• 제목/요약/키워드: oxide reduction

검색결과 1,344건 처리시간 0.026초

Capacitance-voltage Characteristics of MOS Capacitors with Ge Nanocrystals Embedded in HfO2 Gate Material

  • Park, Byoung-Jun;Lee, Hye-Ryeong;Cho, Kyoung-Ah;Kim, Sang-Sig
    • 한국전기전자재료학회논문지
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    • 제21권8호
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    • pp.699-705
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    • 2008
  • Capacitance versus voltage (C-V) characteristics of Ge-nanocrystal (NC)-embedded metal-oxide-semiconductor (MOS) capacitors with $HfO_2$ gate material were investigated in this work. The current versus voltage (I-V) curves obtained from Ge-NC-embedded MOS capacitors fabricated with the $NH_3$ annealed $HfO_2$ gate material reveal the reduction of leakage current, compared with those of MOS capacitors fabricated with the $O_2$ annealed $HfO_2$ gate material. The C-V curves of the Ge-NC-embedded MOS capacitor with $HfO_2$ gate material annealed in $NH_3$ ambient exhibit counterclockwise hysteresis loop of about 3.45 V memory window when bias voltage was varied from -10 to + 10 V. The observed hysteresis loop indicates the presence of charge storages in the Ge NCs caused by the Fowler-Nordheim (F-N) tunneling. In addition, capacitance versus time characteristics of Ge-NC-embedded MOS capacitors with $HfO_2$ gate material were analyzed to investigate their retention property.

플레티늄-실리사이드를 이용한 쇼트키 장벽 다결정 박막 트랜지스터트랜지스터 (Schottky barrier polycrystalline silicon thin film transistor by using platinum-silicided source and drain)

  • 신진욱;최철종;정홍배;정종완;조원주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.80-81
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    • 2008
  • Schottky barrier thin film transistors (SB-TFT) on polycrystalline silicon(poly-Si) are fabricated by platinum silicided source/drain for p-type SB-TFT. High quality poly-Si film were obtained by crystallizing the amorphous Si film with excimer laser annealing (ELA) or solid phase crystallization (SPC) method. The fabricated poly-Si SB-TFTs showed low leakage current level and a large on/off current ratio larger than $10^5$. Significant improvement of electrical characteristics were obtained by the additional forming gas annealing in 2% $H_2/N_2$ ambient, which is attributed to the termination of dangling bond at the poly-Si grain boundaries as well as the reduction of interface trap states at gate oxide/poly-Si channel.

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Growld Plane SOI MOSFET의 단채널 현상 개선 (Reduction of short channel Effects in Ground Plane SOI MOSFET′s)

  • 장성준;윤세레나;유종근;박종태
    • 대한전자공학회논문지SD
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    • 제41권4호
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    • pp.9-14
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    • 2004
  • 매몰 산화층 밑의 실리콘 기판에 자기정렬 방법으로 ground plane 전극을 만든 SOI MOSFET의 단채널 현상과 Punchthrough 특성을 측정·분석하였다. 채널 길이가 $0.2{\mu}m$ 이하의 소자에서는 GP-SOI 소자가 FD-SOI 소자보다 채널 길이에 따른 문턱전압 저하 및 subthreshold swing이 작고 DIBL 현상이 크게 개선됨을 알 수 있었다. 기판전압에 따른 문턱전압 특성으로부터 GP-SOI 소자의 body factor가 FD-SOI 소자보다 큰 것을 알 수 있었다. 그리고 punchthrough 전압 특성으로부터 GP-SOI 소자의 punchthrough 전압이 FD-SOI 소자보다 큰 것을 알 수 있었다.

