• Title/Summary/Keyword: polymer photonics

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The Compound Refractive Lens for Hard X-ray Focusing

  • Choi, J.;Jung, J.;Park, S.;Kwon, T.
    • Journal of the Optical Society of Korea
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    • v.11 no.2
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    • pp.76-81
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    • 2007
  • The compound refractive X-ray lens (CRL) for focusing hard X-rays is investigated to determine the parameters such as the focal length, the focal spot size, and spatial distribution at the focal spot using a simple theoretical calculations and CRLs fabricated by the self-assembly method. The number of individual compound lenses are defined for the given focal length of 1 m. The X-ray energy of 1 to 40 keV is used in the calculations. The CRL for focusing hard X-rays which generated from the X-ray tube is fabricated by nanoparticle-polymer composite in the form of circular concaves. The self-assembly method is applied to form the nanoaluminum-poly (methly meth-acrylate) composite and carbon-polymer composite CRL lenses. Aluminum nanoparticles of 100 nm and carbon microparticles are diffused in the polymer solution then the high gravity up to 6000G is applied in it to form the concave lens shape. X-ray energy at 8 keV is used for characterization of the composite CRLs. The FWHM of intensity for the fabricated nanoaluminium composite CRL system, N=10 is measured as 1.8 mm, which would give about $70{\mu}m$ in FWHM at 1 m of the focal length.

Femtosecond laser pattering of ITO film on flexible substrate (펨토초 레이저를 이용한 플렉시블 ITO 패터닝 연구)

  • Sohn, Ik-Bu;Kim, Young-Seop;Noh, Young-Chul
    • Laser Solutions
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    • v.13 no.1
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    • pp.11-15
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    • 2010
  • Indium tin oxide (ITO) provides high electrical conductivity and transparency in the visible and near IR (infrared) wavelengths. Thus, it is widely used as a transparent electrode for the fabrication of liquid crystal displays (LCDs) and organic light emitting diode displays (OLRDs), photovoltaic devices, and other optical applications. Lasers have been used for removing coating on polymer substrate for flexible display and electronic industry. In selective removal of ITO layer, laser wavelength, pulse energy, scan speed, and the repetition rate of pulses determine conditions, which are efficient for removal of ITO coating without affecting properties of the polymer substrate. ITO coating removal with a laser is more environmentally friendly than other conventional etching methods. In this paper, pattering of ITO film from polymer substrates is described. The Yb:KGW femtosecond laser processing system with a pulse duration of 250fs, a wavelength of 1030nm and a repetition rate of 100kHz was used for removing ITO coating in air. We can remove the ITO coating using a scanner system with various pulse energies and scan speeds. We observed that the amount of debris is minimal through an optical and a confocal microscope, and femtosecond laser pulses with 1030nm wavelength are effective to remove ITO coating without the polymer substrate ablation.

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Fluorescence Switching of Conjugated Polyelectrolyte based on Polydiphenylacetylene

  • Lee, W.E.;Kim, J.H.;Sakaguchi, T.;Kwak, G.;Lee, C.L.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.245.1-245.1
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    • 2013
  • Polydiphenylacetylene (PDPA) derivatives are a class of conjugated polymer that contain intramolecular excimer emission originating the intramolecular stack structure. In contrast with conventional conjugated polymer, the fluorescence property of PDPA significantly depends on the intramolecular stack structure. In this regard, herein, we investigated new fluorescence switching mechanism of conjugated polyelectrolyte (CPE) based on PDPA. The developed CPE showed relatively weak fluorescence emission in water, while the polymer exhibited a great fluorescence amplification behavior by electrostatic complex with proteins. In addition, the CPE is highly sensitive to binding with a little protein despite of turn-on type fluorescence response. We found that the fluorescence switching of the CPE closely relate to a perturbation of the intramolecular stack structure. The new fluorescence switching mechanism of the CPE is very useful for protein assays and discrimination and it also would be provide new sensing approaches as basic sensing mechanism.

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Ultraviolet Light Sensor Based on an Azobenzene-polymer-capped Optical-fiber End

  • Cho, Hee-Taek;Seo, Gyeong-Seo;Lim, Ok-Rak;Shin, Woojin;Jang, Hee-Jin;Ahn, Tae-Jung
    • Current Optics and Photonics
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    • v.2 no.4
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    • pp.303-307
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    • 2018
  • We propose a simple ultraviolet (UV) sensor consisting of a conventional single-mode optical fiber capped with an azobenzene-moiety-containing polymer. The UV light changes the dimensions of the azobenzene polymer, as well as the refractive index of the material. Incident light with a wavelength of 1550 nm was reflected at the fiber/polymer and polymer/air interfaces, and interference of the reflected beams resulted in spectral interference that shifted the wavelength by 0.78 nm at a UV input power of $2.5mW/cm^2$. The UV sensor's response to wavelength is nonlinear and stable. The response speed of the sensor is limited by detection noise, which can be improved by modifying the insertion loss of the UV sensor and the signal-to-noise ratio of the detection system. The proposed compact UV sensor is easy to fabricate, is not susceptible to electromagnetic interference, and only reacts to UV light.

