• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.10
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• pp.1442-1449
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• 2003

We investigated the amount of the toxic gases emitted from the Electrostatic Precipitators(ESPs), which are currently used as the indoor air cleaners. The existing wire-to-plate(WTP) and neddle-to-plate(NTP) types of ESP designs are considered as the experimental corona dischargers. Using the voltage, the polarity of wire, the number of needles of NTP as the input variables, we studied the generation characteristics of ozone and $NO_{x}$ and the particle removal efficiency in the ESPs. As the results, we found out that the concentration of ozone, $NO_{2}$ and $NO_{x}$ is increased with increasing the voltage and the number of needles, but the amount of NO is decreased. And we observed that the generation rates of ozone and $NO_{x}$ are mainly related with the corona region through the photographs. Finally the experimental results showed that the particle removal efficiency of ESP with WTP type charger is more superior to that with NTP type chargers at the same voltage.

• Journal of Soil and Groundwater Environment
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• v.6 no.1
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• pp.3-12
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• 2001

During ozonation process, the hydroxyl radical generation rates were measured under different experimental conditions (ozone feed rate, nitrobenzene concentration, hydroxyl radical scavenger, pH, HO$_2$O$_2$/O$_3$ etc.) Nitrobenzene could be decomposed by hydroxyl radical rather than ozone only and nitrobenzene decomposition rate was expressed with functions of ozone and nitrobenzene concentration. The rate was decreased as the hydroxyl radical scavenger concentration was increased, and all results were followed pseudo first-order reaction. Using a competitive method, hydroxyl radical generation rate was measured with probe compound and scavenger. It was proportional to ozone concentration, and 0.24mo1 of hydroxyl radical was produced with 1mol of ozone. Under different pH conditions, hydroxyl radical generation rates were measured (pH 10.2 (0.91Ms$^{-1}$ ) > pH 7.3 (0.72Ms$^{-1}$ ) > pH 5.6 (0.67Ms$^{-1}$ ) > pH 3.4 (0.63Ms$^{-1}$ )) showing higher generation rate at high pH values. Addition of hydrogen peroxide promoted the generation rate of hydroxyl radical. Considering the results of pH experiments and addition of hydrogen peroxide experiments, the hydroxyl radical generation rate was 1.6 times higher in hydrogen peroxide solution than in high pH solution, indicating addition of hydrogen peroxide is better promoter to produce the hydroxyl radical in ozonation. These results could be applied to AOPs to remediate the contaminated wastewater and groundwater.

• Journal of the Korean Electrochemical Society
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• v.11 no.3
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• pp.135-140
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• 2008

An electrochemical generation of ozonized water was investigated by using ${\beta}-PbO_2$ as an anode and tap water as an anolyte. According to the potentiometric ozone detection which utilizes potential differences arisen from a chemical reaction of ozone and iodide, increasing tendency of ozone concentration on electrolysis time could be observed to show the maximum value of 8 ppm at an electrolysis time of 10 min. Ozone could be generated promptly even at an electrolysis time of 10 sec., suggesting great advantages of this electrochemical process in terms of simplicity and readiness that might be applied directly to practical uses including medical and/ or food industries. Influences of electrolysis on the properties and surface conditions of a $PbO_2$ electrode were also discussed from the results of cyclic voltammetry, scanning electron microscope, and X-ray diffractometer.

• Proceedings of the KIEE Conference
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• 1999.11d
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• pp.1063-1065
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• 1999

Recently the ozone generation system is well used for cleaning the contaminated water by using the strong oxidization effects. Accordingly, with the purpose of improving ozone yield at the peak of ozone concentration, this paper describes the stracture and characteristics of ozonizer, and focused on the development of a 3E-3G discharge tube.

• Journal of Environmental Science International
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• v.4 no.1
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• pp.63-70
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• 1995

Continuous measurements of ground-level ozone (O3) were made in five minutes intervals in the rural area of Korea from July 1993 to June 1994. This site is located in Chongwon, near latitude 36.4$^{\circ}$N, longitude 127.6$^{\circ}$E. The results show that the one-year mean value was 17 ppb, and monthly mean ranged from 6 to 47 ppb. A pronounced maximum in summer and a minimum in winter were found, and these were related to anthropogenic emission and photochemical reaction. Diurnal variations of ozone minimum at 07:00 - 08:00. During the period when ozone concentration was very high (> 80 ppb), the stable winds were from N and UW; on the other hand, when ozone concentration was very low, air movement in the large scale was from the North Pacific Ocean. This suggests that in the rural area the long range transport of anthropogenic pollutants from distant sources can contribute to the larger contribution than the generation of ozone from local sources in the rural area.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2007.05a
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• pp.346-349
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• 2007