자발 '청간탕'이 HepG2 cell의 염증반응에 대한 연구 (Effect of Zibachunggan-tang on lipopolysaccharide-induced expression of NF-kB downstream genes in HepG2 cell)

  • 홍상훈;최병태;이용태
    • 동의생리병리학회지
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    • 제17권5호
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    • pp.1251-1256
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    • 2003
  • To determine the effect of Zibachunggan-tang(ZCT) on the process of lipopolysaccharide (LPS)-induced nuclear factor-kBp65 (NF-kBp65) activation, and LPS-induced expression of pro-inflammatory proteins including tumor necrosis factor-α (TNF-α), nitric oxide synthase (iNOS) and cyclooxygenase-2 (COX-2), in HepG2 cell. Immunoblot analysis showed that the level of nucleic NF-kBp65 was rapidly up-regulated and cytosolic inhibitory I-kBα was down-regulated by LPS challenge. While ZCT inhibited an increase of NF-kBp65 and degradation of I-kBα in HepG2 cell. Beside LPS-induced expression of a group of genes, such as TNF-α, inducible iNOS and COX-2, are repressed by ZCT. It may be concluded that ZCT attenuates the progress of LPS-induced inflammation by reduction of NF-kBp65 activation. The ZCT would be useful as a therapeutic agent for endotoxin-induced liver disease.

In vivo ESR measurement of free radical reaction in living mice

  • Han, Jin-Yi;Hideo Utsumi
    • 한국응용약물학회:학술대회논문집
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    • 한국응용약물학회 2000년도 춘계학술대회
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    • pp.6-7
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    • 2000
  • Recently, free radicals such as active oxygen species, nitric oxide, etc are believed to be one of the key substances in physiological and pathological, toxicological phenomena, and oxidative damages, and all organism have defencing system against such as free radicals. Formation and extinction of free radicals may be regulated through bio-redox system, in which various enzymes and compounds should be involved in very complicated manner. Thus, direct and non-invasive measurement of in vivo free radical reactions with living animals must be essential to understand the role of free radicals in pathophysiological phenomena. Electron spin resonance spectroscopy (ESR) is very selective and sensitive technique to detect free radicals, but a conventional ESR spectrometer has large detect in application to living animals, since high frequent microwave is absorbed with water, resulting in generation of high fever in living body. In order to estimate in vivo free radical reactions in living whole animals, we develop in vivo ESR-CT technique using nitroxide radicals as spin probes. Nitroxide radicals and their reduced forms, hydroxylamines, are known to interact with various redox systems. We found that! ! the signal decay due to reduction of nitroxyl radicals is influenced by aging, inspired oxygen concentration, ischemia-referfusion injury, radiation, etc. In the present paper, I will introduce in vivo ESR technique and my laboratory recent results concerning non-invasive evaluation of free radical reactions in living mice.

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자기 환원성 TiO2 단광의 반응특성에 관한 연구 (Study on the Reaction Behavior of Self-reducing TiO2 Briquette)

  • 백상종;신동엽;민주원;최석우;윤덕재;유병돈
    • 소성∙가공
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    • 제15권8호
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    • pp.615-620
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    • 2006
  • The reduction behavior of $TiO_{2}$ in Al and Al/CaSi containing self-reducing $TiO_{2}$ briquettes(SRTB) was investigated. The maximum yield of Ti was expected with the slag composition of 45-55%CaO in the $CaO-Al_{2}O_{3}$ system. When $CaCO_{3}$ was used as a flux, the oxidation loss of reducing agent by $CO_{2}$ should be compensated, and therefore it leads to excessive requirement of the reducing agent. By using Al and CaSi mixture as a reducing agent of $TiO_{2}$, the reaction products both oxide and metal could be liquefied, and separated effectively with each other. As a result, the yield of Ti increases remarkably. The optimum mixing ratio of CaSi to Al is 78%CaSi-22%Al.

메밀이 흰주 SOD 활성도와 장기에 미치는 영향 (Effects of Buckwheat on Super Oxide Dismutase Activity and Histopathological Change of Rats Fed with Hypercholesterolemic Diet)

  • 김영순;임국환;서형주;정수현;장동덕;조정순
    • 한국식품위생안전성학회지
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    • 제13권1호
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    • pp.68-75
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    • 1998
  • 흰주의 체중은 실험기간동안 증가하였으며, 식이 별로는 대조군이 가장 높은 체중 증가를 보였다. 콜레스테롤의 첨가는 흰쥐의 정상적인 성장을 억제하였으며, 콜레스테롤 첨가군에서는 콜레스테롤 대조군의 체중증가량이 유의하게 가장 낮았다. Rutin과 메밀 채소를 식이에 첨가하였을 때 흰쥐의 콜레스테롤에 의한 성장억제 작용을 효과적으로 감소시키는 것으로 나타났으며, 첨가량의 증가에 따라 혈청의 총 콜레스테롤 함량과 과산화지질 함량은 낮아지는 반면에 HDL-cholesterol 함량은 높아지는 경향을 보였다.

