• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.901-908
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• 2018

Graphite is used as a sample anode active material. However, since the maximum theoretical capacity is limited to $372mA\;h\;g^{-1}$, a new anode active material is required for the development of a high capacity lithium ion battery. The maximum theoretical capacity of Si is $4200mA\;h\;g^{-1}$, which is higher than that of graphite. However, it is not suitable for direct application to the anode active material because it has a volume expansion of 400%. In order to minimize the decrease of the discharge capacity due to the volume expansion, the Si was pulverized by the dry method to reduce the mechanical stress and the volume change of the reaction phase, and the change of the volume was suppressed by coating the carbon layers to the particle size controlled Si particles. And carbon fiber is grown like a thread on the particle surface to control secondary volume expansion and improve electrical conductivity. The physical and chemical properties of the materials were measured by XRD, SEM and TEM, and their electrochemical properties were evaluated. In this study, we have investigated the synthesis method that can be used as anode active material by improving cycle characteristics of Si.

• Geotechnical Engineering
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• v.14 no.6
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• pp.113-125
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• 1998

At the end of 1997 about 3 million tons of coal ash was produced as byproducts from the coal fired electrical power plants in Korea. Only about 27% of that byproducts was utilized as the admixtures of cement and concrete industry. But the large quantity of coal fired fly-ash has been used as the soil improvement materials in other countries. So the aim of this study is the estimation of the applicability of the coal fired fly-ash as microfine grouting materials by admixing the superfine particles which were separated from the coal fired fly-ash for the higher values. The 6 types of specimens were manufactured in the laboratory for the purpose of estimating the chemical and physical properties of cement and grouts. These specimens consisted of 2 specific surfaces of 6, 000 and 8, 000$cm^2$/g in Elaine method. And these specimens are devide into 3 ratios (30%, 50%, 70%) of fly-ash by weight. From the estimated properties of the coal fired fly-ash microflne cements and grouts, 50% fly-ash is the most suitable ratio for grouting materials. However, further study of durability is necessary for using fly-ash grouts practically at the field projects. The higher content of the unburned carbon of fly-ash increases the thinner layer of carbon on the surface of solution of grouts, and requires more quantity of surface active agent. As a results of this study, it is found that the microfine fly-ash is very useful as a good grouting material if 50% of fly-ash is added with the microfine portland cement. So, in the near future, if the coal fired fly-ash is able to be used as grouting material in Korea, the demand of fly-ash will increase rapidly.

• Korean Journal of Materials Research
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• v.5 no.7
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• pp.775-780
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• 1995

Thin films of titanium nitride are formed using the tetrakis-dimethyl-amino-titanium (TDMAT(Ti[N($CH_3$)$_2$]$_4$)) under various conditions. The formation of TiN films has been obtained from the thermal decomposition of the Ti-precursor and the gas phase reaction between TDMAT and ammonia(NH$_3$). The resistivity of the MOCVD film can be attributed to their impurity. Especially the curve fitting graph of XPS data is revealed that main impurities in the films as carbon and oxygen make various interstitial compounds which has influenced physical and electrical properties of the film. In the contact hole with the aspect ratio of 3:1 and the diameter of 0.5${\mu}{\textrm}{m}$, the SEM morphology shows that the step coverage is more decreased in the films formed y flowing ammonia additionally than the films formed by pyrolysis of TDMAT and the phenomenon is probably related with the activation energy.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.22 no.9
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• pp.1-7
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• 2008

