• Title/Summary/Keyword: phase behavior

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Precipitation Behavior of Laves Phase in 10%Cr Ferrite System Alloy (10%Cr 페라이트계 합금에서 라베스상의 석출거동에 관한 연구)

  • Kim, I.S.;Kang, C.Y.;Bae, D.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.21-30
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    • 1999
  • The present study were investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and precipitation of laves phase under stress. Hardness changes in ferrite phase appeared two hardness peaks by precipitation of initial fine precipitator and laves phase in 3Mo-0.3Si and 3Mo-0.3Si-C specimens, respectively. Hardness changes in martensite phase of 3Mo-0.3Si-C specimen was lower in the initial stage of aging by carbide precipitation and after this, increased by re-hardening due to precipitation of laves phase. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time, laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. In the ferrite-martensite interface, laves phase was mainly precipitated and carbide was mainly formed at boundary of lath martensite than grain boundary. Adding the stress in aging, fine precipitator of inital precipitation of laves phase precipitated in (100) of perpendicular to tensile direction and has grown to only followed<010>direction and also, volume fraction of laves phase increased. Consequently, the stress added was accelerated initial precipitation of laves phase.

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Crystallization behavior of Cu-base bulk metallic glass in supercooled liquid region during compression and tension (과냉각 액상구간에서 압축.인장시 Cu기 비정질 합금의 결정화 거동)

  • Park, E.S.;Kim, S.H.;Huh, M.Y.;Kim, H.W.;Bae, J.C.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.215-217
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    • 2008
  • Crystallization behavior of the bulk metallic glass (BMG) during compression and tension was studied in the supercooled liquid region (SLR). Rod samples of the BMG alloy were produced by consolidating gas atomized powders of $Cu_{54}Zr_{22}Ti_{18}Ni_6$ using spark plasma sintering. The crystallization behavior in these samples was examined by tackling changes in thermal property during heating the samples in DSC. The present BMG alloy was firstly decomposed and then crystallized during annealing in the SLR. The phase decomposition from the original amorphous phase was retarded by the compressive stress, while it was accelerated by the tensile stress.

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Convergence Behavior of the filtered-x LMS Algorithm for Active Noise Caneller

  • Lee, Kang-Seung
    • The Journal of the Acoustical Society of Korea
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    • v.17 no.2E
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    • pp.10-15
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    • 1998
  • Application of the Filtered-X LMS adaptive filter to active noise cancellation requires to estimate the transfer characteristics between the output and the error signal of the adaptive canceler. In this paper, we derive an adaptive cancellation algorithm and analyze is convergence behavior when the acoustic noise is assumed to consist of multiple sinusoids. The results of the convergence analysis of the Filtered-X LMS algorithm indicate that the effects of parameter estimation inaccuracy on the convergence behavior of the algorithm are characterize by two distinct components : Phase estimation error and estimated magnitude. In particular, the convergence of the Filtered-X LMS algorithm is show to be strongly affected by the accuracy of the phase response estimate. Simulation results of the algorithm are presented which support the theoretical convergence analysis.

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Molecular Dynamics Simulation of Nano-Deformation Behavior of the Grain-Size Controlled Rheology Material (분자동력학을 이용한 결정립 제어 레오로지 소재의 나노 변형거동 전산모사)

  • Kim J. W.;Youn S. W.;Kang C. G.
    • Transactions of Materials Processing
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    • v.14 no.4 s.76
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    • pp.319-326
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    • 2005
  • In this study, the nano-deformation behavior of semi-solid Al-Si alloy was investigated using a molecular dynamics simulation as a part of the research on the surface crack behavior in thixoformed automobile parts. The microstructure of the grain-size controlled Al-Si alloy consists of primary and eutectic regions. In eutectic regions the crack initiation begins with initial fracture of the eutectic silicon particles and inside other intermetallic phases. Nano-deformation characteristics in the eutectic and primary phase of the grain-size controlled Al-Si alloy were investigated through the molecular dynamics simulation. The primary phase was assumed to be single crystal aluminum. It was shown that the vacancy occurred at the zone where silicon molecules were.

Thermal Behavior of Langmuir-Blodgett Film of Poly(tert-butyl methacrylate) by Principal Component Analysis Based Two-Dimensional Correlation Spectroscopy

  • Jung, Young-Mee;Kim, Seung-Bin
    • Bulletin of the Korean Chemical Society
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    • v.26 no.12
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    • pp.2027-2032
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    • 2005
  • This paper demonstrates details of thermal behavior of Langmuir-Blodgett (LB) film of poly(tert-butyl methacrylate) (PtBMA) by using the principal component analysis based two-dimensional correlation spectroscopy (PCA2D) through eigenvalue manipulating transformation (EMT). By uniformly lowering the power of a set of eigenvalues associated with the original data, the smaller eigenvalues becomes more prominent and the subtle contribution from minor components is now highlighted much more strongly than the original data. Thus, the subtle difference of thermal behavior of LB film of PtBMA from minor components, which is not readily detectable in the conventional 2D correlation analysis, is much more noticeable than the original data. PCA2D correlation spectra with EMT operation for the temperature-dependent IR spectra of LB film of PtBMA reveal the hidden property of phase transition processes during heating.

