• 제목/요약/키워드: polar effect(e)

검색결과 63건 처리시간 0.024초

몇 가지 용매가 양모의 저온염색에 미치는 영향 (Effect of Several Solvents on Low Temperature Wool Dyeing)

  • 도성국
    • 한국의류산업학회지
    • /
    • 제11권4호
    • /
    • pp.672-677
    • /
    • 2009
  • To reduce the dependence of wool dyeing on the temperature several solvents with different properties and structures were added to the dye bath of C. I. Acid Yellow 42. Nearly the same total solubility parameters(${\delta}_t$) of solvents as those of wool fiber and hydrophobic part of the dyestuff were needed to increase disaggregation of dye molecules, loosening the wool fiber and wickabilty of dyeing solution; besides, the large surface tension(${\gamma}$) value of the solvents and the well balanced values of the three-component Hansen solubility parameters such as dispersion(${\delta}_d$), polar(${\delta}_p$), and hydrogen(${\delta}_h$) bonding parameters were required. Among the added solvents dimethyl phthalate(DMP) and acetophenone(AP) were satisfied with these conditions and worked the most successfully in the low temperature wool dyeing. Their effectiveness proven by the dyeing rate and the activation energy ($E_a$) of the dyeing was in the order of DMP > AP > DBE > CH > M >NONE. In conclusion the total solubility parameters(${\delta}_t$), the three-component Hansen parameters and the surface tension(${\gamma}$) of DMP and AP could be the guidelines to select suitable solvents for low temperature wool dyeing.

Regulation of SoxR, the superoxide-sensory regulator in Escherichia coli.

  • Lee Joon-Hee;Koo Mi-Sun;Yeo Won-Sik;Roe Jung-Hye
    • 한국미생물학회:학술대회논문집
    • /
    • 한국미생물학회 2000년도 추계학술발표대회
    • /
    • pp.24-31
    • /
    • 2000
  • In order to find out SoxR-reducing system in E. coli, we generated Tn10-insertion mutants and screened for constitutive expression of SoxS in a soxS-lacZ fusion strain. One mutation was mapped in rseB, a gene in rseABC (Regulation of SigmaE) operon. The constitutive soxS-expressing phenotype was due to the polar effect on the downstream gene, rseC. RseC is likely to function as a component of SoxR reduction system because SoxR was kept in oxidized form to activate soxS expression in rseC mutant. RseC is an integral membrane protein with an N-terminal cysteine-rich domain in the cytoplasm. The functionally critical cysteines were determined by substitution mutagenesis. The truncated N-terminal domain of RseC reduced the soxS transcription by $50\%$ as judged by in vitro transcription assay. Currently RseC is believed to be a reducing factor for SoxR. However, the mechanism for the reduction needs further investigation.

  • PDF

Response of the Poleward Boundary of the Nightside Auroral Oval to Impacts of Solar Wind Dynamic Pressure Enhancement

  • Cho, Joon-Sik;Lee, Dae-Young;Kim, Kyung-Chan;Lee, Ji-Hee
    • Journal of Astronomy and Space Sciences
    • /
    • 제27권3호
    • /
    • pp.189-194
    • /
    • 2010
  • In this paper we have investigated latitudinal variations of the poleward boundary of the nightside auroral oval when the magnetosphere is hit by an enhanced solar wind dynamic pressure front. We used precipitating particle data obtained from Defense Meteorological Satellite Program satellites to identify the locations of the boundary before and after enhanced pressure impacts. The boundary locations are represented by a parameter called "b5e". After performing the analysis for a number of events, we found that the basic effect of the solar wind pressure increase impact is often (but not always) to move the poleward boundary of the nightside auroral oval poleward. However, this effect can be often modified by other factors, such as simultaneous variations of the interplanetary magnetic field with a pressure increase, and thus the boundary response is not necessarily a poleward shift in many cases. We demonstrate this with specific examples, and discuss other possible complicating factors.