This study is intended to compare physical properties of fluorescent luminaires with ones of LED luminaires so as to analyze fundamental characteristics of LED luminaires. For this, a comparative analysis of uniformity ratio of illuminance and luminance distribution of these two luminaires was made, and materials for applying LED luminaires to interior construction space were prepared. This study was carried out in four stages. First, a theoretical review on LED illumination light source was made compared with the existing luminaires. Second, a mock-up to control experimental variables to meet the objective of this study was manufactured. Third uniformity ratio of illuminance and luminance distribution of each luminaire were measured by using the mock-up. Fourth, a comparative analysis of uniformity ratio of illuminance and characteristics of luminance distribution of the existing fluorescent luminaires and LED ones was made. As a result of the study, the uniformity ratio of illuminance of LED luminaires, 0.559, was higher than one of the existing fluorescent luminaires, 0.522. Namely, it was shown that illuminance distribution of LED luminaires was uniform and global diffuse was good. As a result of measuring luminance distribution, it was found that luminance distribution of LED luminaires was more uniform than one of the existing fluorescent luminaires. The maximum luminance of fluorescent luminaires and LED luminaires over the wall was $180.6[cd/m^2]$ and $155.26[cd/m^2]$ respectively. Namely, the maximum luminance of fluorescent luminaires was higher than one of LED luminaires. The average luminance of fluorescent luminaires and LED luminaires was $44.32[cd/m^2]$ and $58.65[cd/m^2]$. Like this, the average luminance of LED luminaires was higher than one of fluorescent luminaires. Considering these results, it's thought that LED luminaires can give a person in the room a more comfortable working environment than fluorescent luminaires.

• Geophysics and Geophysical Exploration
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• v.13 no.4
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• pp.378-387
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• 2010

We present the results of laboratory measurement of porosity and electrical resistivity for the samples collected near marine hydrothermal deposit to provide fundamental perspective of physical properties for future electromagnetic survey. The rock cores are sampled from the host rock, pumice, hydrothermal altered zone, and chimney. These samples are featured as easily brittle, rough surface with large pores, having components easily solvable in the water. We suggest systematic approach for measuring weights, volumes of core samples to calculate density and porosity. Measurements reveal that the resistivities of black host rock, gray host rock, pumice and chimney are 102, 39, 11, 0.1 ohm-m, respectively, when the core samples are saturated with saline water of $32,000\;{\mu}S$/cm (0.5 ohm-m) at temperature of $2.5^{\circ}C$ and these correspond to the factors of 5 for sea water, 110 for pumice and 390~1020 for host rocks with respect to the resistivity of chimney. We also confirm that resistivity of rock samples saturated with water decrease with temperature linearly over the temperature range of $20{\sim}80^{\circ}C$.

• Journal of the Korean Magnetics Society
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• v.19 no.4
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• pp.121-125
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• 2009

Amorphous $Ge_1$_$_xMn_x$ semiconductor thin films grown by low temperature vapor deposition were annealed at various temperatures from 400 to $700^{\circ}C$ for 3 minutes in high vaccum chamber. The electrical and magnetotransport properties of as-grown and annealed samples have been studied. X-ray diffraction patterns analysis revealed that the samples still maintain amorphous state after annealling at $500^{\circ}C$ for 3 minutes and they were crystallized when annealing temperature increase to $600^{\circ}C$. Temperature dependence of resistivity measurement implied that as-grown and annealed $Ge_1$_$_xMn_x$ films have semiconductor characteristics, the increase of resistivity with annealling temperature was obseved. The $700^{\circ}C$-annealed sample exhibited negative magnetoresistance (MR) at low temperatures and the MR ratio was ${\sim}$8.5% at 10 K. The asymmetry was present in all MR curves. The anomalous Hall Effect was also observed at 250 K.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.861-867
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• 2019

$Li_4Ti_5O_{12}$ is a promising next-generation anode material for lithium-ion batteries due to excellent cycle life, low irreversible capacity, and little volume expansion during charge-discharge process. However, it has poor charge capacity at high current density due to its low electrical conductivity. To improve this weakness, porous $Li_4Ti_5O_{12}$ was synthesized by sol-gel method with P123 as chelating agent. The physical characteristics of as-prepared sample was investigated by XRD, SEM, and BET analysis, and electrochemical properties were characterized by cycle performance test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS). $Li_4Ti_5O_{12}$ synthesized by 0.01mol ratio of P123/Ti showed most unified particle size, high specific surface area, and relatively high porosity. EIS analysis showed that depressed semicircle size was remarkably reduced, which suggested resistance value in electrode was decreased. Capacity in rate performance showed 178 mAh/g at 0.2C, 170 mAh/g at 0.5C, 110 mA/h at 5C, and 90 mAh/g at 10C. Capacity retention also showed 99% after rate performance.