Multiwalled Carbon Nanotubes Functionalized with PS via Emulsion Polymerization

  • Park, In-Cheol;Park, Min;Kim, Jun-Kyung;Lee, Hyun-Jung;Lee, Moo-Sung
    • Macromolecular Research
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    • v.15 no.6
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    • pp.498-505
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    • 2007
  • This study demonstrated the in-situ functionalization with polymers of multi-walled carbon nanotubes (MWNTs) via emulsion polymerization. Polystyrene-functionalized MWNTs were prepared in an aqueous solution containing styrene monomer, non-ionic surfactant and a cationic coupling agent ([2-(methacryloyloxy)ethyl]trime-thylammonium chloride (MATMAC)). This process produced an interesting morphology in which the MWNTs, consisting of bead-string shapes or MWNTs embedded in the beads, when polymer beads were sufficiently large, produced nanohybrid material. This morphology was attributed to the interaction between the cationic coupling agent and the nanotube surface which induced polymerization within the hemimicellar or hemicylindrical structures of surfactant micelles on the surface of the nanotubes. In a solution containing MATMAC alone without surfactant, carbon nanotubes (CNTs) were not well-dispersed, and in a solution containing only surfactant without MATMAC, polymeric beads were synthesized in isolation from CNTs and continued to exist separately. The incorporation of MATMAC and surfactant together enabled large amounts of CNTs (> 0.05 wt%) to be well-dispersed in water and very effectively encapsulated by polymer chains. This method could be applied to other well-dispersed CNT solutions containing amphiphilic molecules, regardless of the type (i.e., anionic, cationic or nonionic). In this way, the solubility and dispersion of nanotubes could be increased in a solvent or polymer matrix. By enhancing the interfacial adhesion, this method might also contribute to the improved dispersion of nanotubes in a polymer matrix and thus the creation of superior polymer nanocomposites.

Polymer Waveguide Apodized Grating for Narrow-Bandwidth High-Reflectivity Wavelength Filters (협대역 고반사 파장 필터 구현을 위한 폴리머 광도파로 에포다이즈드 격자)

  • Lee, Won-Jun;Huang, Guanghao;Shin, Jin-Soo;Oh, Min-Cheol
    • Korean Journal of Optics and Photonics
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    • v.26 no.4
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    • pp.203-208
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    • 2015
  • Wavelength filters are essential components for selecting a certain wavelength channel of a WDM optical communication system. To realize wavelength filters with narrow bandwidth and high reflectivity, an apodized grating structure with length of 15 mm and index modulation of $5{\times}10^{-4}$ was designed. The device exhibited a reflectivity of 95%, 3-dB bandwidth of 0.28 nm, and 20-dB bandwidth of 0.70 nm on an 18 mm grating length.

Bragg Reflecting Waveguide Device Fabricated on a Flexible Substrate using a Nano-imprinting Technology (나노임프린팅 기술을 이용한 유연성 브래그 반사 광도파로 소자)

  • Kim, Kyung-Jo;Yi, Jeong-Ah;Oh, Min-Cheol
    • Korean Journal of Optics and Photonics
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    • v.18 no.2
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    • pp.149-154
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    • 2007
  • Bragg reflecting waveguide devices have been fabricated on a flexible polymer substrate utilizing a post lift-off process which could Provide excellent uniformity of grating Patterns on Plastic film. The 510 m Period Bragg grating pattern is made by two methods. In the first sample the grating is fabricated by exposing the laser interference pattern on a photoresist, and then it is inscribed by $O_2$ plasma etching. The grating pattern of the second sample is formed by a PDMS soft mold imprinting process. The selective adhesion property of SU-8 material for Au and Si surfaces is utilized to prepare a 100-mm thick plastic substrate. Single mode waveguide is fabricated on the plastic substrate using polymer materials with refractive indices of 1.540 and 1.430 for the core and the cladding layers, respectively. The Bragg grating on Plastic substrate does not show any degradation in its spectral response compared to the reference sample made on a silicon wafer.