• Title/Summary/Keyword: pH 저감제

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Synergistic Effects for Remediation of Salt-affected Soil using Dendranthema zawadskii var. latilobum and Soil Amendments under High-concentration Calcium Chloride (고농도 염화칼슘 농도처리에 따른 토양개량제와 구절초의 염분저감 상승효과)

  • Yoon, Yong-Han;Yang, Ji;Park, Je-Min;Ju, Jin-Hee
    • Journal of Environmental Science International
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    • v.30 no.10
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    • pp.803-809
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    • 2021
  • This study aimed to investigate the effects of soil amendment (heat-expanded clay and active carbon) and planting of Dendranthema zawadskii var. latilobum on the remediation of salt-affected soil and the plant growth under high calcium chloride (CaCl2) concentration. The experimental group comprised treatments including Non treatment (Cont.), heat-expanded clay (H), active carbon (AC), planting (P), heat-expanded clay+planting (H+P), active carbon+planting (AC+P). A 200 mL solution of CaCl2 at a concentration of 10 g·L-1 was applied as irrigation once every 2 weeks. Compared to the Cont., the incorporation of the 'heat-expanded clay' amendment decreased electrical conductivity of the soil leachate and cation exchange capacity, whereas the growth of Dendranthema zawadskii var. latilobum was relatively increased. These results suggest that the combination of 'heat-expanded clay' amendment and planting will mitigate negative effect of de-icing salts and improve plant growth in salt-contaminated roadside soils.

Pressure Drop of Integrated Hybrid System and Microbe-population Distribution of Biofilter-media (통합 하이브리드시스템의 압력강하 거동 및 바이오필터 담체의 미생물 population 분포)

  • Lee, Eun Ju;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.116-124
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    • 2022
  • In this study, waste air containing ethanol and hydrogen sulfide, was treated by an integrated hybrid system composed of two alternatively-operating UV/photocatalytic reactor-process and biofilter processes of a biofilter system having two units with an improved design (R reactor) and a conventional biofilter (L reactor). Both a pressure drop (△p) per unit process of the integrated hybrid system and a microbe-population-distribution of each biofilter process were observed. The △p of the UV/photocatalytic reactor process turned out very negligible. The △p of the L reactor was observed to increase continuously to 4.0~5.0 mmH2O (i.e., 5.0~6.25 mmH2O/m). In case of R reactor, its △p showed the one below ca. 16~20% of the △p of the L reactor. Adopting such microbes-carrying biofilter media with high porosity as waste-tire crumb media, and the improved biofilter design, contributed to △p of this study, reduced by ca. 37~50% and 40~53%, respectively, from the reported △p of conventional biofilter packed with biofilter media of the mixture (50:50) of wood chip and wood bark. In addition, the △p of R reactor in this study, reduced by ca. 80% from the reported △p of conventional biofilter packed with biofilter media of the mixture (75:25) of scoria with high porosity and compost, was mainly attributed to adopting the improved biofilter design. On the other hand, in case of L reactor, the CFU counts in its lowest column was analyzed double as much as those in any other columns. However, in case of R reactor, its CFU counts were bigger by 50% than the one of L reactor and its microbes were evenly distributed at its higher and lower columns of Rdn reactor and Rup reactor. This phenomena was attributed to an even moisture distribution of 50~55% of R reactor at its higher and lower columns. Therefore, R reactor showed superb characteristics in terms of both △p and microbe-population-distribution, compared to L reactor.