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고체산화물 연료전지용 (La,Sr)$MnO_3$-YSZ 복합체 양극의 산소환원 반응기구 및 전극 특성 (Part II: 전극 특성) (Oxygen Reduction Mechanism and Electrode Properties of (La,Sr)$MnO_3$-YSZ Composite Cathode for Solid Oxide Fuel Cell (Part II: Electrode Properties))

  • 김재동;김구대;이기태
    • 한국세라믹학회지
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    • 제38권1호
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    • pp.93-99
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    • 2001
  • (La,Sr)MnO$_3$(LSM)-YSZ 복합체 양극에 있어서 소결온도 및 전극두께와 cathodic potential이 전극 특성에 미치는 영향을 고찰하였다. 양극의 소결은 삼상계면의 양을 결정하는 중요한 변수로 LSM 단미 양극과 YSZ가 40 wt% 포함된 LSM-YSZ 복합체 양극 모두 120$0^{\circ}C$에 소결했을 때 가장 낮은 분극저항을 나타내었다. 또한 양극 후막의 두께가 얇아지면 양극의 in-plane 저항이 증가하여 ohmic 저항이 증가하였는데, LSM-YSZ 복합체 양극의 경우 약 30$mu extrm{m}$ 정도의 전극두께가 가장 효과적인 전극 특성을 나타내었다. 한편, LSM-YSZ 복합체 양극에 -0.5 V의 cathodic potential을 인가함에 따라 양극에서 일어나는 산소환원반응의 활성이 증가하였는데, 1가 산소이온의 표면확산반응의 분극저항은 감소하였으나, 고주파수 영역에서 나타나는 산소이온전달반응의 저항은 거의 변화하지 않았다. 이것은 Mn의 환원에 의한 양극표면에 생성된 산소공공에 기인한다.

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졸겔법으로 합성된 Mal2O4:Eu2+(M=Sr,Ba,Ca)의 특성 (Characterization of MAl2O4:Eu2+(M=Sr,Ba,Ca) Synthesised by Sol-gel Method)

  • 임규;김용현;이형직;김세기;이형복
    • 한국세라믹학회지
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    • 제46권6호
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    • pp.679-684
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    • 2009
  • Phosphors of $Eu^{2+}$ doped alkaline earth aluminates MA$l_2O_4:Eu^{2+}$ (M=Sr, Ba, Ca) have been prepared by sol-gel process and their characterization of photoluminescence and photocurrent properties have been performed. The phosphors prepared by sol-gel process, due to its advantage of better homogeneity and low synthetic temperature, was synthesized as single phases at lower temperature than the solid-state process; $800{\sim}1000{^{\circ}C}$ for 6 h under mild reduction atmosphere (Ar- 3% $H_2$). It was confirmed that SrA$l_2O_4:Eu^{2+}$ composition revealed the most excellent properties in the brightness and photocurrent.

산화티타늄이 청자유약의 발색에 끼치는 영향에 관한 연구 (Effect of TiO2 on the Color Generation in Celadon Glaze)

  • 노형구;김응수;김종영;조우석;김철성;김진모
    • 한국세라믹학회지
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    • 제51권3호
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    • pp.150-155
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    • 2014
  • In aprevious study, the mutual interaction between $Fe_2O_3$ and $TiO_2$ was found to influence the color of celadon glaze. Celadon samples were prepared with varying concentrations of $TiO_2$ at a fixed level of $Fe_2O_3$. The electronic states of Fe and Ti were analyzed by M$\ddot{o}$ssbauer spectroscopy and electron spin-resonance spectroscopy, respectively. These results were examined with the celadon colors measured according to CIELAB values. This study revealed that an increase of $Ti^{3+}$ in the glassy phase decreased the $Fe^{2+}/Fe^{3+}$ ratio, resulting in a color change of the celadon samples in the GY and Y groups. The maximum reflectance wavelength was shifted from 505 nm to 610 nm with an increase in the $TiO_2$ concentration.