• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.871-873
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• 2009

We report on the growth of rubrene ($C_{42}H_{28}$) wire fabricated by thermal evaporation, followed by solvent-vapor annealing for the application of organic thin film transistor. Solvent-vapor annealing was carried out in precisely controlled vapor pressure at elevated temperature. Micro-sized, and elongated rubrene wire was obtained via solvent annealing process reproducibly. Optical image and XRD data shows highly crystalline quality of rubrene wire.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.192.2-192.2
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• 2013

Crystalline order and surface stability of 1,4,5,8,9,11-hexaazatriphenylene-hexanitrile (HATCN) thin films on organic surface were investigated using grazing incidence wide angle x-ray scattering and x-ray reflectivity measurements. In the initial growth regime (less than 20 nm), HATCN molecules were stacked to low crystalline order with substantial amorphous phase. Meanwhile, a thicker film with 50 nm thickness showed high crystalline order of hexagonal phase with three different orientational domains. The domain distribution was quantitatively obtained as a function of tilted angle. By an organic-inorganic interface formation of IZO/HATCN thin film from an indium zinc oxide (IZO) electrode deposition, the surface stability of HATCN film was investigated and the sharp interface was confirmed by the x-ray reflectivity measurement.

• Journal of the Korean institute of surface engineering
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• v.33 no.5
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• pp.339-348
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• 2000

The study was conducted on the effect of bath composition on the surface appearance, the hardness and the crystal orientation of zinc electrodeposits from the chloride bath. (1) The hardness of the zinc electrodeposits from the chloride bath was increased by suppressing mass transfer of zinc through adding the organic additives and the chlorine ion in the electrolyte. (2) The surface whiteness of zinc deposits was decreased due to the change of the preferred orientation from (002) , (103) to (101) , (100) through increasing the organic additives and chlorine ion in the electrolyte. (3) The addition of Cu, Sn, Ni or Co in the chloride bath elevated the hardness of the zinc deposits but darkened the surface whiteness. (4) The optimum condition of the organic additives and the chlorine ion for increasing the hardness of zinc deposits and preventing dark surface ranges 0.3 m1/1 to 0.4 m1/1 and 6.5 mol/1 to 6.8mol/l respectively.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.2 no.1
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• pp.69-78
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• 1998

Contents of heavy metals (Cr, Cu, Zn, Cd, and Pb) in the sediments of Ulsan Bay were investigated by the sequential extraction methods that classifies heavy metals into five types of chemical forms: exchangeable, bound to carbonates, bound to Fe-Mn oxides, bound to organic matter and residual. The analytes were determined by using an ICP-MS. Total Cr concentrations in the sediments were in the range of 41.6-96.4, Cu 60.7-680, Zn 189-1954, Cd 33.1-83.4, and Pb 138-567 mg/kg. Results of sequential fractionation indicates that relatively high proportion $(\~44\%)$ of Cu is associated with organic matter A large proportion of Pb is associated with three types of chemical forms: Fe-Mn oxides, organic matter, and residual. There were significant correlation in concentrations between the exchangeable components and total organic carbons. The heavy metals in the residual phase cannot be easily released to the environment since these are bound to the crystal lattice. But, reducible and organic Phases cfn a significant amount of most heavy metals. Therefore. there is potential danger of a substantial amount of metals becoming chemically mobile with environmental changes.

• Journal of Environmental Science International
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• v.2 no.1
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• pp.69-78
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• 1993

Contents of heavy metals (Cr, Cu, Zn, Cd, and Pb) in the sediments of Ulsan Bay were investigated by the sequential extraction methods that classifies heavy metals into five types of chemical forms: exchangeable, bound to carbonates, bound to Fe-Mn oxides, bound to organic matter and residual. The analyses were determined by using an ICP-MS. Total Cr concentrations in the sediments were in the range of 41.6-96.4, Cu 60.7-680, Zn 189-1954, Cd 33.1-83.4, and Pb 138-567 mg/kg. Results of sequential fractionation indicates that relatively high proportion ( ~44%) of Cu is associated with organic matter. A large proportion of Pb is associated with three types of chemical forms: Fe-Mn oxides, organic matter, and residual. There were significant correlation in concentrations between the exchangeable components and total organic carbons. The heavy metals In the residual phase cannot be easily released to the environment since these are bound to the crystal lattice. But, reducible and organic Phases con a significant amount of most heavy metals. Therefore, there is Potential dancer of a substantial amount of metals becoming chemically mobile with environmental changes.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.4
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• pp.160-164
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• 2008