Effects of High Pressure and Binding Agents on the Quality Characteristics of Restructured Pork (초고압처리 및 결착제 첨가가 재구성 돈육의 품질특성에 미치는 효과)

  • Choi, Ye-Chul;Jung, Kyung-Hun;Chun, Ji-Yeon;Choi, Mi-Jung;Hong, Geun-Pyo
    • Food Science of Animal Resources
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    • v.33 no.5
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    • pp.664-671
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    • 2013
  • The objective of this study was to investigate the effect of high pressure treatment and type of binding agents on the quality characteristics of restructured pork. For binding agents, 2% (w/w) isolated soy protein (SP), 0.5% (w/w) wheat flour (WF) and 0.5% (w/w) ${\kappa}$-carrageenan (KC) were incorporated into meat batter with or without 0.5% (w/w) glucono-${\delta}$-lactone (GdL). The restructured pork was pressurized at varying pressure levels (0.1-450 MPa) for 3 min under ambient temperature and thermal treated at $75^{\circ}C$ for 30 min. As quality parameters of restructured pork, pH, water binding properties, instrumental color and texture profile analysis were determined and compared with control (C, no binder). For type of binders, SP exhibited the best water binding properties, however, the impact on textural properties were lesser than KC and WF. The addition of GdL decreased the pH of restructured pork down to 0.4 unit, while high pressure processing prevented the moisture loss caused from pH decrease by GdL. In particular, meat restructuring efficiency of SP as a binder improved under the presence of GdL. Therefore, the present study demonstrated the potential advantages of low amount of GdL (0.5%, w/w) combined with protein based binder (SP) and high pressure processing in restructuring meat particles.

Effects of Additional Levels of Phyllostachys bambusoides on Ruminal Fermentation Characteristics and Methane Emission in in vitro (왕대의 첨가수준이 반추위 in vitro 발효성상과 메탄 발생량에 미치는 영향)

  • Jo, Seong-Uk;Lee, Shin-Ja;Lee, Ye-Jun;Kim, Hyun-Sang;Eom, Jun-Sik;Choi, You-Young;Bae, Eun-Ji;Lee, Sung-Sill
    • Korean Journal of Organic Agriculture
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    • v.29 no.2
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    • pp.241-256
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    • 2021
  • The current study was to evaluate the antioxidant activity of Phyllostachys bambusoides (PHB) as a feed additives and investigate whether its antioxidant activity could be helpful for increasing rumen fermentation characteristics and methane reduction. The antioxidant activity results showed that total polyphenols and flavonoids contents were 43.54 ± 8.68 mg CE/g and 17.13 ± 0.45 mg QE/g, respectively, and the IC50 values for 1,1-diphenyl-2-prcrylhydrazyl (DPPH) and 2,2'-azino-bis (3- ethylbenzthiazoline-6- sulphonic acid) (ABTS) radical scavenging activity were 163.13 ± 19.25 ㎍/mL and 97.07 ± 4.46 ㎍/mL, respectively. Two heads of cannulated Hanwoo (450 ± 30 kg), consuming timothy hay and a commercial concentrate (60:40, w/w) twice daily (at 09:00 and 17:30) at 2% of body weight, with free access to water and a mineral block, were used as rumen fluid donors. An in vitro incubation experiment was performed after 6, 12, 24, 48, and 72 hr with PHB added at concentration of 2, 4, and 6% of timothy hay basis. Total gas emission decreased as the amount of PHB addition increased at 6 and 24 hr of incubation. However, PHB addition did not affect total volatile fatty acid production, and methane and carbon dioxide emission also decreased as the amount of addition increased at 48 hr of incubation. Therefore, PHB was expected to be used as methane reducing additives in the ruminants.

Magnetite Dissolution by Copper Catalyzed Reductive Decontamination (촉매제로 구리이온을 이용한 환원성 제염에 의한 마그네타이트 용해)

