• 제목/요약/키워드: polyamide fiber

검색결과 109건 처리시간 0.028초

A Study on the Development of a Hybrid Fiber Reinforced Composite for a Type 4 CNG Vessel (CNG용 Type 4 하이브리드 섬유 복합재 용기 개발에 대한 연구)

  • Cho, Sung-min;Cho, Min-sik;Jung, Geunsung;Lee, Sun-kyu;Lee, Seung-kuk;Park, Ki-dong;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • 제16권4호
    • /
    • pp.97-103
    • /
    • 2017
  • The objective of this study is to develop and commercialize an on-board fuel storage system for CNG vehicles. A type 4 vessel is made of resin-impregnated continuous filament windings on a polyamide (PA6) liner. In particular, this study localized the PA6 liner's fabrication and development. To analyze the filament winding, a specimen test was performed, and the results were verified values obtained using finite element analysis. In this study, the filament winding and fibers were optimized for a 207 bar composite cylinder in a compressed natural gas vehicle.

Characterization of Thermal Degradation of Polymide 66 Composite: Relationship between Lifetime Prediction and Activation Energy (폴리아미드 66 복합소재의 열 열화 특성: 수명 예측과 활성화 에너지의 상관관계)

  • Jung, Won-Young;Weon, Jong-Il
    • Polymer(Korea)
    • /
    • 제36권6호
    • /
    • pp.712-720
    • /
    • 2012
  • Thermal degradation for glass fiber-reinforced polyamide 66 composite (PA 66) with respect of thermal exposure time has been investigated using optical microscopy, scanning electron microscopy and Fourier transform infrared spectroscopy. As the thermal exposure time was prolonged, a slight increase in tensile strength for only initial stage and afterward, a proportional decrease of tensile strength was observed. These results can be explained by the increase of crystallinity, followed by the increase of crosslinking density, chain scission and the decrease in chain mobility, due to thermal oxidation with the exposure time. Fourier transform infrared spectroscopy results showed the increase of ketone peak and silica peak on the surface of thermally exposed PA 66. In addition, the thermal decomposition kinetics of PA 66 was analyzed using thermogravimetric analysis at three different heating rates. The relationship between activation energy and lifetime-prediction of PA 66 was investigated by several methodologies, such as statistical tool, UL 746B, Ozawa and Kissinger. The activation energy determined by thermogravimetric analysis had a relatively large value compared with that from the accelerated test. This may result in over-estimating the lifetime of PA 66. In this study, a master curve of exponential fitting has been developed to extrapolate the activation energy at various service temperatures.

A Study on the mechanical properties of fabrics by fabric trend themes -2002/03 Fall & Winter season for women′s wear- (소재 트랜드 테마별 직물의 역학적 특성 연구 -2002/03 여성복 추동 시즌을 중심으로-)

  • 주정아;유효선
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • 제27권8호
    • /
    • pp.958-968
    • /
    • 2003
  • The purpose of this study was to clarify the different mechanical properties of fabrics among the theme groups classified by fashion fabric trend. This study can be useful for fabric marketers and planners to design new products. In order to carry out this study, the fabric samples of representative theme for‘2002/03 F/W fashion fabric trend were collected from a fashion company and were measured to analyze the mechanical properties, hand value(H.V) and total hand value(T.H.V) by KES-FB System. The results were as follows. 1. The theme-A of‘Luxury, Elegance’was consisted of wool, rayon and PET and had a lower B, 2HB of bending properties and a lower G and 2HG5 of shear properties. The theme-B of‘Technical, Functional’was consisted of synthetic fibers such as PET, PA, PU and elastic fiber and had a higher MIU and a lower MMD, SMD of surface properties. The theme-C of‘Vintage, Aged’was consisted of mostly cotton and had the highest B and 2HB. The theme-D of‘Fancy, Airy’was consisted of mostly woolen wool, polyacryl and polyamide and had a high MMD and SMD of surface properties and a high LC and RC of compression properties. 2. As the results of analyzing H.V and T.H.V through KES-FB system, the theme-A showed a higher Smoothness and lower Stiffness. The theme-B had a lower Smoothness, Fullness, Soft feeling and T.H.V and the theme-C had the highest Stiffness. The theme-D showed the highest Fullness and Soft Feeling but the lowest Stiffness.

