• Title/Summary/Keyword: polarization model

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THE ELECTROCHEMICAL STUDY ON CORROSION RESISTANCE OF VARIOUS DENIAL MAGNETIC ATTACHMENTS (수종 치과용 자석유지장치의 부식저항성에 대한 전기화학적 연구)

  • Sohn Byoung-Sup;Chang Ik-Tae;Heo Seong-Joo;Keak Jai-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.4
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    • pp.336-350
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    • 2001
  • The purpose of this study was to investigate corrosion tendency and to compare corrosion resistance of three dental magnetic attachments and its keeper alloy by coercive, electrochemical method. By using petentiodynamic polarization technique, magnetic elements and its keeper alloy of Magfit EX600 system(MF, MFK), Dyna ES regular system(DN, DNK) and Shiner SR magnet system(SR, SRK) were corroded electrochemically in 0.9% NaCl electrolytic solution. Open-circuit potential and anodic polarization curve was measured with Potentiostat(model 273 EG&E) and polarization curve was created by current density per square area following scanning of increased series of voltage in the rate of 1.0mV per second. Before and after electrochemical corrosion, the surface roughness test was done. Thereafter the change of mean surface roughness value(Ra) and mean peak value(Rt) of surface roughness was compared one another. In order to observe the corroded surface of each specimen, metallurgical light microscopic(${\times}37.5$) and scanning electron microscopic view(SEM ${\times}100$) was taken and compared one another. Conclusion is followings. 1. All of six covering metal of dental magnetic attachments and its keeper alloy were corroded in various degree after electrochemical corrosion. 2. The corrosion resistance of which used in this experiment is the following in high order; DNK, MFK, DN, MF, SRK and SR. 3. Especially Shiner magnet system and its keeper alloy were more severely corroded after electrochemical corrosion and the change of Ra Rt value were more increased than others. 4 Metallurgical and scanning electron microscopic view showed the pitting corrosion tendency of all experimental alloy but DNK and SR. 5. Covering metal of magnet was more corroded than its keeper alloy.

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A Study on Polarization of the Molten Carvonate Fuel Cell (용융탄산염 연료전지의 분극현상 연구)

  • Nam, S.W.;Suh, S.H.;Lim, T.H.;Oh, LH.;Hong, S.A.;Lim, H.C.
    • Transactions of the Korean hydrogen and new energy society
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    • v.3 no.2
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    • pp.55-62
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    • 1992
  • To improve the MCFC performance it is important to distingush between polarization losses occuring in the individual electrodes and other components. In this study a current interruption technique has been applied to a MCFC unit cell having a reference electrode to separately study the contributions of IR loss and other polarization losses. At a current density of $150mA/cm^2$ the IR-free polarization of a Ni anode was about 60mV while that of a NiO cathode was 130mV and the Ohmic loss of the cell was as large as 170mV suggesting that both the cathode and the cell structure need further improvement. The thin-film electrode model was used to simulate the performance of the electrodes. Both andoe data and cathode data were successfully fitted.

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Performance Analysis of PCM Cell Search Algorithm for Fast Cell Search in WCDMA Systems (WCDMA. 시스템에서 빠른 셀 탐색을 위한 극성 변조 셀 탐색 알고리즘의 성능 분석)

  • 배성오;임재성
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.8A
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    • pp.598-606
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    • 2003
  • In this paper, we analyze the performance of the PCM cell search algorithm proposed for fast cell search of WCDMA systems. In order to improve both performance and complexity of the cell search algorithm standardized for WCDMA systems the PCM scheme uses a group of the polarization codes produced by a Gold code generator. The PCM scheme only uses one synchronization channel since the polarization codes modulated on P-SCH can replace the RS codes of S-SCH. Thus, the PCM reduces the BS's transmission power since only one synchronization channel can be used, and it can also reduce the complexity of receiver as compared with the conventional one. In this paper, by defining a numerical model, we analyze the performance of the PCM cell search algorithm in terms of detection probability and mean acquisition time. Consequently, we could demonstrate that the PCM cell search algorithm is superior to the standard WCDMA cell search algorithm.

Effect of Concentration Polarization on The Pervaporation of Aqueous Chlorinated-Organic Solution (유기염화물 수용액의 투과증발에 미치는 농도분극의 영향)

  • Cho, Min-Suk;Kim, Seung-Jai;Kim, Jin-Hwan
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.698-703
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    • 1998
  • The pervaporation experiments of aqueous solutions of trichloroethylene (TCE) and chlorobenzene (CB) through the silicone rubber (polydimethylsiloxane, PDMS) membrane were carried out and the effect of concentration polarization on the separation characteristics was investigated. The resistance-in-series model was used to explain the boundary layer resistance. It was clear that the concentration polarization phenomenon had a significant effect on the permeation behavior in the pervaporation separation of the trace organic chlorides from aqueous solutions. With the same membrane thickness, the permeation of TCE, which has a stronger affinity for the PDMS, appeared to be more influenced by the boundary layer resistance than that of CB. The effect of boundary layer resistance was reduced and the membrane resistance became dominant with increasing membrane thickness at a given hydrodynamic condition. The separation factor was increased to approach the intrinsic separation factor of the membrane with its thickness.

