• Applied Chemistry for Engineering
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• v.5 no.4
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• pp.624-629
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• 1994

Chitosan-g-poly(4-vinyl pyridine)membranes were prepared by crosslinking reaction using glutaraldehyde and glucose oxidase immobilized chitosan/acrylamide composite membranes were fabricated by chitosan-g-poly(4-vinyl-pyridine) copolymer and acrylamine. Water content and permeability of insulin through chitosan-g-poly(4-vinyl pyridine )membranes increased with decreasing the pH of the medium. Permeability of insulin through chitosan/acrylamide composite membranes increased with increasing the concentration of glucose.

• Macromolecular Research
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• v.17 no.7
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• pp.469-475
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• 2009

We investigated the feasibility of dispersion polymerization without any stabilizer, which has been considered essential for ensuring colloidal stability. By employing small amounts of a lyophilic comonomer, 4-vinyl pyridine, styrene was successfully polymerized by dispersion polymerization in aqueous alcohol without stabilizer to afford stable poly(styrene-co-4-vinyl pyridine) copolymer microspheres. The stable microspheres were produced in the 4-vinyl pyridine range of 2-15 wt% to styrene. Without 4-vinyl pyridine, severely coagulated particles were obtained, implying that the poly(4-vinyl pyridine) moiety endowed colloidal stability. The polymerization kinetics, behavior, and properties of the ultimate particles showed general features of dispersion polymerization. The study results suggest that stabilizer- tree dispersion polymerization is possible, thereby facilitating the synthesis of impurity(stabilizer)-tree polymer particles.

• Journal of Radiation Industry
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• v.4 no.4
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• pp.341-345
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• 2010

The surface functionalization of a fluoropolymer by ion beam-induced graft polymerization was described in this research. The surface of poly(tetrafluoroethylene) (PTFE) films were irradiated by a 150 keV $H^+$ ions, and 4-vinyl pyridine (4VP) as a functional monomer was then thermally graft polymerized on the irradiated surface. The surface properties of poly(4-vinyl pyridine) (P4VP)-grafted PTFE films were investigated in terms of grafting degree, wettability, chemical structure, and morphology. The results revealed that the surface of PTFE films was successfully functionalized by ion beam-induced graft polymerization of 4VP.

• Journal of Adhesion and Interface
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• v.20 no.2
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• pp.53-60
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• 2019

Stable graphene dispersions in various organic solvents and in water were achieved via noncovalent functionalization of graphene surfaces using different types of commercially available surfactants. Stable dispersions were obtained in short time sonication, 3 h. In NMP, graphene with Tween and Span series, and with Pluronic surfactants showed stable dispersions. In ethanol, nitrogen based surfactants showed stable dispersions. In water and dichloromethane partially stable graphene dispersions were obtained using poly(4-vinyl pyridine) and sodium dodecyl sulfonate surfactants. Large scale productions of stable dispersions were successful using poly(4-vinyl pyridine), poly(vinyl pyrrolidone), and poly(2-(dimethylamino)ethyl methacrylate). Thus, this work will serve as a library to select the surfactants for different solvent systems.

• Polymer(Korea)
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• v.29 no.4
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• pp.392-398
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• 2005

Self-assembled multilayer thin films of poly(ethylene-alt-maleic anhydride) (PEMAh) and poly(4-vinyl pyridine) (P4VP) were fabricated by layer-by-layer (LbL) sequential adsorption. Fourier transform infrared (FT-IR) spectroscopic analysis of the self-assembled PEMAh/P4VP multilayer films confirms that the driving forces for the multilayer buildup are the intermolecular hydrogen bonding and electrostatic interactions. The linear increase of absorption peak of P4VP at 256 nm with increasing number of PEMAh/P4VP bilayers indicates that the multilayer buildup is an uniform assembling process. We also investigate the effects of polyelectrolyte concenhation variation of the dipping solution and pH variation of the PEMAh solution on the multilayer film formation. Thickness. adsorbed polyelectrolyte mass and surface roughness of the multilayer films were measured by UV-visible spectroscopy, quartz crystal microbalance (QCM), and atomic force microscopy (AFM), respectively.