볼 베어링과 스퀴즈 필름 댐퍼로 지지되는 차량용 터보차저의 회전체동역학 해석: 스퀴즈 필름 댐퍼 설계 인자와 회전체 불균형 질량의 영향 (Rotordynamic Analysis of Automotive Turbochargers Supported on Ball Bearings and Squeeze Film Dampers in Series: Effect of Squeeze Film Damper Design Parameters and Rotor Imbalances)

  • 김규만;류근
    • Tribology and Lubricants
    • /
    • 제34권1호
    • /
    • pp.9-15
    • /
    • 2018
  • Modern high-performance automotive turbochargers (TCs) implement ceramic hybrid angular contact ball bearings in series with squeeze film dampers (SFDs) to enhance transient responses, thereby reducing the overall emission levels. The current study predicts the rotordynamic responses of the commercial automotive TCs (compressor wheel diameter = ~53 mm, turbine wheel diameter = ~43 mm, and shaft diameter at the bearing locations = ~7 mm) supported on ball bearings and SFDs for various design parameters of SFDs, including radial clearance, axial length, lubricant viscosity, and rotor imbalance conditions (i.e., amplitudes and phase angles) while increasing rotor speed up to 150 krpm. This study validates the predictive rotor finite element model against measurements of mass, polar and transverse moments of inertia, and free-free mode natural frequencies and mode shapes. A nonlinear rotordynamic model integrates nonlinear force coefficients of SFDs to calculate the transient responses of the TC rotor-bearing system. The predicted results show that SFD radial clearances, as well as phase angles of rotor imbalances, have the paramount effect on the dynamic responses of TC shaft motions.

다중 셀 MIMO 하향채널의 셀 에지 SINR (Cell Edge SINR of Multi-cell MIMO Downlink Channel)

  • 박주용;김기중;김정수;이문호
    • 한국인터넷방송통신학회논문지
    • /
    • 제15권4호
    • /
    • pp.105-117
    • /
    • 2015
  • 본 논문에서는 PRC (polar-rectangular coordinate) 에 대한 2 tier 19 셀에 대해 고려해보고, BS 와 같은 셀 중앙으로 부터의 거리에 기반해 셀룰러 망의 셀 에지(edge) 성능을 제시한다. BS 들은 하향링크 다중 셀 시스템에서 ICI (intercell interference) 제거를 위한 자신들의 SINR (signal-to-interference-noise ratio) 을 개선하기 위해 셀 에지 user 와 협력하여 송신한다. 제안한 새로운 모델은 다중 셀 시스템의 MIMO DC sum rate 용량을 계산한다. 이 모델은 협력 하향 링크 다중 셀 시스템에서 셀 간 간섭을 제거해 셀 에지 user의 성능을 개선시킨다. 모의실험 결과 제안한 방법이 망 경로 지수에 최소 영향을 주어 셀 에지 SINR 관점에서 기존 방법들보다 좋은 성능을 보였다. 경로손실 지수가 3.6인 경우에는 reuse-1에 비해 reuse-3을 사용한 결과 셀 에지 SINR에서 대략 13 dB가 개선되었다.

