• Title/Summary/Keyword: polar effect(e)

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Effect of Several Solvents on Low Temperature Wool Dyeing (몇 가지 용매가 양모의 저온염색에 미치는 영향)

  • Dho, Seong-Kook
    • Fashion & Textile Research Journal
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    • v.11 no.4
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    • pp.672-677
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    • 2009
  • To reduce the dependence of wool dyeing on the temperature several solvents with different properties and structures were added to the dye bath of C. I. Acid Yellow 42. Nearly the same total solubility parameters(${\delta}_t$) of solvents as those of wool fiber and hydrophobic part of the dyestuff were needed to increase disaggregation of dye molecules, loosening the wool fiber and wickabilty of dyeing solution; besides, the large surface tension(${\gamma}$) value of the solvents and the well balanced values of the three-component Hansen solubility parameters such as dispersion(${\delta}_d$), polar(${\delta}_p$), and hydrogen(${\delta}_h$) bonding parameters were required. Among the added solvents dimethyl phthalate(DMP) and acetophenone(AP) were satisfied with these conditions and worked the most successfully in the low temperature wool dyeing. Their effectiveness proven by the dyeing rate and the activation energy ($E_a$) of the dyeing was in the order of DMP > AP > DBE > CH > M >NONE. In conclusion the total solubility parameters(${\delta}_t$), the three-component Hansen parameters and the surface tension(${\gamma}$) of DMP and AP could be the guidelines to select suitable solvents for low temperature wool dyeing.

Regulation of SoxR, the superoxide-sensory regulator in Escherichia coli.

  • Lee Joon-Hee;Koo Mi-Sun;Yeo Won-Sik;Roe Jung-Hye
    • Proceedings of the Microbiological Society of Korea Conference
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    • 2000.10a
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    • pp.24-31
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    • 2000
  • In order to find out SoxR-reducing system in E. coli, we generated Tn10-insertion mutants and screened for constitutive expression of SoxS in a soxS-lacZ fusion strain. One mutation was mapped in rseB, a gene in rseABC (Regulation of SigmaE) operon. The constitutive soxS-expressing phenotype was due to the polar effect on the downstream gene, rseC. RseC is likely to function as a component of SoxR reduction system because SoxR was kept in oxidized form to activate soxS expression in rseC mutant. RseC is an integral membrane protein with an N-terminal cysteine-rich domain in the cytoplasm. The functionally critical cysteines were determined by substitution mutagenesis. The truncated N-terminal domain of RseC reduced the soxS transcription by $50\%$ as judged by in vitro transcription assay. Currently RseC is believed to be a reducing factor for SoxR. However, the mechanism for the reduction needs further investigation.

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Response of the Poleward Boundary of the Nightside Auroral Oval to Impacts of Solar Wind Dynamic Pressure Enhancement

  • Cho, Joon-Sik;Lee, Dae-Young;Kim, Kyung-Chan;Lee, Ji-Hee
    • Journal of Astronomy and Space Sciences
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    • v.27 no.3
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    • pp.189-194
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    • 2010
  • In this paper we have investigated latitudinal variations of the poleward boundary of the nightside auroral oval when the magnetosphere is hit by an enhanced solar wind dynamic pressure front. We used precipitating particle data obtained from Defense Meteorological Satellite Program satellites to identify the locations of the boundary before and after enhanced pressure impacts. The boundary locations are represented by a parameter called "b5e". After performing the analysis for a number of events, we found that the basic effect of the solar wind pressure increase impact is often (but not always) to move the poleward boundary of the nightside auroral oval poleward. However, this effect can be often modified by other factors, such as simultaneous variations of the interplanetary magnetic field with a pressure increase, and thus the boundary response is not necessarily a poleward shift in many cases. We demonstrate this with specific examples, and discuss other possible complicating factors.

Rotordynamic Analysis of Automotive Turbochargers Supported on Ball Bearings and Squeeze Film Dampers in Series: Effect of Squeeze Film Damper Design Parameters and Rotor Imbalances (볼 베어링과 스퀴즈 필름 댐퍼로 지지되는 차량용 터보차저의 회전체동역학 해석: 스퀴즈 필름 댐퍼 설계 인자와 회전체 불균형 질량의 영향)

  • Kim, Kyuman;Ryu, Keun
    • Tribology and Lubricants
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    • v.34 no.1
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    • pp.9-15
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    • 2018
  • Modern high-performance automotive turbochargers (TCs) implement ceramic hybrid angular contact ball bearings in series with squeeze film dampers (SFDs) to enhance transient responses, thereby reducing the overall emission levels. The current study predicts the rotordynamic responses of the commercial automotive TCs (compressor wheel diameter = ~53 mm, turbine wheel diameter = ~43 mm, and shaft diameter at the bearing locations = ~7 mm) supported on ball bearings and SFDs for various design parameters of SFDs, including radial clearance, axial length, lubricant viscosity, and rotor imbalance conditions (i.e., amplitudes and phase angles) while increasing rotor speed up to 150 krpm. This study validates the predictive rotor finite element model against measurements of mass, polar and transverse moments of inertia, and free-free mode natural frequencies and mode shapes. A nonlinear rotordynamic model integrates nonlinear force coefficients of SFDs to calculate the transient responses of the TC rotor-bearing system. The predicted results show that SFD radial clearances, as well as phase angles of rotor imbalances, have the paramount effect on the dynamic responses of TC shaft motions.