Fishing power estimation of biodegradable traps in the East Sea (동해 생분해성 통발의 어획성능 평가)

  • Bae, Bong-Seong;An, Heui-Chun;Jeong, Eui-Cheol;Park, Hae-Hoon;Park, Seong-Wook;Park, Chang-Doo
    • Journal of the Korean Society of Fisheries and Ocean Technology
    • /
    • 제46권4호
    • /
    • pp.292-301
    • /
    • 2010
  • For an effective management of fisheries resources, it is very important that to make clean inhabitation environment and to preserve fisheries resources. The material which is mainly used as fishing gear in modern times, is polyethylene, polypropylene, polyamide, etc., chemical fiber. And lost fishing gears which are make of these, occur ghost fishing and ocean pollution. To solve these problem, we development biodegradable fishing trap using the polybutylene succinate (PBS). Developed traps are for red snow crab (Chionoecetes japonicus) and shrimp, major traps in the East Sea, and we carried out fishing research using two kind traps in the coastal sea of Ayajin-port (Goseong) to analysis fishing efficiency of PE trap and PBS trap. As a result for fishing experiment (year 2005-2006) of red snow crab trap, two kind traps were almost the same in catches and length composition. During a experiment, parts of meshes, used for over 1 year, were cut by biodegradation. As a result for fishing experiment (year 2007) of shrimp trap, northern shrimp (Pandalus eous), coonstripe shrimp (Pandalus hypsinotus) and morotoge shrimp (Pandalopsis japonica) were catched, and the almost is northern shrimp. Two kind traps were almost the same in catches and length composition. In accordance with these result, it is recommended that the developed traps are have to commercialized because the fishing powers of PE traps and PBS traps were same. But biodegradation speed is have to controled in consideration of ocean microorganism volume and traps life.

Preparation and Characterization of Ultra-fine PAI Continuous Fibers Using Electrospinning Process (전기방사 공정을 이용한 극세 PAI 연속사 제조 방법에 관한 연구)

  • Lee, Jae-Rock;Ji, Seung-Yong;Hong, Young-Taik;Park, Soo-Jin
    • Applied Chemistry for Engineering
    • /
    • 제17권3호
    • /
    • pp.331-334
    • /
    • 2006
  • In this study, the ultra-fine fibers (UFs) having an alignment were prepared by electrospinning process, using different collectors made from various materials and collecting methods. A spinning solution was prepared by dissolving poly(amide-co-imide) (PAI) in NMP. The UFs were prepared by using various collectors and collecting methods, and the fibrous shapes were observed by SEM. As a result, a sort of materials of collectors and the collecting methods had not influenced on the average diameters of fibers but the forms of them. The just accumulated UFs on the collectors formed net structures, which had no alignment. On the contrary, the continuously collected UFs formed long fibers with alignment. It was found that the water collector played the roles of the fiber haul, temporary collector, moving path of fibers, and caused some friction between fibers and water, attributed to the formation of continuous UFs at a suitable collecting speed.

Surface properties and interception behaviors of GO-TiO2 modified PVDF hollow fiber membrane

  • Li, Dongmei;Liang, Jinling;Huang, Mingzhu;Huang, Jun;Feng, Li;Li, Shaoxiu;Zhan, Yongshi
    • Membrane and Water Treatment
    • /
    • 제10권2호
    • /
    • pp.113-120
    • /
    • 2019
  • To investigate surface properties and interception performances of the new modified PVDF membrane coated with Graphene Oxide (GO) and nano-$TiO_2$ (for short the modified membrane) via the interface polymerization method combined with the pumping suction filtration way, filtration experiments of the modified membrane on Humic Acid (HA) were conducted. Results showed that the contact angle (characterizing the hydrophilicity) of the modified membrane decreased from $80.6{\pm}1.8^{\circ}$ to $38.6{\pm}1.2^{\circ}$. The F element of PVDF membrane surface decreased from 60.91% to 17.79% after covered with GO and $TiO_2$. O/C element mass ratio has a fivefold increase, the percentage of O element on the modified membrane surface increased from 3.83 wt% to 20.87%. The modified membrane surface was packed with hydrophilic polar groups (like -COOH, -OH, C-O, C=O, N-H) and a functional hydrophilic GO-polyamide-$TiO_2$ composite configuration. This configuration provided a rigid network structure for the firm attachment of GO and $TiO_2$ on the surface of the membrane and for a higher flux as well. The total flux attenuation rate of the modified membrane decreased to 35.6% while 51.2% for the original one. The irreversible attenuation rate has dropped 71%. The static interception amount of HA on the modified membrane was $158.6mg/m^2$, a half of that of the original one ($295.0mg/m^2$). The flux recovery rate was increased by 50%. The interception rate of the modified membrane on HA increased by 12% approximately and its filtration cycle was 2-3 times of that of the original membrane.

