• 제목/요약/키워드: pH Sensor

검색결과 488건 처리시간 0.023초

TEM법에 의한 모르타르 중의 철근 부식 측정에 관한 연구 (A Study on the Measurement of Steel Corrosion in Mortar by TEM Method)

  • 이상호;한정섭
    • 한국해양공학회지
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    • 제20권2호
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    • pp.59-65
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    • 2006
  • Steel, as a reinforcing mechanism in concrete, provides the tensile strength that is lacking in concrete, alone, and the high alkaline environment (pH 12.5) in concrete offers satisfactory protection against most corrosion of the steel. However, the corrosion of reinforcing steel in concrete can occur by chloride attack or carbonation, and it can cause a loss of integrity a section and concrete failure through cracking and spalling. In this study, a transient electro magnetic method (TEM) of a nondestructive technique is adapted to study the measuring method of steel corrosion in mortar. The sensor was made of an enameled wire, with a diameter of 0.25mm and anacril. He sensor configuration used was a coincident loop type. The secondary electro motive force (2nd EMF) was measured with SIROTEMIII, which equipped the accelerator. The accelerator allowsthe transmitter to turn off approximately $10\sim15$ times faster than normal. The high-resolution time series, used for very shallow or a high resistivity investigation was selected. After steels were corroded by the salt spray, during 4, 8, 15 and 25 days, they were embedded in mortar. The content results acquired in this study are as follows. The variation of the secondary electro motive force (2nd EMF) was shown by the change of steel surface with different corrosion time steel. It was confirmed that measurement of steel corrosion in mortar by a transient electro-magnetic method (TEM) can be possible.

Amperometric Glucose Biosensor Based on Sol-Gel-Derived Zirconia/Nafion Composite Film as Encapsulation Matrix

  • Kim, Hyun-Jung;Yoon, Sook-Hyun;Choi, Han-Nim;Lyu, Young-Ku;Lee, Won-Yong
    • Bulletin of the Korean Chemical Society
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    • 제27권1호
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    • pp.65-70
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    • 2006
  • An amperometric glucose biosensor has been developed based on the use of the nanoporous composite film of sol-gel-derived zirconia and perfluorosulfonated ionomer, Nafion, for the encapsulation of glucose oxidase (GOx) on a platinized glassy carbon electrode. Zirconium isopropoxide (ZrOPr) was used as a sol-gel precursor for the preparation of zirconia/Nafion composite film and the performance of the resulting glucose biosensor was tuned by controlling the water content in the acid-catalyzed hydrolysis of sol-gel stock solution. The presence of Nafion polymer in the sol-gel-derived zirconia in the biosensor resulted in faster response time and higher sensitivity compared to those obtained at the pure zirconia- and pure Nafion-based biosensors. Because of the nanoporous nature of the composite film, the glucose biosensor based on the zirconia/Nafion composite film can reach 95% of steady-state current less than 5 s. In addition, the biosensor responds to glucose linearly in the range of 0.03-15.08 mM with a sensitivity of 3.40 $\mu$A/mM and the detection limit of 0.037 mM (S/N = 3). Moreover, the biosensor exhibited good sensor-to-sensor reproducibility (~5%) and long-term stability (90% of its original activity retained after 4 weeks) when stored in 50 mM phosphate buffer at pH 7 at 4 ${^{\circ}C}$.

Terra-Scope - a MEMS-based vertical seismic array

  • Glaser, Steven D.;Chen, Min;Oberheim, Thomas E.
    • Smart Structures and Systems
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    • 제2권2호
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    • pp.115-126
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    • 2006
  • The Terra-Scope system is an affordable 4-D down-hole seismic monitoring system based on independent, microprocessor-controlled sensor Pods. The Pods are nominally 50 mm in diameter, and about 120 mm long. They are expected to cost approximately $6000 each. An internal 16-bit, extremely low power MCU controls all aspects of instrumentation, eight programmable gain amplifiers, and local signal storage. Each Pod measures 3-D acceleration, tilt, azimuth, temperature, and other parametric variables such as pore water pressure and pH. Each Pod communicates over a standard digital bus (RS-485) through a completely web-based GUI interface, and has a power consumption of less than 400 mW. Three-dimensional acceleration is measured by pure digital force-balance MEMS-based accelerometers. These accelerometers have a dynamic range of more than 115 dB and a frequency response from DC to 1000 Hz with a noise floor of less than $30ng_{rms}/{\surd}Hz$. Accelerations above 0.2 g are measured by a second set of MEMS-based accelerometers, giving a full 160 dB dynamic range. This paper describes the system design and the cooperative shared-time scheduler implemented for this project. Restraints accounted for include multiple data streams, integration of multiple free agents, interaction with the asynchronous world, and hardened time stamping of accelerometer data. The prototype of the device is currently undergoing evaluation. The first array will be installed in the spring of 2006.

