• 상하수도학회지
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• 제25권2호
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• pp.223-230
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• 2011

An electrolytic oxidation process was applied to remove odorous compounds from non-point odor sources including wastewater pipelines and manholes. In this study, a distance between the anode and the cathode of the electrolytic process was varied as a system operating parameters, and its effects on odor removal efficiencies and reaction characteristics were investigated. Odor precursors such as sediment organic matters and reduced sulfur/nitrogen compounds were effectively oxidized in the electrolytic process, and a change in oxidation-reduction potential (ORP) indicated that an stringent anaerobic condition shifted to a mild anoxic condition rapidly. At an electrode distance of 1 cm and an applied voltage of 30 V, a system current was maintained at 1 A, and the current density was 23.1 $mA/cm^{2}$. Under the condition, the removal efficiency of hydrogen sulfide in gas phase was found to be 100%, and 93% of ammonium ion was removed from the liquid phase during the 120 minute operating period. Moreover, the sulfate ion (${SO_4}^{2-}$) concentration increased about three times from its initial value due to the active oxidation. As the specific power consumption (i.e., the energy input normalized by the effective volume) increased, the oxidation progressed rapidly, however, the oxidation rate was varied depending on target compounds. Consequently, a threshold power consumption for each odorous compound needs to be experimentally determined for an effective application of the electrolytic oxidation.

• 한국축산시설환경학회지
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• 제19권1호
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• pp.1-8
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• 2013

Slurry treatments included peanut shell, palm golden fiber, almond hull, which was added 2% of the amount of slurry, and non-treatment control (n=4 each group). Levels of odorous compounds were measured from the liquid slurry incubated in $20^{\circ}C$ for 2 wk in chamber whose structure is similar to slurry pit. Concentration of phenols and indoles was higher (p<0.05) in control (48.4, 4.0 ppm) compared to almond hull (31.5, 1.4 ppm) or palm golden fiber (29.1, 1.6 ppm) group. Short chain fatty acid (SCFA) level was lowest (p<0.05) in control (2,121 ppm) but highest in peanut shell group (3,640 ppm). Branched chain fatty acid (BCFA) concentration was highest (p<0.05) in peanut shell (296 ppm), but lowest in almond hull (90 ppm). Taken together, concentration of odorous compounds was decreased by addition of almond hull in pig slurry by which crude fiber and non-digestible fiber (NDF) may act as a carbon source.

• 한국물환경학회지
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• 제31권5호
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• pp.460-467
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• 2015

We analyzed the formation of phytoplankton community and the occurences of odorus compound from benthic cyanobacteria in North, South Han-River, Paldang-Lake and Kyeongan-Stream sediments. Sediments were incubated in different water temperature. Akinetes were found (0~500 cells/g) with the highest number on sediment in Yangsoo railroad bridge (YC). The result showed that Anabaena ranged between $0.02{\sim}0.53{\times}10^3cells/mL$ in Sambong (SB), YC, Mukhyen-Stream (MS), Paldang-Lake (P2) and Kyeongan-Stream (KK). The total 68 taxa of phytoplankton were observed during the incubation period. A standing crop of phytoplankton was in the range of $0.13{\sim}8.97{\times}10^3cells/mL$ and Microcystis appeared in SB, YC, P2 and KK sites with $20{\sim}25^{\circ}C$ temperature. In South Han-River (P3), Oscillatoria tenuis was dominant at $25^{\circ}C$ temperature. The concentration of geosmin was the highest in SB-$15^{\circ}C$ (25.5 ng/L), and the concentration of 2-MIB was the highest in P3-$25^{\circ}C$ (286.8 ng/L). Odorous compounds were detected in all the temperature conditions from each site. Our results indicate that the dominant benthic cyanobacteria (O. tenuis, O. limosa, Phormidium tenue and Pseudanabaena limnetica) have high correlation with the occurrence odorous compounds and 2-MIB.

• 한국대기환경학회지
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• 제23권6호
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• pp.666-674
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• 2007

In this study, sampling and analysis was carried out for 13 compounds, in order to investigate the odorous compound emissions from landfill stacks and surrounding ambient air. These results revealed that concentration of hydrogen sulfide was $0.13{\sim}0.66\;ppb$ in the ambient air. Also, concentrations of hydrogen sulfide ($151{\sim}358\;ppm$) were the highest value in odorous sulfur compounds from landfill stacks. In case of VOC, toluene was obtained the highest out of volatile organic compounds. It was found that the concentrations of hydrogen sulfide near the landfill was higher than that inside city such as Seoul although it was located in a rural area. The result was due to the effect of hydrogen sulfide emitted from landfill stacks.

• Journal of Microbiology and Biotechnology
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• 제27권7호
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• pp.1316-1323
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• 2017

Geosmin and 2-methylisoborneol (2-MIB), responsible for earthy or musty smell, are a major concern for safe drinking water supplies. This study investigated the effects of environmental factors on odorous compound production and cell growth in cyanobacterial strains. Anabaena sp. FACHB-1384, a 2-MIB producer, was sensitive to low temperature (<$20^{\circ}C$). However, geosmin producers, Anabaena sp. Chusori and Anabaena sp. NIER, were sensitive to high light intensity (>$100{\mu}mol/m^2/sec$), but not to low temperature. Geosmin concentrations increased under higher nitrate concentrations, being linearly proportional to cell density. A P-limited chemostat showed that P-stress decreased the geosmin productivity and extracellular geosmin amount per cell in Anabaena sp. NIER. However, only 2-MIB productivity was reduced in Planktothrix sp. FACHB-1374 under P-limitation. The extracellular 2-MIB amount per cell remained constant at all dilution rates. In conclusion, high light intensity and P-stress can contribute to the lower incidence of geosmin, whereas 2-MIB reduction could be attainable at a lower temperature.