Cell Edge SINR of Multi-cell MIMO Downlink Channel (다중 셀 MIMO 하향채널의 셀 에지 SINR)

  • Park, Ju-Yong;Kim, Ki-Jung;Kim, Jeong-Su;Lee, Moon-Ho
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.15 no.4
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    • pp.105-117
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    • 2015
  • In this paper, we consider 19 cells with the two tiers for polar-rectangular coordinates (PRCs) and provide the cell edge performance of cellular networks based on distance from cell center i.e., BS (base station). When FFR is applied(or adopted) to cell edge, it is expected that BS cooperation, or a coordinated multipoint (CoMP) multiple access strategy will further improve the system performance. We proposed a new method to evaluate the sum rate capacity of the MIMO DC of multicell system. We improve the performance of cell edge users for intercell interference cancelation in cooperative downlink multicell systems. Simulation results show that the proposed scheme outperforms the reference schemes, in terms of cell edge SINR (signal-to-interference-noise ratio) with a minimal impact on the network path loss exponent. We show 13 dB improvements in cell-edge SINR by using reuse of three relative to reuse of one. BS cooperation has been proposed to mitigate the cell edge effect.

Effect of Proline on First Polar Body Formation in Porcine Primary Oocyte

  • Oh, H. J.;Lee, E. J.;B. C. Yang;W. K. Chang;Kim, J. S.;J. K. Lim;Y. K. Yeo;M. A. Della-Fera;Park, Y. S.
    • Korean Journal of Animal Reproduction
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    • v.26 no.2
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    • pp.165-171
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    • 2002
  • Follicular fluid (FF) contains an oocyte maturation inhibitor with unknown chemical properties. This study was carried out to chemically define the factor(s) inhibiting cumulus cell denudation (CD) and first polar body formation (PBF). Porcine FF (PFF) was extracted with methanol and the extract was serially separated using gel filtration on Superose 12 and Superdex columns. A Superdex fraction was derived with PITC and analyzed with an amino acid analysis column. The results obtained are as follows; PFF had an activity inhibiting both CD and PBF of porcine primary oocytes. Superdex fractions RV2.11 prepared from PFF exhibited an activity inhibiting CD and PBF. By amino acid analysis, the fraction RV2.11 appeared to be proline having the same activity inhibiting CD and PBF. In conclusion, PFF had oocyte maturation inhibitors, of which proline should inhibit CD and PBF.

A Study of Arctic Microbial Community Structure Response to Increased Temperature and Precipitation by Phospholipid Fatty Acid Analysis

  • Sungjin Nam;Ji Young Jung
    • Proceedings of the National Institute of Ecology of the Republic of Korea
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    • v.4 no.2
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    • pp.86-94
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    • 2023
  • Climate change is more rapid in the Arctic than elsewhere in the world, and increased precipitation and warming are expected cause changes in biogeochemical processes due to altered microbial communities and activities. It is crucial to investigate microbial responses to climate change to understand changes in carbon and nitrogen dynamics. We investigated the effects of increased temperature and precipitation on microbial biomass and community structure in dry tundra using two depths of soil samples (organic and mineral layers) under four treatments (control, warming, increased precipitation, and warming with increased precipitation) during the growing season (June-September) in Cambridge Bay, Canada (69°N, 105°W). A phospholipid fatty acid (PLFA) analysis method was applied to detect active microorganisms and distinguish major functional groups (e.g., fungi and bacteria) with different roles in organic matter decomposition. The soil layers featured different biomass and community structure; ratios of fungal/bacterial and gram-positive/-negative bacteria were higher in the mineral layer, possibly connected to low substrate quality. Increased temperature and precipitation had no effect in either layer, possibly due to the relatively short treatment period (seven years) or the ecosystem type. Mostly, sampling times did not affect PLFAs in the organic layer, but June mineral soil samples showed higher contents of total PLFAs and PLFA biomarkers for bacteria and fungi than those in other months. Despite the lack of response found in this investigation, long-term monitoring of these communities should be maintained because of the slow response times of vegetation and other parameters in high-Arctic ecosystems.

