Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
권호 표지

Photopatternability of Poly(vinylcarbazole) Bearing Cinnamate Pendants and Its Blends with a Soluble Poly(p-phenylene vinylene) Derivative

  • Yu, Young-Jun (Department of Chemistry, Center for Electro- and Photo-Responsive Molecules, Korea University) ;
  • Lee, Seung-Hun (Department of Chemistry, Center for Electro- and Photo-Responsive Molecules, Korea University) ;
  • Choi, Dong-Hoon (Department of Chemistry, Center for Electro- and Photo-Responsive Molecules, Korea University) ;
  • Jin, Jung-Il (Department of Chemistry, Center for Electro- and Photo-Responsive Molecules, Korea University) ;
  • Tessler, Nir (Microelectronic & Nanoelectronic Centers, Electrical Engineering Department)
  • Published : 2007.03.31
Download PDF
⟨ Previous Next ⟩

Abstract

Poly[(1-(9-carbazoly1)ethylene)-co-(3-cinnamoyloxyoctyl-9-carbazolyl)] ethylene (PVK-Cin) was prepared by tethering cinnamate pendants to a carbazole group via an octylene spacer. The photopatternability of the new PVK based-polymer was investigated using a photocrosslinking reaction under UV light illumination $(\lambda=254nm)$. Blends of the PVK-Cin and a soluble poly(phenylene vinylene) (CzEh-PPV) were employed to study the photocrosslinking behavior. Well resolved lithographic patterns were observed in these polymer systems. PVK-Cin produced a blue light emitting pattern both before and after the photocrosslinking reaction. The blends of PVK-Cin and CzEh-PPV also showed corresponding emissions at 398 and 525 (560) nm in the film state.

Keywords

References

  1. J. Kido, K. Hougawa, and K. Nagai, Appl. Phys. Lett., 63, 2627 (1993) https://doi.org/10.1063/1.109817
  2. I. H. Campbell, D. L. Smith, R. L. Martin, and J. P. Ferraris, Phys. Rev. B, 65, 085210 (2002)
  3. S. H. Jin, M. Y. Kim, K. Lee, and Y. S. Gal, J. Am. Chem. Soc., 126, 2474 (2004) https://doi.org/10.1021/ja037954k
  4. Mark T. Bernius, M. Inbasekaran, and Weishi Wu, Adv. Mater., 12, 1737 (2000)
  5. C. H. Cheon, S. H. Joo, K. Kim, and J.-I. Jin, Macromolecules, 38, 6336 (2005)
  6. C. Kocher, A. Mountali, and P. Smith, Adv. Funct. Mater., 11, 31 (2001)
  7. S. Holdcroft, Adv. Mater., 13, 1753 (2003) https://doi.org/10.1002/adfm.200390003
  8. M. Naparothinam and Jagadese J. Vittal, Macromol. Rapid Commun., 27, 1091 (2006)
  9. J. F. Morin, P. L. Boudreault, and M. Leclerc, Macromol. Rapid Commun., 23, 1032 (2002)
  10. J. Li, C. Ma, J. Tang, and Shuittong Lee, Chem. Mater., 17, 615 (2005)
  11. N. Hanai, M. Sumitomo, and H. Yanagi, Thin Solid Films, 331, 106 (1998)
  12. K. Kim, Y. R. Hong, and J.-I. Jin, J. Mater. Chem., 11, 3023 (2001)
  13. W. L. F. Armarego and D. D. Perrin, Purification of Laboratory Chemicals, 4th Edition, Pergamon Press, New York, 1996, p.334
  14. N. Ono, T. Yamada, T. Saito, and A. Kaji, Bull. Chem. Soc. Jpn., 51, 2401 (1978) https://doi.org/10.1246/bcsj.51.978
  15. S. Perny and P. L. Barny, Liq. Cryst., 27, 329 (2000)
  16. A. Rivaton, B. Mailhot, G. Derderian, and J.-L. Gardette, Macromolecules, 36, 5815 (2003)
  17. Y. Hua and J. V. Crivello, Macromolecules, 34, 2488 (2001) https://doi.org/10.1021/ma002404h
  18. S. I. Semenova, H. Ohya, and K. Soontarapa, Desalination, 110, 251 (1997)