• 제목/요약/키워드: oxidizing acid

검색결과 145건 처리시간 0.019초

Scanning Electron Microscopic Study of Slime Formations in a Water Injection Station of Oil India Limited in Assam, India

  • Bhagobaty, Ranjan K.;Purohit, S.;Nihalani, M.C.
    • Applied Microscopy
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    • 제45권4호
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    • pp.249-253
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    • 2015
  • Microorganisms specifically groups of bacteria exhibiting physiological activities of production of acids are a major cause of concern because of their ability to induce corrosion in oil field pipelines and metal systems involved in water handling. Water Injection Stations as a means of secondary recovery from existing oil producing reservoirs, are often employed in most upstream oil and gas industries to ensure replenishment of voidage, maintenance of reservoir pressure and optimization of crude emulsion throughput. In the present study, scanning electron microscopy of macroscopic orange coloured slime formations sampled from leaking valves on the flow-lines of a Water Injection Stations of Oil India Limited revealed the presence of filamentous bacterial mats in association with diatoms. The species composition of the acidic slime formations from the sampled locations reveal the possible role of acid producing iron oxidizing bacteria (IOB) like Acidithiobacillus ferrooxidans in association with Gomphonema sp. in creating conditions for bio-corrosion.

전처리 공정에 따른 폐 신문지의 효소 가수분해 특성

  • 문남규;이재환;김성배
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 춘계학술발표대회
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    • pp.459-462
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    • 2000
  • The pretreatment of used newspaper for the enzymatic digestion preprocess was performed on a percolation reactor and a batch reactor. The test condition of percolation process was $170^{circ}C$, 60min, 1 mL/min, and 400psi, that of batch was $40^{circ}C$, 3hr. and latm Reaction solutions used in pretreatment process were aqueous ammonia, sulfuric acid, water, and hydrogen-peroxide as an oxidizing agent. As a result, the effect of pretreatment was similar to batch and percolation process, but the yield of enzymatic hydrolysis was higher in batch than percolation. This batch pretreatment enhanced enzymatic hydrolysis rate and increased glucose yield from about 15 to 20%. The inhibition factors influenced the rate of enzymatic hydrolysis was investigated, and the ink contented newspaper was the major factor.

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저품위 동광석의 세균침출에 관한 연구 4 (A Study on Bacterial Leaching of Low-Grade Copper Mineral(IV))

  • 박원구;이강순
    • 미생물학회지
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    • 제11권4호
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    • pp.189-195
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    • 1973
  • With the gradual expansion of copper demands, the utilization of enormous tonnages of waste copper mineral containig up to 0.5% copper becomes available. In order to investigate the possibilities on the application of bacterial leaching method to waste dumps or abandoned mines, the authors had carried out microbial leaching of copper minerals by F.ferrooxidans isolated from the Dalsung copper mine water. The results obtained were as follows : 1. The copper extraction rate from the Dalsung chalcopyrite has been a little accerelated by using flasks in place of percolators. 2. The percentage of copper extracted from the Dalsung chalcopyrite sample was 100% in 30 days in the presence of iron-oxidizing bacteria F.ferrooxidans while 9.27% in the absence of bacteria. 3. F.ferroxidans was capable of producing sufficient quantities of ferric sulfate and sulfuric acid from ferrous iron to bring about the dissolution of 100% of copper from the Dalsung chalcopyrite.

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Fouling and cleaning of a tubular ultrafiltration ceramic membrane

  • Siddiqui, Farrukh Arsalan;Field, Robert W.
    • Membrane and Water Treatment
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    • 제7권5호
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    • pp.433-449
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    • 2016
  • The successful application of cleaning protocols is vital for optimized filtration processes. A series of experiments with an ultrafiltration ceramic tubular membrane were carried out for the foulants dextran and carboxymethyl cellulose. Firstly, the impact on fouling of concentration changes was investigated with the increase in resistance being used as the key parameter. In the second phase, removal of reversible fouling was also investigated by employing intermittent rinsing consisting of a cold water rinse followed by a hot one. A comparative analysis for both foulants is reported. Across a range of concentrations and for both foulants, the reduction in resistance due to rinsing was found to depend upon concentration (C); it changed as $C^n$ where n was found to be 0.3. A plausible semi-theoretical explanation is given. Thirdly, for both foulants, the application of a combination of strong alkaline solutions with oxidizing agent (mainly sodium hypochlorite) followed by acid was found to be appropriate for cleaning of the ceramic membrane. The effect of increased temperature for cleaning agents followed by a warm water rinse contributed positively to the cleaning capability.

폴리머 시멘트 모르타르를 이용한 철근콘크리트 흄관 라이닝에 관한 연구 (A Study on the Lining of Reinforced Concrete Pipe Using Polymer-Modified Mortar)

  • 김영집;김한엽;조영구;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 봄 학술발표회 논문집
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    • pp.333-338
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    • 2000
  • At present, reinforced concrete pipe has been widely used as drain pipe. However, many reinforced concrete pipe is exposed at deteriorated environment by the growth of a sulfur-oxidizing bacterium isolated from corroded concrete. The purpose of this study is to evaluate the effects of lining by polymer-modified mortar on the development in durability of reinforced concrete pipe. Polymer-modified mortars ate prepared with various polymer typer as cement modifier and polymer-cement ratio and rested for compressive and flexural strengths, adhesion in tension, acid resistance test, freezing and thawing test, and lining test of product in the field. From the rest results, it is apparent that polymer-modified mortars have good mechanical properties and durability as lining material. In practice, all polymers can be used as lining materials for reinforced concrete pip, and type of polymer, and polymer-cement ratio and curing conditions are controlled for good lining product.

