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http://dx.doi.org/10.5229/JECST.2019.10.2.139

Embargo Nature of CuO-PANI Composite Against Corrosion of Mild Steel in Low pH Medium  

Selvaraj, P. Kamatchi (P.G and Research Dept. of Chemistry, Govt. Arts College for Men (Aut))
Sivakumar, S. (Manonmaniam Sundarnar University)
Selvaraj, S. (P.G and Research Dept. of Chemistry, Govt. Arts College for Men (Aut))
Publication Information
Journal of Electrochemical Science and Technology / v.10, no.2, 2019 , pp. 139-147 More about this Journal
Abstract
Incorporation of CuO nanoparticles during the polymerization of aniline in the presence of ammonium peroxydisulphate as an oxidizing agent and sodium salt of dodecylbenzene sulphonic acid as dopant as well as surfactant yielded water soluble CuO-PANI composite. Comparison of recorded spectra like FTIR, XRD and SEM with reported one confirm the formation of the composite. Analysis by gravimetric method exposes that the synthesized composite is having resistivity against corrosion, with slight variation in efficiency on extending the time duration up to eight hours in strong acidic condition. OCP measurement, potentiodynamic polarization and EIS studies also confirms the suppression ability of composite against corrosion. Riskless working environment could be provided by the synthesized composite during industrial cleaning process.
Keywords
CuO-PANI; Mild steel; OCP; Potentiodynamic polarization; EIS;
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