  • Kim, Seonbyeong;Park, Sangyoon;Choi, Wangkyu;Won, Huijun;Park, Jungsun;Seo, Bumkyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.421-429
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    • 2018
  • Hydrazine based reductive dissolution applied on magnetite oxide was investigated. Dissolution of Fe(II) and Fe(III) from magnetite takes place either by protonation, surface complexation, or reduction. Solution containing hydrazine and sulfuric acid provides hydrogen to break bonds between Fe and oxygen by protonation and electrons for the reduction of insoluble Fe(III) to soluble Fe(II) in acidic solution of pH 3. In terms of dissolution rate, numerous transition metal ions were examined and Cu(II) ion was found to be the most effective to speed up the dissolution. During the cycle of Cu(I) ions to Cu(II) ions, the released electron promoted the reduction of Fe(III) and Cu(II) ions returned to Cu(I) ion due to the oxidation of hydrazine. In the experimental results, the addition of a very low amount of cupric ion (about 0.5 mM) to the solution increased the dissolution rate about 40% on average and up to 70% for certain specific conditions. It is confirmed that even though the coordination structure of copper ions with hydrazine is not clear, the $Cu(II)/H^+/N_2H_4$ system is acceptable regarding the dissolution performance as a decontamination reagent.

상수를 염소소독시 생성되는 염소 소독부산물(DBPs)의 생성능에 관한 연구

  • Jeong, Yong;Shin, Dong-Cheon;Lim, Young-Uk;Kim, Jun-Seong;Park, Yeon-Sin
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 1996.12a
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    • pp.75-75
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    • 1996
  • 최근 가장 관심이 집중되고 있는 음용수중의 미량오염물질로는 인위적으로 첨가되는 소독제(disi octant)로 인한 소독부산물(disinfection by-products: DBPs)을 들 수 있다. 1970년대부터 염소소독시 수중의 유기오염물길과 반응하여 발암성물질 과 돌연변이 물질이 다수 함유되어 있는 클로로포름(chloform)을 포함한 트리할로메탄(Trih리omethane: THMs)의 생성이 발견되었으며 이로 인한 건강상의 영향이 지속적으로 보고되고 있다. 염소소독시 780가지 이상의 화합물이 염소와 휴믹산(humic acids)과의 반응에 의해 생성되며, 이중 대부분이 할로겐 화합물로 알려져 있다. 염소 소독부산물로는 인체발암력을 지니고 있는 트리할로메탄(THMs) 이외에도 할로아세틱산(Haloaceticacids: HAAs), 할로아세토나이트릴(Haloacetbnitriles: HANs)등이 주 생성물질인 것으로 알려져 있으나 우러나라의 원수특성에 따른 소독부산물의 생성능 (Formation potential)에 대한 연구가 미흡한 실정이다. 본 연구에서는 우리나라 주요 4대강(한강, 대청호, 영산강, 낙동강)의 원수를 실험실내에서 염소처리하여 생성되는 소독부산물의 생성농과 pH, 체류시간 등의 조건에 따라 생성능을 조사하였다. 각 화합물은 추출 및 농축과정을 거친 후 GC/MSD를 사용하여 물질을 확인한 후 할로겐화합물에 민감한 GC/ECD를 사용하여 시료를 분석하였다. pH와 시간, 원수중의 유기물 함량이 소독부산물의 생성에 많은 영향을 미치는 것으로 나타났다. THMs은 알칼리에서, HAAs의 경우는 약산성에서 접촉시간이 증가할수록 높은 생성능을 보였고, HANs의 경우는 급속히 생성했다가 시간이 경과함에 따라 소멸하며 약산성에서 높은 생성능을 보임을 알 수 있었다, 강별로는 낙동강에서 THMs파 HANs의 생성능이 비교적 높았고, 영산강에서는 HAAs의 생성능이 높았다. 각 원수의 특성에 따른 생성능을 파악함으로써 생성능 저감방안을 마련하며, 소독 부산물질의 인체노출평가에 따른 위해성평가를 통해 관리기준을 설정해야 할 것이다.

