• Title/Summary/Keyword: polymer pattern

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The Effect of Energy-absorbing layers on Micro-patterning of Magnetic Metal Films using Nd:YAG Laser (Nd:YAG Laser를 이용한 자성금속막의 패턴 식각에 있어서 에너지 흡수층이 미치는 영향)

  • 이주현;채상훈;서영준;송재성;민복기;안승준
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.538-544
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    • 2000
  • The laser patterning of sputter-deposited CoNdZr/Cu/CoNbZr multi-layered films had been tried using Nd:YAG laser. However generally it is very difficult to remove metal films because of their high reflectance of the laser on the surfaces. As a counterproposal for this problem authors for the first time tried to deposit energy-absorbing layers on the metal films and then irradiated the laser on the surfaces of energy-absorbing layers. Here the energy-absorbing layers consisted of laser energy-absorbing fine powders and binding polymers. Three kinds of powders for the energy-absorbing layers had been used to see the difference in the pattern formation with the degree of laser energy absorption. They were electrically conductive silver powders insulating BaTiO$_3$powder and semiconducting carbon powder. Remarkable difference in width of the formed pattern and the roughness of pattern edge were observed with the characteristic of the powder for the energy-absorbing layer. The pattern width using carbon paste was about three times larger than that using BaTiO$_3$paste. It was observed that the energy-absorbing layer with carbon was the most effective on this micro-patterning.

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Direct Patterning of Self Assembled Nano-Structures of Block Copolymers via Electron Beam Lithography

  • Yoon Bo Kyung;Hwang Wonseok;Park Youn Jung;Hwang Jiyoung;Park Cheolmin;Chang Joonyeon
    • Macromolecular Research
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    • v.13 no.5
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    • pp.435-440
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    • 2005
  • This study describes a method where the match of two different length scales, i.e., the patterns from self-assembled block copolymer (<50 nm) and electron beam writing (>50 nm), allow the nanometer scale pattern mask. The method is based on using block copolymers containing a poly(methyl methacrylate) (PMMA) block, which is subject to be decomposed under an electron beam, as a pattern resist for electron beam lithography. Electron beam on self assembled block copolymer thin film selectively etches PMMA microdomains, giving rise to a polymeric nano-pattern mask on which subsequent evaporation of chromium produces the arrays of Cr nanoparticles followed by lifting off the mask. Furthermore, electron beam lithography was performed on the micropatterned block copolymer film fabricated by micro-imprinting, leading to a hierarchical self assembled pattern where a broad range of length scales was effectively assembled, ranging from several tens of nanometers, through submicrons, to a few microns.

Behavior of FRP-reinforced steel plate shear walls with various reinforcement designs

  • Seddighi, Mehdi;Barkhordari, Mohammad A.;Hosseinzadeh, S.A.A.
    • Steel and Composite Structures
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    • v.33 no.5
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    • pp.729-746
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    • 2019
  • The nonlinear behavior of single- and multi-story steel plate shear walls (SPSWs) strengthened with three different patterns of fiber reinforced polymer (FRP) laminates (including single-strip, multi-strip and fully FRP-strengthened models) is studied using the finite element analysis. In the research, the effects of orientation, width, thickness and type (glass or carbon) of FRP sheets as well as the system aspect ratio and height are investigated. Results show that, despite an increase in the system strength using FRP sheets, ductility of reinforced SPSWs is decreased due to the delay in the initiation of yielding in the infill wall, while their initial stiffness does not change significantly. The content/type/reinforcement pattern of FRPs does affect the nonlinear behavior characteristics and also the mode and pattern of failure. In the case of multi-strip and fully FRP-strengthened models, the use of FPR sheets almost along the direction of the infill wall tension fields can maximize the effectiveness of reinforcement. In the case of single-strip pattern, the effectiveness of reinforcement is decreased for larger aspect ratios. Moreover, a relatively simplified and approximate theoretical procedure for estimating the strength of SPSWs reinforced with different patterns of FRP laminates is presented and compared with the analytical results.