• Journal of the Korean Chemical Society
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• v.37 no.11
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• pp.923-928
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• 1993

The series of solid solutions in the $Sr_{1+x}Ho_{1-x}FeO_{4-y}$ (x = 0.00, 0.25, 0.50, 0.75 and 1.00) systems with $K_2NiF_4$ type structure have been prepared at 1550$^{\circ}$C under an atmospheric air pressure. The X-ray powder diffraction spectra of these samples assign that the crystallographic phases are tetragonal system over the whole x range. The lattice volume was increased with increasing the substitution amount of the $Sr^{2+}$ ion. The mole ratio of the $Fe^{4+}$ ion to total iron ions or ${\tau}$ value has been determined by Mohr salt titration of the sample and then the y value was calculated from x and ${\tau}$ values. The ${\tau}$ and y values have been increased with x values. The nonstoichiometric chemical formula are formulated from the general formula of $Sr_{1+x}Ho_{1-x}Fe^3_{1-}\;^+_{\tau}Fe_{\tau}^{4+}O_{4-y}$ replaced by x,${\tau}$ and y values. Mossbauer spectra show the mixed valence state and coordination state of $Fe^{3+}\;and\;Fe^{4+}$ ions. It is found out that the magnetic property of the samples is paramagnetic at room temperature. Electrical conductivity varied within the semiconductivity range of 1.0 to 1 ${\times}\;10^{-9}{\Omega}^{-1}cm^{-1}$. Activation energy of the electrical conductivity was decreased with the $\tau$ value. The conduction mechanism should be explained by the hopping model of the conduction electrons between the valence states of $Fe^{3+}\;and\;Fe^{4+}$ ions.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2013.10a
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• pp.914-916
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• 2013

Renewable energy from the environment in a variety of ways to obtain various forms of energy. Recent functional polymer composites (EAP) to take advantage of the pressure and vibration of physical energy into electrical energy storage, to take advantage of current collector technology is attracting attention. EAP, a type of IPMC (Ionic exchange Polymer Composite) got a hydrophilic properties, marine power plants is being studied as a source of energy. Studies using IPMC marine power plant because there is a constraint on the time, IPMC in real time, which can measure the power generated by the system is required, Due to the nature of the power plant to be floating in the sea through the power cable and data transmission measurement system is hard drive self-generation and wireless data transmission system is required. In this study, IPMC marine power plant is to develop a system of monitoring. IPMC for several power plants to build individual current-voltage measurement system, CAN communication with the main system to collect all the information and wireless data transmission to occur, and Generation of electricity using solar energy to building systems in real-time without an external power supply to drive the measuring system is to develop a monitoring system.

• Journal of the Microelectronics and Packaging Society
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• v.18 no.4
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• pp.19-25
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• 2011

The size reduction of the semiconductor chip and the improvement of the electrical performance have been enabled through the introduction of the Cu/Low-K process in modern electronic industries. However, Cu/Low-K has a disadvantage of the physical properties that is weaker than materials used for existing semiconductor manufacture process. It causes many problems in chip manufacturing and package processes. Especially, the delamination between the Cu layer and the low-K dielectric layer is a main defect after the temperature cycles. Since the Cu/Low-K layer is located on the top of the pad of the flip chip, the stress on the flip chip affects the Cu/Low-K layer directly. Therefore, it is needed to improve the underfill process or materials. Especially, it becomes very important to select the underfill to decrease the stress at the flip-chip and to protect the solder bump. We have solved the delamination problem in a 90 nm Cu/Low-K flip-chip package after the temperature cycle by selecting an appropriate underfill.