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역삼투막의 제조 및 최근 동향

  • 구자영
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.09a
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    • pp.1-30
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    • 1998
  • 1. RO History 2. Asymmetric Membranes by Phase Inversion 3. Thin Film Composite (TFC) Membrane 4. Structure and Property Relationship of TFC Membrane 5. Membrane Materials 6. Tranport Mechanism(Model) 7. Membrane Characters in Separation Process 8. Concentration Polarization and Fouling Phenomenon 9. RO Membrane Module Configuration and System Design 10. Futrue Trend in RO Industry

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A Study on Design of Broadband Electromagnetic Wave Absorber for Single Polarization (단일편파용 광대역 전파흡수체의 설계에 관한 연구)

  • 김동일;이수영;정세모
    • Journal of the Korean Institute of Navigation
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    • v.19 no.4
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    • pp.93-102
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    • 1995
  • A design method of an electromagnetic wave absorber with ferrite fins in the second layer, which has very wide band frequency characteristics, is proposed and discussed. A theoretical model using the equivalent material constants method is adopted, assessed for its accuracy by comparision with the Hashin-Shtrikman formulas and compared with the conventional absorbers. Based on the model, a wide band electromagnetic wave absorber with excellent reflectivity frequency characteristics in frequency range of 30MHZ to 3530MHZ has been designed.

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A Study on the Optical Characteristics of Biaxial Film by using Dual Rotating Retarder Polarimeter and a Novel Simulation Model

  • Yun, C.H.;Jeon, B.K.;Park, M.S.;Yu, J.S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.809-813
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    • 2006
  • We have studied the optical properties of the biaxial film such as fast axis, retardance and the change of polarization state between crossed polarizer using dual rotating retarder polarimeter. We have developed a novel simulation model, which could explain well the experimental results, and found that it could be used to optimize the compensation film in LCD for improving wide-viewing property.

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Relative Comparison of Cathode Polarizations in Solid Oxide Fuel Cells Using the Spreading Concept in AC 2 Point Impedance Spectroscopy

  • Lee, Byung-Kook;Kim, Eui-Hyun;Hwang, Jin-Ha
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.163-167
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    • 2013
  • A modified two-point impedance spectroscopy technique exploits the geometric constriction between an electrolyte and a cathode with an emphasis on semispherical-shaped electrolytes. The spatial limitation in the electrolyte/electrode interface leads to local amplification of the electrochemical reaction occurring in the corresponding electrolyte/electrode region. The modified impedance spectroscopy was applied to electrical monitoring of a YSZ ($Y_2O_3$-stabilized $ZrO_2$)/SSC ($Sm_{0.5}Sr_{0.5}CoO_3$) system. The resolved bulk and interfacial component was numerically analyzed in combination with an equivalent circuit model. The effectiveness of the "spreading resistance" concept is validated by analysis of the electrode polarization in the cathode materials of solid oxide fuel cells.

Equivalence Between Two Orthogonal Oriented Circular Loops and Planar Inveryed-F Antenna Array (직교형 원형 루프 안테나와 역 에프형 배열구조의 등가성 분석)

  • Kim, Jong-Sung;Park, Seung-Mo;Choi, Won-Kyu;Seong, Nak-Seon
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2005.11a
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    • pp.289-292
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    • 2005
  • Two planar inverted-F antenna (PIFA) arrays are proposed as an alternative model to generate input and radiation characteristics of two orthogonal oriented circular loops, which has polarization diversity, but inherent mechanical instability of two orthogonal loops, in particular, in installation and operation conditions. Two $1\times2$ PIFA sub-arrays are orthogonally placed on a ground plane and two different feeding networks are applied to control horizontal and vertical radiation current flows for each sub-array, respectively. Equivalence of scattering parameters and radiation patterns between two antennas are validated by the available commercial simulator.

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Corrosion Analysis of Cracked Concrete based on Mass Transfer (물질이동에 기초한 균열콘크리트의 철근부식 해석)

  • Kim Tae-Hwan;Song Ha-Won;Kim Ho-Jin;Byun Keun-Joo;Lee Seung-Hoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.806-809
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    • 2004
  • The early-age cracks have bad effects on the diffusion movement of chloride ions and oxygen. In this study, a corrosion analysis algorithm for cracked concrete is proposed to examine the influence of early-age cracks on corrosion of RC structures. For different environmental exposure conditions of RC structures, a corrosion model is combined with models for activation polarization and concentration polarization. From the finite element corrosion analysis using the proposed algorithm and the models, the effects of early-age cracks to the corrosion is simulated.

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