NUMERICAL STUDY ON THE FLOW CHARACTERISTICS OF MANIFOLD FEED-STREAM IN POLYMER ELECTROLYTE FUEL CELL (고분자 전해질 연료전지의 매니폴드 설계 및 해석)

  • JUNG Hye-Mi;UM Sukkee;PARK Jungsun;LEE Won-Yong;KIM Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.260-263
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    • 2005
  • The effects of internal manifold designs the reactant feed-stream in Polymer Electrolyte Fuel Cells (PEFCs) is studied to figure out mass flow-distribution patterns over an entire fuel cell stack domain. Reactants flows are modeled either laminar or turbulent depending on regions and the open channels in the bipolar plates are simulated by porous media where permeability should be pre-determined for computational analysis. In this work, numerical models for reactant feed-stream in the PEFC manifolds are classified into two major flow patterns: Z-shape and U-shape. Several types of manifold geometries are analyzed to find the optimal manifold configurations. The effect of heat generation in PEFC on the flow distribution is also investigated applying a simplified heat transfer model in the stack level (i.e. multi-cell electrochemical power-generation unit). This modeling technique is well suited for many large scale problems and this scheme can be used not only to account for the manifold flow pattern but also to obtain information on the optimal design and operation of a PEMC system.

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A Study on Module Design and Performance of Polymer Arrester (폴리머 피뢰기의 모듈 설계 및 성능에 관한 연구)

  • Cho, Han-Goo;Chun, Jong-Uk;Kang, Yeong-Kil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05e
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    • pp.108-111
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    • 2003
  • The main objective of this paper is to module design and pressure relief test a new type of polymer gapless surge arrester for power distribution line. Metal oxide surge arrester for most electric power system applications, power distribution line and electric train are now being used extensively to protect overvoltage due to lightning. Surge arresters with porcelain housing must not have explosive breakage of the housing to minimize damage to other equipment when subjected to internal high short circuit current. When breakdown of gapless elements in a surge arrester occurs due to flashover, fault short current flows through the arrester and internal pressure of the arrester rises. The pressure rise can usually be limited by fitting a pressure relief diaphragm and transferring the arc from the inside to the outside of the housing. However, there is possibility of porcelain fragmentation caused by the thermal shock, pressure rise, etc. Non-fragmenting of the housing is the most desired way to prevent damage to other equipment. The pressure change which is occurred by flashover become discharge energy. This discharge energy raises to damage arrester housing and arrester housing is dispersed as small fragment. Therefore, the pressure relief design is requested to obstruct housing dispersion.

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Numerical Study on the Thermal and Flow Characteristics of Manifold Feed-Stream in Polymer Electrolyte Fuel Cells (고분자 전해질 연료전지 매니폴드의 열유동 특성에 관한 수치적 연구)

  • Jung Hye-Mi;Um Sukkee;Sohn Young-Jun;Park Jungsun;Lee Won-Yong;Kim Chang-Soo
    • New & Renewable Energy
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    • v.1 no.2 s.2
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    • pp.41-52
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    • 2005
  • The effects of internal manifold designs on the reactants feed-stream in Polymer Electrolyte Fuel Cells [PEFCs] is studied to figure out flow and thermal distribution patterns over an entire fuel cell stack. Reactants flows are modeled either laminar of turbulent depending on regions and the open channels in the bipolar plates are simulated by porous media where permeability should be pre-deter-mined for computational analysis. In this work, numerical models for reactants feed-stream In the PEFC manifolds are classified Into two major flow patterns: Z-shape and U-shape. Several types of manifold geometries are analyzed to find the optimal manifold configurations. The effect of heat generation in PEFC on the flow distribution is also Investigated applying a simplified heat transfer model in the stack level (i.e. multi-cell electrochemical power-generation unit). This modeling technique Is well suited for many large scale problems and this scheme can be used not only to account for the manifold flow pattern but also to obtain Information on the optimal design and operation of PEFC systems.

