• Title/Summary/Keyword: poly

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Compatibilization and Properties of Modified Starch-Poly(lactic acid) Blend (변성 전분-폴리락트산 블렌드의 상용성 및 물성)

  • 이상환;김덕준;김지흥;이동현;심상준;남재도;계형산;이영관
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.519-523
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    • 2004
  • Starch was grafted with maleic anhydride by melt process and then the grafted starch was blended with poly(lactic acid). The thermal properties of the poly(lactic acid), poly(lactic acid)/starch, and poly(lactic acid)/ modified starch were observed by DSC and TGA analysis. In the case of poly(lactic acid)/modified starch, an additional melting peak at 1$65^{\circ}C$ accompanying with 172$^{\circ}C$ assigned to pure poly(lactic acid) melting transition was clearly displayed in DSC analysis. Also, smooth decomposition pattern between starch and poly(lactic acid) was also monitored in poly(lactic acid)/modified starch blend by TGA analysis. The modulus of poly(lactic acid)/modified starch was 12% higher than that of poly(lactic acid)/starch. The thermal and mechanical characteristics of poly(lactic acid)/modified starch might be due to the enhanced compatibilization between each components, which was also observed in SEM analysis.

A Greedy Poly-jog Switch-Box Router(AGREE) (Poly-jog을 사용한 그리디 스위치박스 배선기)

  • Lee, Chul-Dong;Chong, Jong-Wha
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.4
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    • pp.88-97
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    • 1989
  • This paper proposes an efficient switch-box router which consists of two parts ; greedy poly-jog router and via minimizer. The greedy switch-box router of Luk, routes not only metal wires at horizontal tracks and poly-silicon wires at vertical tracks but also poly-siliocon wires ar horizontal tracks if necessary. The via minimizer reduces the number of vias and the wire length by fipping of each corner, parallel moving of wire segment, transformation metal into poly-silicon, and transformation poly-silicon into metal. The result is generated through the column-wise scan across the routing region. The expected time complexity is O(M(Nnet)). Where M, N, and Nnet are respectively the number of columns, rows, and nets in the routing region.

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Dispersion Polymerization of Acrylate Monomers in Supercritical $CO_2$ using GMA-functionalized Reactive Surfactant (초임계 이산화탄소에서 Glycidyl methacrylate 반응성 계면활성제를 이용한 아크릴레이트의 분산중합)

  • Park, Kyung-Kyu;Kang, Chang-Min;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.45 no.4
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    • pp.256-262
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    • 2010
  • Dispersion polymerization of methyl acrylate, ethyl acrylate, butyl acrylate, and glycidyl methacrylate were performed in supercritical $CO_2$ at $80\;^{\circ}C$ and 346 bar. Glycidyl methacrylate linked poly(dimethylsiloxane) (GMS-PDMS) surfactant, which was prepared by linking glycidyl methacrylate to monoglycidyl ether terminated PDMS with amino-propyltriethoxysilane, was used as surfactant for the dispersion polymerization in $CO_2$. The yield of the poly(alkyl acrylate) polymers, synthesized in $CO_2$ medium, decreased as the alkyl tail of the acrylate monomers increased. Poly(glycidyl methacrylate) and poly(methyl acrylate) were produced in bead form whereas poly(ethyl acrylate) and poly(butyl acrylate) were viscous liquid. The poly(glycidyl methacrylate) particles had a number average diameter of 2.45 ${\mu}m$ and monodisperse distribution. The poly(methyl acrylate) had a number average diameter of 0.52 ${\mu}m$ and the particle size distribution was bimodal. The glass transition temperatures ($T_g$) of the poly(glycidyl methacrylate) and the poly(alkyl acrylate) products were 4~9 K higher than the $T_g$ of the corresponding acrylate polymers synthesized in conventional processes.

FT-IR and Raman Spectroscopy for the Interaction between Poly(2-hydroxyethylmethacrylate) and Amino Acids (Poly(2-hydroxyethylmethacrylate)와 아미노산과의 상호작용에 관한 FT-IR과 Raman 분광학적 연구(II))

  • 김의락;정봉진
    • KSBB Journal
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    • v.11 no.5
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    • pp.557-564
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    • 1996
  • The interaction between poly(2-hydroxyethylmethacrylate)(poly(HEMA)) which is a material of contact lens containing approximately 45%o water and water soluble amino acids (alanine, arginine, glycine, lysine, methionine, proline, and serine) was investigated by using FT-IR and Raman spectroscopy. The results revealed that arginine and lysine had the strongest interaction with poly(HEMA) among amino acids. The interaction depended on the quantity of charges on ammo acids. They interacted predominately with hydroxyl groups in poly(HEMA).