Effect of Proline on First Polar Body Formation in Porcine Primary Oocyte

  • Oh, H. J.;Lee, E. J.;B. C. Yang;W. K. Chang;Kim, J. S.;J. K. Lim;Y. K. Yeo;M. A. Della-Fera;Park, Y. S.
    • 한국가축번식학회지
    • /
    • 제26권2호
    • /
    • pp.165-171
    • /
    • 2002
  • 난포액에는 난자의 성숙을 억제하는 인자를 함유하고 있으나 화학적 성질이 정확히 알려져 있지않다. 본 연구에서는 1차 난모세포에서 난구세포의 해리와 제1극체의 형성을 억제하는 난포액 성분을 화학적으로 동정하기 위하여 수행되었다 이를 위하여 돼지 난포액을 methanol로 추출한 다음이 추출물을 Superose 12 및 Superdex column을 이용 연속적으로 분리하였으며, Superdex 분절은 PITC로 처리한 다음 아미노산 분석용 column을 이용 분석하였다. 얻어진 결과는 다음과 같다. 난포액은 1차 난모세포에서 난구세포의 해리와 제1극체의 형성을 억제하였다 난포액에서 추출 분리한 Superdex분절 RV2.11 역시 난구세포의 해리와 제1극체의 형성을 억제하였다. 아미노산 분석 결과, 분절 RV2.11은 proline으로 추정되며, proline은 난구세포의 해리와 제1극체의 형성을 억제하였다. 결론적으로 난포액에는 난구세포의 해리와 제1극체의 형성을 억제하는 성분인 proline을 함유하고 있으며, 이는 난자의 성숙을 억제하는 성분일 것으로 추정된다.

A Study of Arctic Microbial Community Structure Response to Increased Temperature and Precipitation by Phospholipid Fatty Acid Analysis

  • Sungjin Nam;Ji Young Jung
    • Proceedings of the National Institute of Ecology of the Republic of Korea
    • /
    • 제4권2호
    • /
    • pp.86-94
    • /
    • 2023
  • Climate change is more rapid in the Arctic than elsewhere in the world, and increased precipitation and warming are expected cause changes in biogeochemical processes due to altered microbial communities and activities. It is crucial to investigate microbial responses to climate change to understand changes in carbon and nitrogen dynamics. We investigated the effects of increased temperature and precipitation on microbial biomass and community structure in dry tundra using two depths of soil samples (organic and mineral layers) under four treatments (control, warming, increased precipitation, and warming with increased precipitation) during the growing season (June-September) in Cambridge Bay, Canada (69°N, 105°W). A phospholipid fatty acid (PLFA) analysis method was applied to detect active microorganisms and distinguish major functional groups (e.g., fungi and bacteria) with different roles in organic matter decomposition. The soil layers featured different biomass and community structure; ratios of fungal/bacterial and gram-positive/-negative bacteria were higher in the mineral layer, possibly connected to low substrate quality. Increased temperature and precipitation had no effect in either layer, possibly due to the relatively short treatment period (seven years) or the ecosystem type. Mostly, sampling times did not affect PLFAs in the organic layer, but June mineral soil samples showed higher contents of total PLFAs and PLFA biomarkers for bacteria and fungi than those in other months. Despite the lack of response found in this investigation, long-term monitoring of these communities should be maintained because of the slow response times of vegetation and other parameters in high-Arctic ecosystems.

Effect of NH3 plasma on thin-film composite membrane: Relationship of membrane and plasma properties

  • Kim, Eun-Sik;Deng, Baolin
    • Membrane and Water Treatment
    • /
    • 제4권2호
    • /
    • pp.109-126
    • /
    • 2013
  • Surface modification by low-pressure ammonia ($NH_3$) plasma on commercial thin-film composite (TFC) membranes was investigated in this study. Surface hydrophilicity, total surface free energy, ion exchange capacity (IEC) and zeta (${\zeta}$)-potentials were determined for the TFC membranes. Qualitative and quantitative analyses of the membrane surface chemistry were conducted by attenuated total reflectance Fourier transform infrared (ATR FT-IR) spectroscopy. Results showed that the $NH_3$ plasma treatment increased the surface hydrophilicity, in particular at a plasma treatment time longer than 5 min at 50 W of plasma power. Total surface free energy was influenced by the basic polar components introduced by the $NH_3$ plasma, and isoelectric point (IEP) was shifted to higher pH region after the modification. A ten (10) min $NH_3$ plasma treatment at 90 W was found to be adequate for the TFC membrane modification, resulting in a membrane with better characteristics than the TFC membranes without the modification for water treatment. The thin-film chemistry (i.e., fully-aromatic and semi-aromatic nature in the interfacial polymerization) influenced the initial stage of plasma modification.