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셀룰로오스 단열재의 연기발생에 관한 연구 (Studies of the Smoke Emission from Cellulose Fiber Insulation)

  • 김홍;강영구
    • 한국안전학회지
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    • 제9권2호
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    • pp.12-17
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    • 1994
  • Smoke evolved from burning cellulose insulation treated with boric acid-borax-alum as combustion retardants has been studied using a light absorption method. It has been shown that the quantity of smoke are decreased with the increase of oxygen concentration. Applied fire retardants did not increase smoke generation from investigated cellulose insulation in range of themal degradation without flaming. These same fire retardants increased from in the range of flaming combustion. The results of this work have been analysed using imperical equation, which correlated the smoke density at oxygen content of combustion transition. This equation may be. $\sigma$=$\sigma$$_{T}$ exp{-7.24$\times$10$^{-7}$ ( $O_2$ $O_{2.T}$)}Where $O_2$is the concentration of oxygen in the oxidizing gas, and $O_{2.T}$ refers to oxygen concentration of combustion transition.n.n.n.

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Fabrication and Evaluation of a New High-Temperature pH Sensor for Use in PWR Nuclear Power Plants

  • Jung, Yong-Ju;Yeon, Jei-Won
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2939-2942
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    • 2010
  • A new high-temperature pH sensor has been successfully developed by reforming the internal reference systems of the pH sensors based on oxygen-ion conducting ceramic membrane. The conventional internal reference system, a mixture of Ni and NiO, has been replaced with partially oxidized Ni powders, where Ni and NiO coexist on the surface of particles, in order to avoid the cumbersome mixing step of Ni and NiO particles. The partially oxidized Ni particles were made by oxidizing Ni under air atmosphere at $600^{\circ}C$ and characterized by X-ray diffraction (XRD) and FTIR spectroscopy. The viability of the pH sensor developed was assessed in boric acid (1000 ppm-B)/ lithium hydroxide (1 to 3 ppm-Li) buffer solutions at $280^{\circ}C$. The pH sensor showed excellent accuracy with a small error less than ${\pm}0.2$ pH units.

Embargo Nature of CuO-PANI Composite Against Corrosion of Mild Steel in Low pH Medium

  • Selvaraj, P. Kamatchi;Sivakumar, S.;Selvaraj, S.
    • Journal of Electrochemical Science and Technology
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    • 제10권2호
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    • pp.139-147
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    • 2019
  • Incorporation of CuO nanoparticles during the polymerization of aniline in the presence of ammonium peroxydisulphate as an oxidizing agent and sodium salt of dodecylbenzene sulphonic acid as dopant as well as surfactant yielded water soluble CuO-PANI composite. Comparison of recorded spectra like FTIR, XRD and SEM with reported one confirm the formation of the composite. Analysis by gravimetric method exposes that the synthesized composite is having resistivity against corrosion, with slight variation in efficiency on extending the time duration up to eight hours in strong acidic condition. OCP measurement, potentiodynamic polarization and EIS studies also confirms the suppression ability of composite against corrosion. Riskless working environment could be provided by the synthesized composite during industrial cleaning process.

산화 그래핀 나노플레이트릿을 혼입한 에폭시 도료의 역학적 특성 (Mechanical Properties of Epoxy Paints Containing Oxidized Graphene Nanoplatelet)

  • 서원우;김규용;윤민호;황의철;백재욱;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.153-154
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    • 2017
  • Graphene is a nanomaterial and is known to have very high mechanical strength, thermal and electrical properties. However, graphene is known to be difficult to disperse among carbon-based materials due to van der Waals force. In this study, to solve the dispersion problem of graphene nanoplatelet, oxidized graphene nanoplatelet was prepared by oxidizing GNP in nitric acid. The prepared GO was dispersed in ethanol and distilled water before incorporation into the epoxy paint to confirm dispersibility. In addition, GNP/Epoxy and GO/Epoxy tensile specimens were prepared by mixing GNP and GO at 0.1, 0.3, 0.5 and 1.0 wt.% In epoxy coatings and tensile stress-strain characteristics were investigated.

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양극슬라임으로부터 무기침출제에 의한 금과 은의 침출 (Leaching of Gold and Silver from Anode Slime with Inorganic Reagents)

  • 행위동;이기웅;이만승
    • 자원리싸이클링
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    • 제26권1호
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    • pp.30-36
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    • 2017
  • 양극흙에 함유된 금과 은을 회수하기 위해 무기산(염산, 질산, 황산)과 thiourea 및 thiosulfate에 의한 침출실험을 수행했다. 산화제를 첨가하지 않은 조건에서 금은 무기산용액에 전혀 용해되지 않았다. 3종류의 무기산의 농도가 동일한 조건에서 황산용액에서 은의 침출율이 가장 높았으며, 염산의 농도가 증가함에 따라 $AgCl_2{^-}$의 형성에 따라 은의 침출율이 증가하였다. 한편 주석은 질산용액에 전혀 용해되지 않았으나, 구리, 니켈과 아연은 본 실험조건에서 모두 용해되었다. 황산과 thiourea의 혼합용액에서 금과 은은 모두 용해되었다. Thiosulfate용액에 은의 일부가 용해되었으나, 금은 전혀 용해되지 않았다.