• Title/Summary/Keyword: phosphor

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Luminescent Properties of BaSi2O5:Eu2+ Phosphor Film Fabricated by Spin-Coating of Ba-Eu Precursor on SiO2 Glass

  • Park, Je Hong;Kim, Jong Su;Kim, Jong Tae
    • Journal of the Optical Society of Korea
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    • v.18 no.1
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    • pp.45-49
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    • 2014
  • Well-crystallized $BaSi_2O_5:Eu^{2+}$ phosphor films were synthesized by heat treatment of spin-coated BaO:Eu on $SiO_2$ glass. We investigated luminescence-structure properties of these phosphor films as a function of heat-treatment temperature. From x-ray diffraction patterns, our $BaSi_2O_5:Eu^{2+}$ phosphor films revealed that (111)- and (204)-crystal planes of $BaSi_2O_5$ crystal were dominantly increased with an increase of heat-treatment temperature. Photoluminescence intensities of $BaSi_2O_5:Eu^{2+}$ phosphor films were increased with amount of these crystal planes. It can be explained that $Eu^{2+}$ ions were stably occupied at specific crystal orientation of $BaSi_2O_5$ crystal, enhancing the luminescent intensities of $BaSi_2O_5:Eu^{2+}$ phosphor films. In addition, our $BaSi_2O_5:Eu^{2+}$ phosphor films had transmittance of 70% at 510 nm,.due to the dense morphology and specific crystallinity of $BaSi_2O_5:Eu^{2+}$ phosphor films.

Fabrication of Red and Green Phosphor Ink for the Micro LED Color Filter Using Ink-Jet Process (Micro LED 제작을 위한 Color Filter용 잉크젯 공정 적색, 녹색 형광체 잉크 연구)

  • Bo Joong Kim;Si Hong Ryu;Hyo Sil, Yang;Young Boo Moon;Chang-Bun Yoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.5
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    • pp.494-499
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    • 2023
  • In this paper, in order to apply the CF (color filter) type of the micro light emitting device (Micro LED) display method, a study on the manufacturing process of red and green phosphor inks for the inkjet process was conducted. The blue light-emitting KSF and LuAG phosphors were respectively used to control the phosphor particle size to about 1㎛, and a phosphor ink was prepared by synthesizing with a low-viscosity solution (IPA/Eg). A chemical dispersion method was applied to selectively control the dispersion characteristics in the manufacture of phosphor inks, and in particular, phosphor inks with a dispersant applied a dispersant secured stable dispersion characteristic compared to phosphor inks without a dispersion process. Therefore, it seems possible to manufacture CF for Micro LED through an inkjet process capable of controlling the dispersion characteristics of phosphor ink.

Photoluminescence and Long-phosphorescent Characteristics of SrAl2O4:Eu2+,Dy3+ Phosphor by Glycine-nitrate Combustion Method (글리신-질산염 연소법으로 합성된 SrAl2O4:Eu2+,Dy3+ 형광체의 발광 및 장잔광 특성)

  • Lee, Young-Ki;Kim, Jung-Yeul;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.20 no.7
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    • pp.364-369
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    • 2010
  • A $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor powder with stuffed tridymite structure was synthesized by glycine-nitrate combustion method. The luminescence, formation process and microstructure of the phosphor powder were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). The XRD patterns show that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was an amorphous phase. However, a crystalline $SrAl_2O_4 $ phase was formed by calcining at $1200^{\circ}C$ for 4h. From the SEM analysis, also, it was found that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was in irregular porous particles of about 50 ${\mu}m$, while the calcined phosphor was aggregated in spherical particles with radius of about 0.5 ${\mu}m$. The emission spectrum of as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor did not appear, due to the amorphous phase. However, the emission spectrum of the calcined phosphor was observed at 520 nm (2.384eV); it showed green emission peaking, in the range of 450~650 nm. The excitation spectrum of the $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor exhibits a maximum peak intensity at 360 nm (3.44eV) in the range of 250~480 nm. After the removal of the pulse Xe-lamp excitation (360 nm), also, the decay time for the emission spectrum was very slow, which shows the excellent longphosphorescent property of the phosphor, although the decay time decreased exponentially.

Red-emitting α-SrO·3B2O3:Sm2+ Phosphor for WLED Lamps: Novel Lighting Properties with Two-layer Remote Phosphor Package

  • Tin, Phu Tran;Nguyen, Nhan K.H.;Tran, Minh Q.H.;Lee, Hsiao-Yi
    • Current Optics and Photonics
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    • v.1 no.4
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    • pp.389-395
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    • 2017
  • This paper investigates a method to improve the lighting performance of white light-emitting diodes (WLEDs), which are packaged using two separate remote phosphor layers, a yellow-emitting YAG:Ce phosphor layer and a red-emitting ${\alpha}-SrO{\cdot}3B_2O_3:Sm^{2+}$ phosphor layer. The thicknesses of these two layers are $800{\mu}m$ and $200{\mu}m$, respectively. Both of them are examined in conditions where the average correlated color temperatures (CCT) are 7700 K and 8500 K. For this two-layer model, the concentration of red phosphor is varied from 2% to 30% in the upper layer, while in the lower layer the yellow phosphor concentration is kept at 15%. It was found interestingly that the lighting properties such as color rendering index (CRI) and luminous flux are enhanced significantly, while the color uniformity is maintained in a relatively close range to the one of one-layer configuration (measured at the same correlated color temperature). Besides, the transmitted and reflected light of each phosphor layer are revised by combining Kubelka-Munk and Mie-Lorenz theories. Through analysis, it is demonstrated that the packaging configuration of two-layer remote phosphor that employs red-emitting ${\alpha}-SrO{\cdot}3B_2O_3:Sm^{2+}$ phosphor particles provides a practical solution for general WLEDs lighting.

