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Fabrication of an Alternating Multilayer Film of Poly(ethylene-alt-maleic anhydride) and Poly(4-vinyl pyridine) by Layer-by-Layer Self-Assembly Method  

Lee Joon Youl (Department of Advanced Polymer and Fiber Materials, College of Environment and Applied Chemistry, Kyung Hee University)
Hong Sook-Young (Department of Advanced Polymer and Fiber Materials, College of Environment and Applied Chemistry, Kyung Hee University)
Publication Information
Polymer(Korea) / v.29, no.4, 2005 , pp. 392-398 More about this Journal
Abstract
Self-assembled multilayer thin films of poly(ethylene-alt-maleic anhydride) (PEMAh) and poly(4-vinyl pyridine) (P4VP) were fabricated by layer-by-layer (LbL) sequential adsorption. Fourier transform infrared (FT-IR) spectroscopic analysis of the self-assembled PEMAh/P4VP multilayer films confirms that the driving forces for the multilayer buildup are the intermolecular hydrogen bonding and electrostatic interactions. The linear increase of absorption peak of P4VP at 256 nm with increasing number of PEMAh/P4VP bilayers indicates that the multilayer buildup is an uniform assembling process. We also investigate the effects of polyelectrolyte concenhation variation of the dipping solution and pH variation of the PEMAh solution on the multilayer film formation. Thickness. adsorbed polyelectrolyte mass and surface roughness of the multilayer films were measured by UV-visible spectroscopy, quartz crystal microbalance (QCM), and atomic force microscopy (AFM), respectively.
Keywords
self-assembled multilayer films; poly(ethylene-alt-maleic anhydride); poly (4-vinyl pyridine); polyelectrolytes; layer-by-layer sequential adsorption; pH variation;
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