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Application of Chemical Dust Suppressants for Control of Fugitive Dust in Ash pond of Thermal Power Plant (화력발전소의 회처리장 내 비산먼지 저감을 위한 화학적 먼지억제제 적용 연구)

  • Choi, Yu-Lim;Choi, Jong-Soo;Yang, Jae-Kyu;Park, Sun-Hwan;Joo, Hyun Soo;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
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    • v.23 no.6
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    • pp.82-89
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    • 2018
  • The objective of this study is to evaluate efficiencies of chemical suppressants for control of fugitive dust in ash pond of thermal power plant. In this study, $MgCl_2$, PAM (polyacrylamide), and PVA (poly vinyl alcohol) that are generally applied to suppression of fugitive dust generated from unpaved road, coal mining, storage piles and etc, were employed as chemical dust suppressants. The coal ash (coal combustion residuals) were sampled from the ash pond of Yeongheung power division in Incheon, South Korea. The characterization of the sample including particle size distribution, pH, $pH_{PZC}$ and pore volume as well as XRF analysis were carried out. The suppressant treated-samples were investigated with the wind tunnel experiments to estimate and compare the effect of suppressants on stabilization of the surface of coal ash samples. According to the results, the stability of suppressant-treated samples were significantly improved compared to water-treated samples. Among the three kinds of suppressants, PAM and PVA showed higher efficiencies and cost saving than $MgCl_2$.

Evaluation of Properties of Artificial Soil Aggregate Based on Ground Granulated Blast-Furnace Slag According to Unit Binder Content (단위결합재량에 따른 고로슬래그 기반 육성용 인공토양골재의 특성평가)

  • Mun, Ju-Hyun;Sim, Jae-Il;Yun, In-Gu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.5
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    • pp.85-92
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    • 2016
  • The eight mixes and artificial soil aggregates were prepared for evaluating the practical application of lightweight foamed concrete as soil aggregates. The main parameter was unit binder content ranged between from 100 to $800kg/m^3$. In lightweight foamed concrete, flow, slurry and dried density, and compressive strength at different ages were measured. In Artificial soil aggregates crushed from lightweight foamed concrete, particle size distribution, pH, coefficient of permeability, cation exchange capacity(CEC), and ratio of carbon to nitrogen(ratio of C/N), were measured. The test results showed that flow, slurry and dried density, and compressive strength at different ages of lightweight foamed concrete increased with the increasing of unit binder content. Compressive strength at age of 28, of lightweight foamed concrete with unit binder of more than $500kg/m^3$, was more than 4 MPa. The ammonium phosphate immersion time of more than age of 3, was effective to decrease pH of artificial soil aggregates. In addition, artificial soil aggregates was evaluated as high class in terms of cation exchange capacity(CEC), while satisfied with value of ratio of carbon to nitrogen(ratio of C/N) recommended by landscape specification.

A Comparative Study between Microbial Fermentation and Non-Fermentation on Biological Activities of Medicinal Plants, with Emphasis on Enteric Methane Reduction (천연 약용식물의 미생물 발효를 통한 장내 메탄 생성 억제 효과 비교 연구)