• Polymer(Korea)
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• v.29 no.6
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• pp.593-598
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• 2005

This work studied the loading capabilities and release behaviors of poly(ethylene-alt-maleic anhydride) (PEMAh)/poly(4-vinyl pyridine) (P4VP) multilayer films formed by the layer-by-layer(LbL) sequential self-assembly method, using Rodamine 6G(R6G) as an indicator. Thickness of the multilayer, and loading and subsequent release behavior of R6G from the multilayer were studied using UV-visible spectroscopy. The amount of R6G loaded in multilayer film increased linearly with increasing film thickness. pH-Sensitive permeability was observed, where lower pH environments increased both release rate and release amount. By additional assembling of PEMAh/poly(ethyleneimine) (PEI) capping layers on top of (PEMAh/P4VP)n multilayers, the release of R6G was better controlled.

• Polymer(Korea)
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• v.30 no.6
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• pp.519-524
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• 2006

Poly(4-vinyl pyridine) (PVP) and its copolymers, poly(4-vinyl pvridine- co-acrylamide) and poly(4-vinyl pyridine-co-allylamine), were synthesized and evaluated for application to organic solder-ability preservatives (OSP). The copolymers were synthesized by radical polymerization of vinyl pyridine in the presence of acrylamide or allylamine as a comonomer. Various kinds of polymers with different chemical composition were synthesized by varying the feed ratio of monomers and their low $M_w$ polymers can be obtained by adding 2-mercaptoethanol as a chain transfer agent during poly-merization. All the polymers showed good adhesion properties on Cu pad when they were spin-coated. Especially, allylamine -containing copolymers showed both good adhesion and solubility properties. Also, they exhibited better thermal stability than PVP homopolymer and such thermal properties were changed depending on the chemical composition and their $M_w$, which were evidenced by the measurement of oxygen induced temperature (OIT). From the OIT measurement, poly(4-vinyl pyridine- co-allylamine) was thermally stable up to $230^{\circ}C$ for 70 min in the 100% oxygen environment. As a result, allylamine-containing copolymers can be considered as a promising OSP coating material that has excellent thermal and adhesive properties applicable to the present microelectronic package processes.

• Polymer(Korea)
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• v.30 no.6
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• pp.556-562
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• 2006

Quarternized poly(4-vinyl pyridine)s have been prepared by the reaction of poly (4-vinyl pyridine)s (Mw=50 kg/mol and 200 kg/mol) and alkylating agents varying the carbon numbers of the alkyl groups (m):dimethyl sulfate (m=1) as well as bromoalkane (m= 5, 8, 12, 16, and 22) was used as an alkylating agent. The degree of alkylation was determined by using an elemental analysis and NMR spectroscopy. As a result, polyelectrolytes were obtained by the almost full alkylation of poly (4-vinyl pyridine)s. The critical aggregation concentration (CAC) was determined by measuring the change of turbidity occurred by addition of sodium dodecyl sulfate (SDS) into aqueous solution of quarternized poly-(4-vinyl pyridine)s, and the dependence of molecular weight of polymer, the length of N-alkyl group and concentration of NaCl upon CAC was investigated. As a result, as the molecular weight or the length of alkyl group was increased, less amount of SDS Gould induce the aggregation.

• Textile Coloration and Finishing
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• v.3 no.2
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• pp.43-48
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• 1991

Cellulose acetate (CA) and poly-4-vinyl pyridine (PVP) in various weight proportions were mixed in a mixed solvent of trifluoroacetic acid: methylene chloride/6:4 (v:v). CA was miscible with PVP in that solvent system. CA/PVP/solvent show liquid crystal in a certain range of concentration and the nature of that liquid crystal was cholesteric. Films of the liquid crystal composite cast from the liquid crystal solutions of CA/PVP were tested in a viewpoint of biomembrane. Results show that considering permselectivity CA/PVP membrane is better than that of CA and CA/PVP membrane is closer to cell membrane.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.1405-1407
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• 2009

We prepared polystyrene-b-poly(2-vinyl pyridine) (PSb-P2VP) lamellar films which is hydrophobic block-hydrophilic polyelectrolyte block polymer have 57 kg/mol-b-57 kg/mol. The result of UV-visible absorption spectra supported that effect of poly(ethylene oxide) on the band gap tuning of PS-P2VP photonic gel like salt effect.