Extension of the Dynamic Range using the Switching Operation of In-Pixel Inverter in Complementary Metal Oxide Semiconductor Image Sensors

  • Seong, Donghyun;Choi, Byoung-Soo;Kim, Sang-Hwan;Lee, Jimin;Lee, Jewon;Lee, Junwoo;Shin, Jang-Kyoo
    • 센서학회지
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    • 제28권2호
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    • pp.71-75
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    • 2019
  • This paper proposes the extension of the dynamic range in complementary metal oxide semiconductor (CMOS) image sensors (CIS) using switching operation of in-pixel inverter. A CMOS inverter is integrated in each unit pixel of the proposed CIS for switching operations. The n+/p-substrate photodiode junction capacitances are added to each unit pixel. When the output voltage of the photodiode is less than half of the power supply voltage of the CMOS inverter, the output voltage of the CMOS inverter changes from 0 V to the power supply voltage. Hence, the output voltage of the CMOS inverter is adjusted by changing the supply voltage of the CMOS inverter. Thus, the switching point is adjusted according to light intensity when the supply voltage of the CMOS inverter changes. Switching operations are then performed because the CMOS inverter is integrated with in each unit pixel. The proposed CIS is composed of a pixel array, multiplexers, shift registers, and biasing circuits. The size of the proposed pixel is $10{\mu}m{\times}10{\mu}m$. The number of pixels is $150(H){\times}220(V)$. The proposed CIS was fabricated using a $0.18{\mu}m$ 1-poly 6-metal CMOS standard process and its characteristics were experimentally analyzed.

양식장 환경 데이터 모니터링 시스템의 구현 및 성능 평가 (Implementation and Performance Evaluation of Environmental Data Monitoring System for the Fish Farm)

  • 아리아 비스마 와휴타마;황민태
    • 한국정보통신학회논문지
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    • 제26권5호
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    • pp.743-754
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    • 2022
  • 본 논문은 양식장의 환경 데이터 모니터링 시스템 개발 및 성능 평가 결과를 담고있다. 하드웨어 개발을 위해 용존 산소량, 질소 이온 농도, 염도 및 해수 온도 데이터 수집을 위한 아날로그 센서들과 외부 온습도 및 위치 정보를 수집하기 위한 디지털 센서들을 이용하였으며, 이들 수집 데이터들을 클라우드 기반의 Firebase DB에 전달하기 위한 통신 모듈로 LoRa 송수신 세트를 이용하였다. Firebase에 저장되는 수집 데이터들은 웹 브라우저와 모바일 단말기 상에서 그래프 형태로 출력해 양식장 환경 데이터 변화를 실시간으로 관찰할 수 있도록 하였으며, 임계치를 지정해 수집 데이터가 이 범위를 벗어나는 경우 모바일 단말기 상에 실시간 알림이 도착하도록 구현하였다. 개발 시스템의 성능 평가를 위해 하드웨어 모듈에서부터 웹/모바일 애플리케이션까지 타임 스탬프 기반의 응답 시간을 측정한 결과 6.2초에서 6.85초 사이의 변화를 보여주고 있어 만족할 만한 결과임을 알 수 있었다.

탄소나노튜브 대면적 어셈블리를 통한 고감도-고선택성 과산화수소 센서 개발 (Highly sensitive and selective enzymatic detection for hydrogen peroxide using a non-destructively assembled single-walled carbon nanotube film)

  • 이동욱;안희호;서병관;이승우
    • 센서학회지
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    • 제30권4호
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    • pp.229-235
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    • 2021
  • This study presents a simple approach for the assembly of a free-standing conductive electronic nanofilm of single-walled carbon nanotubes (SWNTs) suitable for enzymatic electrochemical biosensors. A large-scale SWNT electronic film was successfully produced by the dialysis of p-Terphenyl-4,4''-dithiol (TPDT)-treated SWNTs. Furthermore, Horseradish peroxidase (HRP) was immobilized on the TPDT-SWNT electronic film, and the enzymatic detection of hydrogen peroxide (H2O2) was demonstrated without mediators. The detection of H2O2 in the negative potential range (-0.4 V vs. Ag/AgCl) was achieved by direct electron transfer of heme-based enzymes that were immobilized on the TPDT-SWNT electronic film. The SWNT-based biosensor exhibited a wide detection range of H2O2 from 10 µM to 10 mM. The HRP-doped SWNT electronic film achieved a high sensitivity of 342 ㎛A/mM·cm2 and excellent selectivity against a variety of redox-active interfering substances, such as ascorbic acid, uric acid, and acetaminophen.

섬유 보강 복합레진의 섬유 방향이 중합수축에 미치는 영향 (EFFECT OF FIBER DIRECTION ON THE POLYMERIZATION SHRINKAGE OF FIBER-REINFORCED COMPOSITES)