  • Lee, A-Leum;Park, Hae-Ryoung;Kim, Mi-So;Cho, Sangbuem;Choi, Nag-Jin
    • Korean Journal of Organic Agriculture
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    • v.22 no.4
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    • pp.801-813
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    • 2014
  • A study was conducted to improve the biological activity of two medicinal plants, Eucommia ulmoides Oliv. and Glycyrrhiza uralensis, by fermentation. The biological activity was assessed by determining antibacterial, antioxidant and antimethanogenic properties. Fermentation was achieved by adding the plant materials in MRS broth at 10% (w/v) and different starter cultures at 1% (v/v). Condition for fermentation were incubation temperature of $30^{\circ}C$ and agitation at 150 rpm for 48 h. Six starter cultures, Weissella confusa NJ28 (Genbank accession number KJ914897), Weissella cibaria NJ33 (Genbank accession number KJ914898), Lactobacillus curvatus NJ40 (Genbank accession number KJ914899), Lactobacillus brevis NJ42 (Genbank accession number KJ914900), Lactobacillus plantarum NJ45 (Genbank accession number KJ914901) and Lactobacillus sakei NJ48 (Genbank accession number KJ914902) were used. Antibacterial activity was observed in L. curvatus NJ40 and L. plantarum NJ45 only as opposed to other treatments, including the non-fermented groups, which showed no antibacterial activity. Both plants showed antioxidant activity, although E. ulmoides Oliv. had lower activity than G. uralensis. However, fermentation by all strains significantly improved (p<0.05), antioxidant activity in both plants compared to non-fermented treatment. Six treatments were based on antibacterial activity results, selected for in vitro rumen fermentation; 1) non-fermented E. ulmoides, 2) fermented E. ulmoides NJ40, 3) fermented E. ulmoides NJ45, 4) non-fermented G. uralensis, 5) fermented G. uralensis NJ40, 6) fermented G. uralensis NJ45. A negative control was also added, making a total of 7 treatments for the in vitro experiment. Medicinal plant-based treatments significantly improved (p<0.05) total volatile fatty acid (VFA) concentration. Significant methane reduction per mol of VFA were observed in G. uralensis (p<0.05). Based on the present study, fermentation improves the biological activity of E. ulmoides Oliv. and G. uralensis. Fermented G. uralensis could also be applied as an enteric methane mitigating agent in ruminant animals.

Monitoring of temporal and spatial variation of water quality in agricultural reservoir during summer (여름철 소규모 농업용 저수지의 시공간적 특성 모니터링)

  • Kim, Ui Seok;Byeon, Sang Don;Park, Tae Seon;Nam, Chang Dong;Hong, Eun Mi
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.175-175
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    • 2021
  • 농업용 저수지는 양질의 농업용수를 저장하여 알맞은 시기에 적절하게 급수하기 위한 필수적인 시설로 사용되고 있다. 근래에 농업용수의 용도가 점차 확장되면서 농산물의 품질에 필요한 관개용수의 수질뿐만 아니라 인근 하천과 생태계의 환경유지용량 대한 연구의 필요성이 제시되고 있다. 그러나 규모가 작거나 환경적 보전가치가 없어 조사 대상에서 제외되는 소규모 농업용 저수지는 측정 및 조사자료가 부족한 실정이다. 따라서 본 연구에서는 여름철 소규모 농업용 저수지의 모니터링을 통해 시공간적인 수질특성을 파악하고자 한다. 조사유역은 강원도 횡성군 횡성읍에 위치한 반곡저수지로 선정하였고, 2020년 7월에서 10월까지 8회에 걸쳐 상부와 하부지점에서 총 7개의 수질항목 간의 특성을 분석하였다. 공간적인 특성분포 파악을 위해 총 13지점에서 수질 관측 지점별로 7개의 수질항목에 대해 Spearman 상관분석을 실시하였다. 측정결과, 반곡저수지는 호소 생활환경기준과 OECD 부영양화 기준으로 과영양상태에 도달하였다. 집중적 강우로 인해 희석효과가 발생하여 수질항목 간의 경향성이 저하되어 정확한 분석은 어려웠지만 Chl-a와 T-P, DO와 pH 간의 유의함이 나타났으며, Chl-a와 T-P의 TSIKO 상호편차가 양의 값을 나타내며 다량의 인과 함께 조류가 성장할 수 있는 조건이 형성되고 있었다. 공간적 특성분포는 저수지의 상부지점에서 농도가 높은 경향이 나타났으며 강우 시 인근 농경지와 축산시설에 적치된 축산분뇨의 호 내 유입과 얕은 수심으로 바람에 의한 수직혼합이 영양물질을 용출시켜 부영양화를 악화시키는 것으로 판단된다. 반곡저수지 상부에 녹조제거제 투입 및 저감시설이 필요하며, 향후 지속적인 모니터링을 통해 소규모 농업용 저수지 수질 연구를 위한 기초자료로 활용할 수 있을 것으로 사료된다.

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