Effect of NH3 plasma on thin-film composite membrane: Relationship of membrane and plasma properties

  • Kim, Eun-Sik;Deng, Baolin
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.109-126
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    • 2013
  • Surface modification by low-pressure ammonia ($NH_3$) plasma on commercial thin-film composite (TFC) membranes was investigated in this study. Surface hydrophilicity, total surface free energy, ion exchange capacity (IEC) and zeta (${\zeta}$)-potentials were determined for the TFC membranes. Qualitative and quantitative analyses of the membrane surface chemistry were conducted by attenuated total reflectance Fourier transform infrared (ATR FT-IR) spectroscopy. Results showed that the $NH_3$ plasma treatment increased the surface hydrophilicity, in particular at a plasma treatment time longer than 5 min at 50 W of plasma power. Total surface free energy was influenced by the basic polar components introduced by the $NH_3$ plasma, and isoelectric point (IEP) was shifted to higher pH region after the modification. A ten (10) min $NH_3$ plasma treatment at 90 W was found to be adequate for the TFC membrane modification, resulting in a membrane with better characteristics than the TFC membranes without the modification for water treatment. The thin-film chemistry (i.e., fully-aromatic and semi-aromatic nature in the interfacial polymerization) influenced the initial stage of plasma modification.

Growth and Photocurrent Properties of $CuGaSe_2$ Single Crystal ($CuGaSe_2$ 단결정 박막 성장과 광전류 특성)

  • K.J. Hong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.81-81
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    • 2003
  • The stochiometric mixture of evaporating materials for the CuGaSe$_2$ single crystal thin films were prepared from horizontal furnace. Using extrapolation method of X-ray diffraction patterns for the polycrystal CuGaSe$_2$, it was found tetragonal structure whose lattice constant no and co were 5.615$\AA$ and 11.025$\AA$, respectively. To obtains the single crystal thin films, CuGaSe$_2$ mixed crystal was deposited on throughly etched GaAs(100) by the Hot Wall Epitaxy(HWE) system. The source and substrate temperature were 61$0^{\circ}C$ and 45$0^{\circ}C$ respectively, and the growth rate of the single crystal thin films was about 0.5${\mu}{\textrm}{m}$/h. The crystalline structure of single crystal thin films was investigated by the double crystal X-ray diffraction(DCXD). Hall effect on this sample was measured by the method of van der pauw and studied on carrier density and mobility depending on temperature. From Hall data, the mobility was likely to be decreased by pizoelectric scattering in the temperature range 30K to 150K and by polar optical scattering in the temperature range 150K to 293K. The optical energy gaps were found to be 1.68eV for CuGaSe$_2$ single crystal thin films at room temperature. The temperature dependence of the photocurrent peak energy is well explained by the Varshni equation then the constants in the Varshni equation are given by a=9.615$\times$ 10$^{-4}$ eV/K, and $\beta$=335K. From the photocurrent spectra by illumination of polarized light of the CuGaSe$_2$ single crystal thin films. We have found that values of spin orbit coupling ΔSo and crystal field splitting ΔCr was 0.0900eV and 0.2498eV, respectively. From the PL spectra at 20K, the peaks corresponding to free bound excitons and D-A pair and a broad emission band due to SA is identified. The binding energy of the free excitons are determined to be 0.0626eV and the dissipation energy of the acceptor-bound exciton and donor-bound exciton to be 0.0352eV, 0.0932eV, respectively.

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Seasonal Characteristics of the Longitudinal Wavenumber-4 Structure in the Equatorial Ionospheric Anomaly

  • Kim, E.;Jee, G.;Kim, Y.H.
    • Journal of Astronomy and Space Sciences
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    • v.25 no.4
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    • pp.335-346
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    • 2008
  • Using the global total electron contents (TEC) measured by the TOPEX satellite from Aug. 1992 to Oct. 2005, we investigate the variations of the longitudinal wavenumber-4 (LW-4) structure in the equatorial anomaly (EA) crests with season, local time, and solar activity. Our study shows that the LW-4 structure in the EA crests ($5{\sim}20^{\circ}$ MLAT in both hemispheres) has clear four peaks at fixed longitude sectors during the daytime for both equinoxes and June solstice. In spite of being called a wavelike structure, however, the magnitudes and spatial intervals of the four peaks are far from being the same or regular. After sunset, the four-peak structure begins to move eastward with gradual weakening in its amplitude during equinoxes and this weakening proceeds much faster during June solstice. Interestingly, the longitudinal variations during December solstice do not show clear four-peak structure. All these features of the LW-4 structure are almost the same for both low and high solar activity conditions although the ion densities are greatly enhanced from low to high solar activities. With the irrelevancy of the magnetic activity in the LW-4, this implies that the large changes of the upper atmospheric ion densities, one of the important factors for ion-neutral interactions, have little effect on the formation of the LW-4 structure. On the other hand, we found that the monthly variation of the LW-4 is remarkably similar to that of the zonal component of wavenumber-3 diurnal tides at low latitudes, which implies that the lower atmospheric tidal forcing, transferred to the upper atmosphere, seems to have a dominant role in producing the LW-4 structure in the EA crests via the E-region dynamo.