  • 염중원;이인복
    • Restorative Dentistry and Endodontics
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    • 제34권4호
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    • pp.364-370
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    • 2009
  • 본 연구의 목적은 strain gage와 LVDT (linear variable differential transformer) 변위센서를 이용하여 섬유 보강 복합레진에서 섬유의 방향이 복합레진의 중합수축에 미치는 영향을 알아보기 위함이다. 지름 10 mm, 높이 2 mm의 원반 모양 유동성 복합레진 (Aeliteflo A2, Bisco, Inc., IL, USA) 중앙에 유리섬유 (X-80821P Glass Fiber, Bisco, Inc., IL, USA)를 위치시키고, 섬유가 배열된 장축 방향 (longitudinal)과 수직방향 (transversal)의 중합수축량을 strain gage (Linear S-series 350${\Omega}$, CAS, Seoul, Korea)를 이용하여 각각 측정하였다. 사용된 유동성 복합레진 자체의 free 중합수축을 구하기 위해 지름 7 mm, 높이 1 mm의 원반 모양 시편의 수직 방향 (axial) free 중합수축값을 LVDT로 측정하였다. 중합된 시편들을 절단하여 주사전자현미경으로 복합 레진 내부의 섬유배열을 관찰하고 각 군에서 측정된 평균 수축값들을 ANOVA로 비교하였고 Scheffe post-hoc test로 사후 검정하였다 (${\alpha}$=0.05). 섬유가 배열된 평면 상에서 복합레진의 중합수축 (radial shrinkage)은 섬유와 평행한 방향에서 감소하고 섬유와 수직한 방향에서 증가했다 (p<0.05). 본 연구의 결과 섬유 보강 복합레진으로 스플린트나 수복물을 제작할 때 중합수축량은 보강된 섬유의 배열방향에 따라 큰 차이가 남을 알 수 있었다.

Copper(II) Selective PVC Membrane Electrodes Based on Schiff base 1,2-Bis (E-2-hydroxy benzylidene amino)anthracene-9,10-dione Complex as an Ionophore

  • Jeong, Eun-Seon;Lee, Hyo-Kyoung;Ahmed, Mohammad Shamsuddin;Seo, Hyung-Ran;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • 제31권2호
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    • pp.401-405
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    • 2010
  • The Schiff base 1,2-bis(E-2-hydroxy benzylidene amino)anthracene-9,10-dione has been synthesized and explored as ionophore for preparing PVC-based membrane sensors selective to the copper ($Cu^{2+}$) ion. Potentiometric investigations indicate high affinity of these receptors for copper ion. The best performance was shown by the membrane of composition (w/w) of ionophore: 1 mg, PVC: 33 mg, DOP: 66 mg and KTpClPB as additive were added 50 mol % relative to the ionophore in 1 ml THF. The proposed sensor's detection limit is $2.8{\times}10^{-7}$ M over pH 5 at room temperature (Nernstian slope 31.76 mV/dec.) with a response time of 15 seconds and showed good selectivity to copper ion over a number of interfering cations.

A Facile Electrochemical Fabrication of Reduced Graphene Oxide-Modified Glassy Carbon Electrode for Simultaneous Detection of Dopamine, Ascorbic Acid, and Uric Acid

  • Yu, Joonhee;Kim, Tae Hyun
    • Journal of Electrochemical Science and Technology
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    • 제8권4호
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    • pp.274-281
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    • 2017
  • This paper describes the simple fabrication of an electrode modified with electrochemically reduced graphene oxide (ERGO) for the simultaneous electrocatalytic detection of dopamine (DA), ascorbic acid (AA), and uric acid (UA). ERGO was formed on a glassy carbon (GC) electrode by the reduction of graphene oxide (GO) using linear sweep voltammetry. The ERGO/GC electrode was formed by subjecting a GO solution ($1mg\;mL^{-1}$ in 0.25 M NaCl) to a linear scan from 0 V to -1.4 V at a scan rate of $20mVs^{-1}$. The ERGO/GC electrode was characterized by Raman spectroscopy, Fourier transform infrared spectroscopy, contact angle measurements, electrochemical impedance spectroscopy, and cyclic voltammetry. The electrochemical performance of the ERGO/GC electrode with respect to the detection of DA, AA, and UA in 0.1 M PBS (pH 7.4) was investigated by differential pulse voltammetry (DPV) and amperometry. The ERGO/GC electrode exhibited three well-separated voltammetric peaks and increased oxidation currents during the DPV measurements, thus allowing for the simultaneous and individual detection of DA, AA, and UA. The detection limits for DA, AA, and UA were found to be 0.46, 77, and $0.31{\mu}M$ respectively, using the amperometric i-t curve technique, with the S/N ratio being 3.

TiO2/GOD 혼합물 기반의 글루코스 바이오 센서의 제작과 표면 처리를 통한 감도개선 (Fabrication and Improved Sensitivity with Surface Treatment of TiO2/GOD Mixture based Glucose Biosensor)

  • 이준엽;정동건;이재용;김재건;정대웅;공성호
    • 센서학회지
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    • 제27권3호
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    • pp.170-174
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    • 2018
  • In this paper, the $TiO_2$/glucose oxidase (GOD) mixture has synthesized through simple and low-cost fabrication methods. The physical properties of the mixture were proved using an FT-IR/NIR spectrometer, an X-Ray diffractometer, and a Raman spectrometer. GOD maintained its bioactivity during all fabrication process. The current characteristics of the glucose biosensor were proportional to the glucose concentration and effective surface area of square pyramid on a silicon substrate. The maximum current change was measured in a pH 7.0 buffer solution. The simple and low-cost fabrication process and surface treatment can be used widely in previous research for improvements in effective surface area.