In this paper, the ozonizer is equipped with three electrodes ( two external electrodes, central electrode ), and AC high voltage which has 180[$180^{circ}C$] phase difference is applied to two H V. Ozone discharge and generation charactristics have been investigated in accordance with output voltage of power supply, flow-rate, discharge power. Ozone concentration, generation and yield were proportionally increased with increasing discharge area size.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1835-1837
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• 1996

Characteristics of Discharge and nonthermal plasma generation in a micro-air gap spacing between a micro-dielectric barrier and a electrode have been investigated experimentally to chert the potential to be used as a micro-scale nonthermal plasma generator. It is found that the output ozone concentration, as a nonthermal plasma intensity parameter, of the micro-air gnp nonthermal plasma generator depended greatly upon the air gap spacing and thickness of the dielectric barrier. As a result, there is a optimal air gap sparing in the same micro dielectric barrier to generate ozone effectively. And the higher ozone concentration was generated from the thinner micro-barrier.

• Advances in environmental research
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• v.4 no.3
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• pp.155-172
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• 2015

In this study, a complete set of recirculating cooling water system and the required instruments were built in a semi-industrial-scale and a 50 g/h ozone generation plant and a chlorine system were designed for cooling water treatment. Both chlorination and ozonation treatment methods were studied and the results were analyzed during two 45-days periods. The concentrations of ozone and chlorine in recirculating water were constant at 0.1 mg/lit and 0.6 mg/lit, respectively. In ozone treatment, by increasing the concentration cycle to 33%, the total water consumption decreased by 26% while 11.5% higher energy efficiency achieved thanks to a better elimination of bio-films. In case of Carbon Steel, the corrosion rate reached to 0.012 mm/yr and 0.025 mm/yr for the ozonation and chlorination processes, respectively. Furthermore, consumptions of the anti-corrosion and anti-sedimentation materials in the ozone cooling water treatment were reduced about 60% without using any oxidant and non-oxidant biocides. No significant changes in sediment load were seen in ozonation compared to chlorination. The Chemical Oxygen Demand of the blow-down in ozonation method decreased to one-sixth of that in the chlorination method. Moreover, the soluble iron and water turbidity in the ozonation method were reduced by 97.5% and 70%, respectively. Although no anaerobic bacteria were seen in the cooling water at the proper concentration range of ozone and chlorine, the aerobic bacteria in chlorine and ozone treatment methods were 900 and 200 CFU/ml, respectively. The results showed that the payback time for the ozone treatment is about 2.6 years.

• Applied Chemistry for Engineering
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• v.22 no.3
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• pp.249-254
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• 2011

A nonthermal plasma reactor in conjunction with a tubular type with a ferroelectric (high-dielectric ceramic) pellet layer was designed and constructed. $SrBiTaO_9$ (SBT) pellets with 2.0 mm in diameter were held within the tube arrangement by two metal mesh electrodes (20 mm separation) connected to a high-voltage AC power supply. The dielectric constant of SBT pellets was 150 at room temperature and 500 at curie temperature ($335^{\circ}C$). The generation rate of ozone in the plasma reactor almost linearly increased with increasing applied voltage. In the case of the plasma reactor packed with SBT pellets the generation rate of ozone sharply increased at the applied voltage more than 20 kV. The ozone generation rate at the negative corona discharge was higher than that of the positive corona discharge. However, the destruction efficiency of toluene and methylene chloride was not increased in proportion to ozone concentration.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.22 no.12
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• pp.176-182
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• 2008

It is the paper that this study develops the small plate-type ozonizer(PTO) for improvements of indoor air and water, and investigated the characteristics. Electric discharge area of ozonizer of each form is same to 60[$cm^2$] and discharge power is the maximum 30[W]. Ozonizer of various forms was devised according to size, numbers and arrangement. The main study object is discharge power-ozone concentration characteristics, discharge power-ozone yield characteristics, amount of gas flow-ozone concentration characteristics and amount of gas flow-ozone yield characteristics. PTOL-P appeared so as to be most excellent, and ozone generation characteristics were able to get the similar results at three kinds of remaining ozonizer ($PTO_{P-P}$, $PTO_{C-P}$, $PTO_{T-P}$).