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Stress Relaxation of Poly(methyl acrylate)-Poly(acrylonitrile) Copolymers (Poly(methyl acrylate)-Poly(acrylonitrile) 공중합체의 응력완화)

  • Kim, Nam-Jeong
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.223-230
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    • 2012
  • The rheological parameters of poly(methyl acrylate)-poly(acrylonitrile) copolymers were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The experimentals of stress relaxation were carried out using the tensile tester with the solvent chamber. The determination of rheological parameters was performed from computer calculation. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusions and viscosities and activation energies of flow segments.

Biodegradability of $Poly({\gamma}-benzyl{\;}L-Glutamate)/Poly(Ethylene Oxide)/poly({\gamma}-benzyl{\;}L-Glutamate)$ Block Copolymer in Mice

  • Oh, In-joon;Oh, Jhin-Yee;Cho, Chong-Su;Lee, Kang-Choon
    • Archives of Pharmacal Research
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    • v.18 no.1
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    • pp.8-11
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    • 1995
  • Biodegradability of poly $Poly({\gamma}-benzyl L-Glutamate)/poly(ethylene oxide)/Poly({\gamma}-benzyl L-Glutamate)$ block copolymer (GEG) having different content of poly(ethylene oxide) (PEO) were examined using magnetite as a tracer in mice. GEG microspheres containing magnetite were injected into mice through tail vein. Biodegradability and tissue distribution of microspheres were examined by analyzing the amount of magnetite in the microspheres recollected from mice organs after specific time interval. The results showed that GEG microsphere of high content of PEO was degraded more rapidly than those of low content of PEO in the mice organs.

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Electrocatalytic Reduction of Molecular Oxygen at Poly(1,8-diaminonaphthalene) and Poly(Co(II)-(1,8-diaminonaphthalene)) Coated Electrodes

  • Park, Hyun;Kwon, Tae-guen;Park, Deog-Su;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.27 no.11
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    • pp.1763-1768
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    • 2006
  • The application of poly(Co(II)-(1,8-diaminonaphthalene))(poly(Co-DAN)) and poly(1,8-diaminonaphthalene) (Poly(1,8-DAN)) to the electrocatalytic reduction of molecular oxygen was investigated, which were electrochemically grown by the potential cycling method on the glassy carbon electrodes. The reduction of oxygen at the polymer and its metal complex polymer coated electrodes were irreversible and diffusion controlled. The Poly(1,8-DAN) and Poly(Co-DAN) films revealed the potential shifts for the oxygen reduction to 30 mV and 110 mV, respectively, in an aqueous solution, compared with that of the bare electrode. Hydrodynamic voltammetry with a rotating ring-disk electrode showed that Poly(1,8-DAN) and Poly(Co-DAN) coated electrodes converted respectively 84% and 22% of $O_2$ to $H_2O$ via a four electron reduction pathway.

Compatibilizing Effect of Polystyrene-Poly(caprolactone) Block Copolymer Synthesized from Macroinitiator in Poly(2, 6-dimethyl-1, 4-phenylene oxide)/Poly(styrene-co-acrylonitrile) Blend (Poly(2, 6-dimethyl-1, 4-phenylene oxide)/Poly(styrene-co-acrylonitrile)블렌드에서 Macroinitiator로 합성한 Polystyrene-Poly(caprolactone) 블록공중합체의 상용제로서의 역할에 관한 연구)

  • Chung, Oong-Kwon;Jeong, Han-Mo;Yang, Sung-Bong;Yoon, Koo-Sik
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.247-255
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    • 1992
  • Polystyrene-poly(caprolactone) (PS-PCL) block copolymer was synthesized from macroazoinitiator, and its compatibilizing effect in poly(2, 6-dimethyl-1, 4-phenylene oxide) (PPO)/poly(styrene-co-acrylonitrile) (SAN, 25wt% acrylonitrile) blend was studied. PS block and PCL block in the block copolymer had shown miscibility with PPO and SAN respectively. The dissolution of SAN into PPO domain was promoted by the addition of the PS-PCL block copolymer.

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