Development of Display by Screen Printing and Heat-transfer (스크린 인쇄법 및 열 전사법에 의한 디스플레이 개발)

  • 이현철;남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.20 no.1
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    • pp.102-112
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    • 2002
  • Cathode ray tubes (CRT) are the most common electronic display in use in information technology. The CRT consists of an electron gun, electrostatic or magnetic fields to direct the electron beam, and a phosphor screen. When the electron beam strikes the phosphor screen, the phosphor generates light. The phosphor screen has formed by precipitation method, electro-forming and centrifuge method. The high quality product was achieved by electro-forming or centrifuge method. Now applying method is electro-forming used with phosphor and Eh(isopropyl alcohol). Now applying method has been much consumption of raw-material, dirty working environment, dangerous fire and require of high cost. New method to form phosphor surface of monochrome is required to improve this matter. This study was developed novel method to form the phosphor surface by heat-transfer method. This method have advantages of simple process, automatization, clean environment, saving raw material and saving running-cost.

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Study on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp (I) Metal Layer (전계방출광원용 고효율 에노드 형광막 특성 연구(I) - 금속막)

  • Lee, Sun-Hee;Kim, Kwang-Bok;Kim, Yong-Won;You, Yong-Chan
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.05a
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    • pp.7-10
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    • 2007
  • The electron charging and degradation of anode phosphor layers are showed major problems in high electric field with anode electrode of field emission devices. An Al metal layer on the phosphor layer may get rid of these problems. This Al metal layer are formed with the roughness of phosphor surface layer without interlayer and cannot be given rise to enhance the luminance efficiency. In order to enhance the brightness, an anode layer need to be flated between phosphor layer and Al metal layer in anode electrode. After optimizing the anode phosphor layer, an anode layer with Al metal and inter layer increased the brightness and luminescence efficiency 1.5 times more than only phosphor layer in anode.

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Study on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp (II) - Diffused Reflection Layer (전계방출광원용 고효율 에노드 형광막 특성 연구(II) - 난반사막)

  • Lee, Sun-Hee;Kim, Kwang-Bok;Kim, Yong-Won;You, Yong-Chan;Kim, Do-Jin
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2007.05a
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    • pp.89-91
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    • 2007
  • In order to decrease the degradation of phosphor on anode, many kinds of methods try to do coating of phosphor powders and AI metal layer of anode phosphor, In case of direct coating of phosphor powder, thin and uniform coating process are difficult to cover homogeneous in the surface of phosphor powders and given rise to decrease the brightness, Anti-reflection-layer(ARC) with $TiO_2$, $Al_2O_3$, $Y_2O_3$ showed 103[%] the enhancement of brightness in comparable with normal phosphor layer.

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New Phosphor and Material Structures for Displays

  • Summers, Christopher J.;King, Jeffrey;Park, Woun-Jhang
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.243-252
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    • 2002
  • We propose a new concept: that of photonic crystal phosphors (PCPs) for display and phosphor related applications. It is well known that microcavities with dimensions comparable to the emitting wavelength strongly enhance light-matter interactions, resulting in a significant increase in spontaneous emission rate, which can be directly translated into enhancement in phosphor efficiency. In recent simulations we have demonstrated that when a microcavity is formed in a nano-phosphor structure, the luminescence band is modified, and can be made spectrally sharp and tunable by engineering the geometry/material properties of the cavity and the surrounding photonic crystal lattice. New phosphor material structures based on photonic crystals are proposed. Applications to thin film EL phosphors and particle phosphors are discussed. Additionally, economic methods of synthesizing and incorporating PCPs into current display applications are proposed.

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A Study on VPT phosphor screen formed by screen printing and thermal transfer method (스크린 인쇄법 및 열전사법에 의한 VPT 형광막의 형성연구)

  • Cho M.J.;Nam S.Y.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.593-594
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    • 2006
  • A novel thermal transfer method was developed to form the phosphor screen for VPT(Video Phone Tube). This method have advantages of simple process, clean environment, saving raw material and running-cost comparison of electrodeposition, spin coating of conventional methods. But now applying phosphor screen for thermal transfer method has been formed three layers (phosphor layer, ITO layer and thermal adhesive layer) on the PET film as substrate. This is complex process, run to waste of raw-material and require of high cost. Also ITO paste at present has been imported from Japan. To improve these problems, we have manufactured phosphor screen formed by two layers (phosphor layer and ITO layer). We have developed ITO paste that had both conductive and excellent thermal transfer abilities, made it of domestic raw-material.

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The Luminescence Properties of YAG:$Tb^{3+}$ Phosphor Prepared by Hydrothermal Synthesis (YAG:$Tb^{3+}$ 형광체 분말의 수열합성과 발광 특성)

  • 김상문;지성훈;구자인;김태옥
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.745-750
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    • 2000
  • YAG:Tb3+ as green phosphor were studied for the development of low voltage FED phosphor prepared by hydrothermal synthesis. We changed the concentration of luminescence center ion Tb3+ in hydrothermal reaction of which conditions were at 8M NH4OH as mineralizer, at 35$0^{\circ}C$ for 12hrs. As results, we could finally get the YAG:Tb3+ (Y3-xTbxAl5O12) powder of which particle size was about 0.2~1.0${\mu}{\textrm}{m}$. The excitation spectra and the green emitted spectra of YAG:Tb3+ phosphor powder were observed. When we doped 0.25 mol Tb to YAG, we could observe the maximum cathodoluminescence from YAG:Tb3+ phosphor and the chromaticity coordinate of the phosphor was shown x=0.35, y=0.56 in CIE1931 diagram.

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