(PVA) film showed the increased physical properties for film formation, such as tensil strength, elongation, and viscosity, compared to either chitosan or PVA film. The FT-IR spectra of chitosan/PVA film indicated that the film was formed by simple blending not by any new synthetic bond. The chitosan and chitosan/PVA film showed effective antifungal activity on B. dothidea. The formed films were well decomposed by ASTM strains used for biodegradability test, on the other hand, the PVA film could not be decomposed by above standard strains. The field test at apple orchard showed that the dispersal of B. dothidea spores could be effectively reduced by coated film, especially by chitosan/PVA film. The spore dispersal was reduced upto 97.0% by 1.0% chitosan/5.0% PVA film during 4 months.

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Assessment of Formwork-Seepage Minimization in High Fluidity, Normal Strength Concrete Utilizing Thixotropic Properties (고유동 일반강도 콘크리트의 요변성 부여에 따른 거푸집 누출 저감 성능 분석)

  • Kim, Young-Ki;Lee, Yu-Jeong;Kim, In-Tae;Han, Dong-Yeop
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.4
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    • pp.337-348
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    • 2023
  • The central objective of this study is to curtail the leakage of mortar or cement paste, often resultant of ill-constructed formwork, by implementing thixotropy in the formulation of high-fluidity, standard-strength concrete. When such concrete is utilized in smaller scale construction projects, instances of formwork gaps due to suboptimal construction precision may lead to significant leakage of mortar and paste, a problem not typically encountered with traditional slump-flow concrete. In this investigation, Polyvinyl Alcohol(PVA) and borax are incorporated into the concrete mixture to induce thixotropy. The experimental design includes varying methodologies for integrating PVA and borax, while assessing alterations in diverse concrete performances, including thixotropy and leakage reduction potential that simulates formwork gap conditions. Under the experimental conditions defined within this study, it was found that replacing, rather than merely adding PVA and borax, aids in averting water addition via suspensions. This approach yielded promising results in terms of concrete properties and proved efficacious in stemming leakage in concrete possessing sufficient thixotropy. Notably, when a 6% PVA suspension was substituted, a significant reduction in leakage was observed. Consequently, it is projected that construction quality can be ensured, even with lower precision formwork, by applying thixotropy to concrete through the use of PVA and borax.