Insulating and conducting 12CaO ${\cdot}7Al_2O_3$ (Cl2A7)-doped indium tin oxide (ITO) (ITO:Cl2A7 insulator and electride) thin films were deposited on glass substrates by an RF magnetron co-sputtering method with increasing number of insulating and conducting Cl2A7 target chips. The structural, electrical and optical properties of these films were investigated. The carrier concentration decreased and resistivity increased in the films with increasing number of Cl2A7 target chips. The optical transmittance of all of the thin films was above 80 % in the visible wavelength range. The structural property and surface roughness of the films were examined and the decrease of crystallinity and surface roughness was strongly dependent on the change of grain size.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.16 no.4
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• pp.166-171
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• 2006

[ $Cu_2O$ ] and Cu have been synthesized from the layered organic-inorganic hybrid, $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$, assisted by microwave irradiation. $Cu_2O$ is formed in aqueous glucose solution, while metallic Cu is formed in ethylene glycol by reduction of $Cu_2(OH)_3(CH_3COO){\cdot}H_2O$. The influence of microwave irradiation time and concentration of glucose on $Cu_2O$ particles formation and growth has been examined. The morphologies of $Cu_2O$ particles change from spheres with a few fm size to nanowires with diameter of 40 nm as increasing the microwave irradiation times.

• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.305-309
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• 2020

In this study, a series of ionic liquids based electrolytes for lithium batteries were prepared by mixing the anion functionalized ionic liquid, [DMIm][MPEGP] (1,3-dimethylimidazolium (2-methoxy(2-ethoxy(2-ethoxy)))-ethylphosphite), with the lithium salt, LiTf₂N (lithium bis(trifluoromethanesulfonyl)imide), and the concentration of lithium salt was varied between 0 and 3.0 molar ratio. We observed the ionic mixtures became opaque and spontaneously aggregated to form a thermotropic ionic liquid crystal. Extensive spectroscopic examinations of the ionic liquid crystals were carried out to investigate their self-organized structures and the ion transport behavior depending on the concentration of lithium salt. An increase in the ionic conductivity was observed for the ionic liquid crystals related to the ability to form ion diffusion pathways along the ordered structures, resulting in improved electrochemical performances of lithium batteries.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3749-3754
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• 2013

Two 3D isomorphous and isostructural complexes, namely, $[Zn(BDOA)(bpy)(H_2O)_2]_n$ (1) and $[Cd(BDOA)-(bpy)(H_2O)_2]_n$ (2); (BDOA = Benzene-1,4-dioxyacetic acid, bpy = 4,4'-bipyridine) were synthesized under hydrothermal conditions and characterized by means of elemental analyses, thermogravimetric (TG), infrared spectrometry, and single crystal X-ray diffraction. Complexes 1 and 2 crystallize in the triclinic system, space group P-1 and each metal ion in the complexes are six-coordinated with the same coordination environment. In the as-synthesized complexes, $BDOA^{2-}$ anions link central metal ions to form a 1D zigzag chain $[-BDOA^{2-}-Zn(Cd)-BDOA^{2-}-Zn(Cd)-]_{\infty}$, whereas bpy pillars connect metal ions to generate a 1D linear chain $[-bpy-Zn(Cd)-bpy-Zn(Cd)-]_{\infty}$. Both infinite chains are interweaved into 2D grid-like layers which are further constructed into a 3D open framework, where hydrogen bonds play as the bridges between the adjacent 2D layers. Luminescent properties of complex 1 showed selectivity for $Hg^{2+}$ ion.

• Bulletin of the Korean Chemical Society
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• v.26 no.8
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• pp.1260-1264
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• 2005

Three new quaternary tantalum thiophosphates, $K_{0.18}TaPS_6,\;K_{0.28}TaPS_6,\;and\;Rb_{0.09}TaPS_6$ have been synthesized by using reactive alkali metal halide fluxes and structurally characterized by single crystal X-ray diffraction techniques. The crystal structures of $K_{0.18}TaPS_6,\;K_{0.28}TaPS_6,\;and\;Rb_{0.09}TaPS_6$ contain 3-dimensional open framework anions, $[TaPS_6]^{x-}$(x = 0.09, 0.18, 0.28) with the empty channel which disordered alkali metal cations, $K^+\;and\;Rb^+$ are located in. Crystal data: $K_{0.18}TaPS_6$, tetragonal, space group$I4_1$/acd (no. 142), a=15.874(3) $\AA$, c=13.146(4) $\AA$, V=3312.7(12) ${\AA}^3$, K, Z=16, R1=0.0545. Crystal data: $K_{0.28}TaPS_6$, tetragonal, space group $I4_1$/acd (no. 142), a=15.880(2) $\AA$, c=13.134(3) $\AA$, V=3312.1(10) ${\AA}^3$, Z=16, R1=0.0562. Crystal data: $Rb_{0.09}TaPS_6$, tetragonal, space group I41/acd (no. 142), a=15.893(3) $\AA$, c=13.163(4) $\AA$, V=3324.7(15) ${\AA}^3$, Z=16, R1=0.0432.