Analysis of Material Properties According to Compounding Conditions of Polymer Composites to Reduce Thermal Deformation (열변형 저감을 위한 고분자 복합소재 배합 조건에 따른 재료특성 분석)

  • Byun, Sangwon;Kim, Youngshin;Jeon, Euy sik
    • Journal of the Semiconductor & Display Technology
    • /
    • 제21권1호
    • /
    • pp.148-154
    • /
    • 2022
  • As the 4th industrial age approaches, the demand for semiconductors is increasing enough to be used in all electronic devices. At the same time, semiconductor technology is also developing day by day, leading to ultraprecision and low power consumption. Semiconductors that keep getting smaller generate heat because the energy density increases, and the generated heat changes the shape of the semiconductor package, so it is important to manage. The temperature change is not only self-heating of the semiconductor package, but also heat generated by external damage. If the package is deformed, it is necessary to manage it because functional problems and performance degradation such as damage occur. The package burn in test in the post-process of semiconductor production is a process that tests the durability and function of the package in a high-temperature environment, and heat dissipation performance can be evaluated. In this paper, we intend to review a new material formulation that can improve the performance of the adapter, which is one of the parts of the test socket used in the burn-in test. It was confirmed what characteristics the basic base showed when polyamide, a high-molecular material, and alumina, which had high thermal conductivity, were mixed for each magnification. In this study, functional evaluation was also carried out by injecting an adapter, a part of the test socket, at the same time as the specimen was manufactured. Verification of stiffness such as tensile strength and flexural strength by mixing ratio, performance evaluation such as thermal conductivity, and manufacturing of a dummy device also confirmed warpage. As a result, it was confirmed that the thermal stability was excellent. Through this study, it is thought that it can be used as basic data for the development of materials for burn-in sockets in the future.

Study on the Hollow Fiber Nano-composite Membrane Preparation onto the Porous PVDF Membrane Surfaces using the Interfacial Polymerization (다공성 PVDF 막의 polyamide 계면중합법처리를 통한 나노 중공사 복합막 제조 연구)

  • Kang, Su Yeon;Cho, Eun Hye;Kim, Ihl hyung;Kim, Cheong Sik;Rhim, Ji Won
    • Membrane Journal
    • /
    • 제24권2호
    • /
    • pp.107-112
    • /
    • 2014
  • The composite membranes were prepared on the surface of hydrophobic porous poly (vinylidene fluoride) (PVDF) hollow fiber membranes through the interfacial polymerization. The preparation variables were the concentrations of piperazine (PIP), trimesoyl chloride (TMC) and the contents of polyethylene glyco l (PEG). The separation characterization of the resulting membranes were carried out for aqueous 100 ppm solution of NaCl, $CaSO_4$, and $MgCl_2$ and also mixed 300 ppm solution of NaCl and $CaSO_4$ in terms of the flux and rejection. Both the flux and rejection were the highest when the interfacial polymerization was conducted using TMC. When TMC concentration was 0.1 wt%, the flux and rejection were shown 48.3 LMH ($L/m^2{\cdot}hr$) and 59%, respectively. To improve the flux, the annealing post-treatment and the addition of PEG into piperazine were done. As expected, the overall flux was enhanced while the rejection was reduced.

Measurement of Viscosity Behavior in In-situ Anionic Polymerization of ε-caprolactam for Thermoplastic Reactive Resin Transfer Molding (반응액상성형에서 ε-카프로락탐의 음이온 중합에 따른 점도 거동 평가)

  • Lee, Jae Hyo;Kang, Seung In;Kim, Sang Woo;Yi, Jin Woo;Seong, Dong Gi
    • Composites Research
    • /
    • 제33권2호
    • /
    • pp.39-43
    • /
    • 2020
  • Recently, fabrication process of thermoplastic polyamide-based composites with recyclability as well as impact, chemical, and abrasion resistance have been widely studied. In particular, thermoplastic reactive resin transfer molding (TRTM) in which monomer with low viscosity is injected and in-situ polymerized inside mold has received a great attention, because thermoplastic melts are hard to impregnate fiber preform due to their very high viscosity. However, it is difficult to optimize the processing conditions because of high reactivity and sensitivity to external environments of the used monomer, ε-caprolactam. In this study, viscosity as an important process parameter in TRTM was measured during in-situ anionic polymerization of ε-caprolactam and the solutions for problems caused by high polymerization rate and sensitivity to moisture and oxygen were suggested. Reliability of the improved measurement technique was verified by comparing the viscosity behavior at various environmental conditions including humidity and atmosphere, and it is expected to be helpful for optimization of TRTM process.