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http://dx.doi.org/10.5012/bkcs.2013.34.12.3749

Two 3D CdII and ZnII Complexes Based on Flexible Dicarboxylate Ligand and Nitrogen-containing Pillar: Synthesis, Structure, and Luminescent Properties  

Liu, Liu (Henan Key Laboratory of Polyoxometalate, Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University)
Fan, Yan-Hua (Henan Key Laboratory of Polyoxometalate, Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University)
Wu, Lan-Zhi (Henan Key Laboratory of Polyoxometalate, Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University)
Zhang, Huai-Min (Henan Key Laboratory of Polyoxometalate, Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University)
Yang, Li-Rong (Henan Key Laboratory of Polyoxometalate, Institute of Molecule and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.12, 2013 , pp. 3749-3754 More about this Journal
Abstract
Two 3D isomorphous and isostructural complexes, namely, $[Zn(BDOA)(bpy)(H_2O)_2]_n$ (1) and $[Cd(BDOA)-(bpy)(H_2O)_2]_n$ (2); (BDOA = Benzene-1,4-dioxyacetic acid, bpy = 4,4'-bipyridine) were synthesized under hydrothermal conditions and characterized by means of elemental analyses, thermogravimetric (TG), infrared spectrometry, and single crystal X-ray diffraction. Complexes 1 and 2 crystallize in the triclinic system, space group P-1 and each metal ion in the complexes are six-coordinated with the same coordination environment. In the as-synthesized complexes, $BDOA^{2-}$ anions link central metal ions to form a 1D zigzag chain $[-BDOA^{2-}-Zn(Cd)-BDOA^{2-}-Zn(Cd)-]_{\infty}$, whereas bpy pillars connect metal ions to generate a 1D linear chain $[-bpy-Zn(Cd)-bpy-Zn(Cd)-]_{\infty}$. Both infinite chains are interweaved into 2D grid-like layers which are further constructed into a 3D open framework, where hydrogen bonds play as the bridges between the adjacent 2D layers. Luminescent properties of complex 1 showed selectivity for $Hg^{2+}$ ion.
Keywords
Benzene-1,4-dioxyacetic acid; Isomorphous; Metal-Organic frameworks; Luminescent properties;
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