Sintering Behavior, Dielectric and Pyroelectric Properties of $(Pb, La)TiO_3$ Ceramics ($(Pb, La)TiO_3$ 세라믹스의 소결 거동 및 유전.초전 특성)

  • 최동구;최시경
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.841-848
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    • 1994
  • The sintering behavior of La-modified PbTiO3 ceramics was investigated in order to improve the poor sinterability of PbTiO3. Addition of La improved the sinterability. It was confirmed that this improvement was due to the decrease in tetragonality ratio c/a of crystal lattice. The variations of dielectric constant and pyroelectric coefficient were measured with temperature. It was observed that with the increase of La content, Curie temperature decreased and dielectric constant at room temperature increased. La-modified PbTiO3 ceramics had smaller pyroelectric figure of merits than those of pyroelectric materials in use. The effects of grain size on dielectric and pyroelectric properties were also investigated. The change of grain size had effect on maximum dielectric constant and pyroelectric coefficient, but is had little effect on pyroelectric figure of merit at room temperature. The closer examination near ferro-paraelectric phase transition temperature revealed that the behavior of phase transition approached a more relaxor character with the increase of La content and the decrease of grain size.

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Fatigue Frequency Effect of High Temperature Fatigue Fracture Behavior of $Al_2O_3$-33Vol.% $SiC_w$ ($Al_2O_3$-33Vol.% $SiC_w$의 고온피로에 미치는 피로하중주파수의 영향)

  • 김송희
    • Journal of the Korean Ceramic Society
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    • v.28 no.10
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    • pp.785-792
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    • 1991
  • An investigation of the crack propagation behavior of Al2O3-33Vol.% SiCw at 140$0^{\circ}C$ was conducted with various loading frequencies. Higher crack propagation was observed in lower frequency and higher load ratios. Interface sliding fracture due to glassy phase from the oxidation of SiCw and cavitation along grain boundary of diffusional creep appeared to be the main mechanism of fatigue fracture in slower crack propagation while interface sliding and whisker pull out aided by glassy phase formation played main role of fatigue fracture for higher crack growth condition. The frequency effect on deformation behavior was discussed with a Maxwell model.

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Convergence of the Filtered-x Least Mean Square Adaptive Algorithm for Active Noise Control of a Multiple Sinusoids (다중 정현파의 능동소음제어를 위한 Filtered-x 최소 평균제곱 적응 알고리듬 수렴 연구)

  • 이강승
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.13 no.4
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    • pp.239-246
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    • 2003
  • Application of the filtered-x Least Mean Square(LMS) adaptive filter to active noise control requires to estimate the transfer characteristics between the output and the error signal of the adaptive controller. In this paper, we derive the filtered-x adaptive noise control algorithm and analyze its convergence behavior when the acoustic noise consists of multiple sinusoids. The results of the convergence analysis of the filtered-x LMS algorithm indicate that the effects of the parameter estimation inaccuracy on the convergence behavior of the algorithm are characterized by two distinct components Phase estimation error and estimated gain. In particular, the convergence is shown to be strongly affected by the accuracy of the phase response estimate. Simulation results are presented to support the theoretical convergence analysis.

The Effects of Maternal Parenting Variables on Preschool Children's Self Regulation (어머니의 양육관련 변인과 유아의 자기조절 능력과의 관련성 탐색)

  • Cho, Young-Suk;Lee, Yang-Hee
    • Journal of the Korean Home Economics Association
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    • v.47 no.6
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    • pp.51-66
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    • 2009
  • The purpose of this study was to develop a model for preschool children's self regulation by examining the effects of maternal parenting variables on preschool children's self regulation. The subjects were 1219 mothers of 4- to 6-year-old preschool children attending kindergarten or child care centers located in Seoul and Kyunggi Province, Korea. For data analysis, exploratory factor analysis(EFA) and confirmatory factor analysis(CFA) were applied to the survey data in the first phase and structural equation modeling(SEM) analysis in the second phase. The major results of this study were as follows: maternal parenting stress and maternal behavior were the most direct influential variables on preschool children's self-regulation. Moreover, maternal parenting efficacy was indirectly mediated through maternal behavior.

Laminar Forced Convective Heat Transfer to Near-Critical Water in a Tube

  • Lee, Sang-Ho
    • Journal of Mechanical Science and Technology
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    • v.17 no.11
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    • pp.1756-1766
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    • 2003
  • Numerical modeling is carried out to investigate forced convective heat transfer to near-critical water in developing laminar flow through a circular tube. Due to large variations of thermo-physical properties such as density, specific heat, viscosity, and thermal conductivity near thermodynamic critical point, heat transfer characteristics show quite different behavior compared with pure forced convection. With flow acceleration along the tube unusual behavior of heat transfer coefficient and friction factor occurs when the fluid enthalpy passes through pseudocritical point of pressure in the tube. There is also a transition behavior from liquid-like phase to gas-like phase in the developing region. Numerical results with constant heat flux boundary conditions are obtained for reduced pressures from 1.09 to 1.99. Graphical results for velocity, temperature, and heat transfer coefficient with Stanton number are presented and analyzed.