$CuGaSe_2$ 단결정 박막 성장과 광전류 특성 (Growth and Photocurrent Properties of $CuGaSe_2$ Single Crystal)

  • K.J. Hong
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
    • /
    • pp.81-81
    • /
    • 2003
  • The stochiometric mixture of evaporating materials for the CuGaSe$_2$ single crystal thin films were prepared from horizontal furnace. Using extrapolation method of X-ray diffraction patterns for the polycrystal CuGaSe$_2$, it was found tetragonal structure whose lattice constant no and co were 5.615$\AA$ and 11.025$\AA$, respectively. To obtains the single crystal thin films, CuGaSe$_2$ mixed crystal was deposited on throughly etched GaAs(100) by the Hot Wall Epitaxy(HWE) system. The source and substrate temperature were 61$0^{\circ}C$ and 45$0^{\circ}C$ respectively, and the growth rate of the single crystal thin films was about 0.5${\mu}{\textrm}{m}$/h. The crystalline structure of single crystal thin films was investigated by the double crystal X-ray diffraction(DCXD). Hall effect on this sample was measured by the method of van der pauw and studied on carrier density and mobility depending on temperature. From Hall data, the mobility was likely to be decreased by pizoelectric scattering in the temperature range 30K to 150K and by polar optical scattering in the temperature range 150K to 293K. The optical energy gaps were found to be 1.68eV for CuGaSe$_2$ single crystal thin films at room temperature. The temperature dependence of the photocurrent peak energy is well explained by the Varshni equation then the constants in the Varshni equation are given by a=9.615$\times$ 10$^{-4}$ eV/K, and $\beta$=335K. From the photocurrent spectra by illumination of polarized light of the CuGaSe$_2$ single crystal thin films. We have found that values of spin orbit coupling ΔSo and crystal field splitting ΔCr was 0.0900eV and 0.2498eV, respectively. From the PL spectra at 20K, the peaks corresponding to free bound excitons and D-A pair and a broad emission band due to SA is identified. The binding energy of the free excitons are determined to be 0.0626eV and the dissipation energy of the acceptor-bound exciton and donor-bound exciton to be 0.0352eV, 0.0932eV, respectively.

  • PDF

Seasonal Characteristics of the Longitudinal Wavenumber-4 Structure in the Equatorial Ionospheric Anomaly

  • Kim, E.;Jee, G.;Kim, Y.H.
    • Journal of Astronomy and Space Sciences
    • /
    • 제25권4호
    • /
    • pp.335-346
    • /
    • 2008
  • Using the global total electron contents (TEC) measured by the TOPEX satellite from Aug. 1992 to Oct. 2005, we investigate the variations of the longitudinal wavenumber-4 (LW-4) structure in the equatorial anomaly (EA) crests with season, local time, and solar activity. Our study shows that the LW-4 structure in the EA crests ($5{\sim}20^{\circ}$ MLAT in both hemispheres) has clear four peaks at fixed longitude sectors during the daytime for both equinoxes and June solstice. In spite of being called a wavelike structure, however, the magnitudes and spatial intervals of the four peaks are far from being the same or regular. After sunset, the four-peak structure begins to move eastward with gradual weakening in its amplitude during equinoxes and this weakening proceeds much faster during June solstice. Interestingly, the longitudinal variations during December solstice do not show clear four-peak structure. All these features of the LW-4 structure are almost the same for both low and high solar activity conditions although the ion densities are greatly enhanced from low to high solar activities. With the irrelevancy of the magnetic activity in the LW-4, this implies that the large changes of the upper atmospheric ion densities, one of the important factors for ion-neutral interactions, have little effect on the formation of the LW-4 structure. On the other hand, we found that the monthly variation of the LW-4 is remarkably similar to that of the zonal component of wavenumber-3 diurnal tides at low latitudes, which implies that the lower atmospheric tidal forcing, transferred to the upper atmosphere, seems to have a dominant role in producing the LW-4 structure in the EA crests via the E-region dynamo.