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The Effect of Molecular Weight and the Linear Velocity of Drum Surface on the Properties of Electrospun Poly(ethylene terephthalate) Nonwovens

  • Kim, Kwan-Woo;Lee, Keun-Hyung;Khil, Myung-Seob;Ho, Yo-Seung;Kim, Hak-Yong
    • Fibers and Polymers
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    • v.5 no.2
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    • pp.122-127
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    • 2004
  • In this study, we evaluated the effect of the molecular weight of the polymer on electrospun poly(ethylene terephthalate) (PET) nonwovens, and their mechanical properties as a function of the linear velocity of drum surface. Polymer solutions and electrospun PET nonwovens were characterized by means of viscometer, tensiometer, scanning electron microscope(SEM), wide angle X-ray diffraction measurement (WAXD) and universal testing machine (UTM). By keeping the uniform solution viscosity, regardless of molecular weight differences, electrospun PET nonwovens with similar average diameter could be obtained. In addition, the mechanical properties of the electrospun PET nonwovens were strongly dependent on the linear velocity of drum surface. From the results of the WAXD scan, it was found that the polymer took on a particular molecular orientation when the linear velocity of drum surface was increased. The peaks became more definite and apparent, evolving from an amorphous pattern at 0 m/min to peaks and signifying the presence of crystallinity at 45 m/min.

Compatibilization and Properties of Modified Starch-Poly(lactic acid) Blend (변성 전분-폴리락트산 블렌드의 상용성 및 물성)

  • 이상환;김덕준;김지흥;이동현;심상준;남재도;계형산;이영관
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.519-523
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    • 2004
  • Starch was grafted with maleic anhydride by melt process and then the grafted starch was blended with poly(lactic acid). The thermal properties of the poly(lactic acid), poly(lactic acid)/starch, and poly(lactic acid)/ modified starch were observed by DSC and TGA analysis. In the case of poly(lactic acid)/modified starch, an additional melting peak at 1$65^{\circ}C$ accompanying with 172$^{\circ}C$ assigned to pure poly(lactic acid) melting transition was clearly displayed in DSC analysis. Also, smooth decomposition pattern between starch and poly(lactic acid) was also monitored in poly(lactic acid)/modified starch blend by TGA analysis. The modulus of poly(lactic acid)/modified starch was 12% higher than that of poly(lactic acid)/starch. The thermal and mechanical characteristics of poly(lactic acid)/modified starch might be due to the enhanced compatibilization between each components, which was also observed in SEM analysis.

Photopatternability of Poly(vinylcarbazole) Bearing Cinnamate Pendants and Its Blends with a Soluble Poly(p-phenylene vinylene) Derivative

  • Yu, Young-Jun;Lee, Seung-Hun;Choi, Dong-Hoon;Jin, Jung-Il;Tessler, Nir
    • Macromolecular Research
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    • v.15 no.2
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    • pp.142-146
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    • 2007
  • Poly[(1-(9-carbazoly1)ethylene)-co-(3-cinnamoyloxyoctyl-9-carbazolyl)] ethylene (PVK-Cin) was prepared by tethering cinnamate pendants to a carbazole group via an octylene spacer. The photopatternability of the new PVK based-polymer was investigated using a photocrosslinking reaction under UV light illumination $(\lambda=254nm)$. Blends of the PVK-Cin and a soluble poly(phenylene vinylene) (CzEh-PPV) were employed to study the photocrosslinking behavior. Well resolved lithographic patterns were observed in these polymer systems. PVK-Cin produced a blue light emitting pattern both before and after the photocrosslinking reaction. The blends of PVK-Cin and CzEh-PPV also showed corresponding emissions at 398 and 525 (560) nm in the film state.

Operation Performance of a Polymer Electrolyte Fuel Cell Cogeneration System for Residential Application (가정용 고분자연료전지 시스템의 운전 방법에 따른 성능 비교)

  • Lee, W.Y.;Jeong, K.S.;Yu, S.P.;Um, S.K.;Kim, C.S.
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.4
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    • pp.364-371
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    • 2005
  • Fuel cell systems(FCS) have a financial and environmental advantage by providing electricity at a high efficiency and useful heat. For use in a residence, a polymer electrolyte fuel cell system(PEFCS) with a battery pack and a hot water storage tank has been modelled and simulated. The system is operated without connection to grid line. Its electric conversion efficiency and heat recovery performance are highly dependent on operation strategies and also on the seasonal thermal and electric load pattern. The output of the fuel cell is controlled stepwise as a function of the state of the battery and/or the storage water tank. In this study various operation strategies for cogeneration fuel cell systems are investigated. Average fuel saving rates at different seasons are calculated to find proper load management strategy. The scheme can be used to determine the optimal operating strategies of PEFCS for residential and building applications.