• 한국축산시설환경학회지
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• 제19권2호
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• pp.89-94
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• 2013

This study was performed to investigate the effect of beet plup and IRG (Italian ryegrass) dry powder in fattening pig diet on reducing concentration of odorous compounds in the pig slurry. Fifty fattening boars [(Landrace ${\times}$ Yorkshire) ${\times}$ Duroc] were randomly assigned to one of 3 treatments (control, beet plup 5%, and IRG 5%). Pigs (BW 50~110 kg) were fed diets formulated to meet the Korean Feeding Standard (2012) and their excretion was collected from the slurry pits. Short chain fatty acid (SCFA) and branched chain fatty acid (BCFA) were higher in beet plup (31,786, 3,985 ppm) and IRG (32,755, 4,261 ppm) treatments, which was not different among treatments (p>0.05), compared to control (p<0.05). Concentrations of phenols and indoles were highest in beet plup (183.83, 168.59 ppm) and IRG (9.32, 8.92 ppm) treatments. Altogether, addition level of two contents was not appropriate to decrease concentration of odorous compounds.

• 한국축산시설환경학회지
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• 제18권sup호
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• pp.35-40
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• 2012

본 연구는 사료에 서양고추냉이 분말 0.03%, 팽이버섯폐배지 0.5% 및 서양고추냉이 분말 0.03%와 팽이버섯폐배지 0.5%의 혼합제를 사료에 각각 첨가한 후 비육돈에 급여하여 분뇨에서 발생되는 악취물질의 농도변화를 조사하였다. 1. 분뇨의 단쇄지방산 농도를 측정한 결과 초산, 프로피온산, 부티르산 및 이성체지방산의 농도는 처리구간에 차이가 없었다(p>0.05). 2. 분뇨의 페놀, p-크레졸 및 이들을 합한 페놀류 농도는 처리구간에 차이가 없었다(p>0.05). 그러나 인돌 농도는 고추냉이 처리구에서 낮았으며(p<0.05), 스카톨 농도는 대조구와 고추냉이구에서 가장 높았고, 고추냉이와 버섯폐배지의 혼합구에서 가장 낮았으며, 버섯폐배지구는 중간이었다(p<0.05). 인돌류 농도는 고추냉이와 버섯폐배지의 혼합구에서 가장 낮았다(p<0.05).

• 한국대기환경학회지
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• 제23권1호
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• pp.39-49
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• 2007

In this study, the performance characteristics of solid phase microextraction (SPME) were investigated for three major odorous groups that consist of 10 individual compounds ([1] volatile organic compounds (VOC): benzene, toluene, p-xylene and styrene, [2] reduced sulfur compounds (RSC): hydrogen sulfide, methyl mercaptan, dimethylsulfide (DMS), dimethyldisulfide (DMDS), and carbon disulfide, and [3] amine: trimethylamine (TMA)). For the purpose of a comparative analysis, two types of SPME fiber ([1] polidimethylsiloxane/divinilbenzene (P/D) and [2] $Carboxen^{TM}$/polidimethylsiloxane (C/P)) were test ε d against each other for a series of standards prepared at different concentration levels (100, 200, and 500 ppb). To compare the analytical performance of each fiber, all standards were analyzed for the acquisition of calibration data sets for each compound. The results of P/D fiber generally showed that its calibration slope increased as a function of molecular weight across different VOCs; however, those of C/P fiber showed a fairly reversed trend. Besides, we confirmed that the application of SPME is limited to many sulfur compounds; only two compounds (DMS and DMDS) are sensitive enough to draw calibration results out of SPME. The calibration data for RSC show generally enhanced slop values for C/P relative to P/D fiber. However, in the case of TMA, we were not able to find a notable difference in their performance.

• 상하수도학회지
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• 제25권6호
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• pp.815-824
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• 2011

In this study, a non-thermal plasma system was employed to simultaneously remove odorous compounds and organic sludge. The system consisted of two reactors; the first one was the non-thermal plasma reactor where ozone was produced by the plasma reaction and the ozone oxidized hydrogen sulfide, the model odorous compound, and then the ozone-laden gas stream was introduced to the second reactor where wasted sludge was disintegrated and solubilized by ozone oxidation. In this study, the gas retention time (GRT) and the hydraulic retention time (HRT) were changed in the two-reactor system, and the effects of GRT and HRT on reduction efficiencies of odor and sludge were determined. As the GRT increased, the ozone concentration increased resulting in an increasing efficiency of hydrogen sulfide removal. However, the overall ozone loading rate to the second sludge reactor was the same at any GRT, which resulted in an insignificant change in sludge reduction rate. When HRTs in the sludge reactor were 1, 2, 4 hours, the sludge reduction rates were approximately 30% during the four-hour operation, while the rate increased to 70% at the HRT of 6 hours. Nevertheless, at HRTs greater than 4 hours, the solubilization efficiency was not proportionally increased with increasing specific input energy, indicating that an appropriate sludge retention time needs to be applied to achieve effective solubilization efficiencies at a minimal power consumption for the non-thermal plasma reaction.

• 한국축산시설환경학회지
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• 제19권1호
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• pp.25-32
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• 2013

This study was performed to analyse the concentration of odorous compounds in the piggeries. Piggeries for different types of pigs include piglets, growing pigs, gestating and lactating sows. Slurry from these piggeries was sampled every month for chemical analysis. Short chain fatty acid (SCFA) was 9,862 ppm (piglet), 8,410 ppm (growing pigs), 6,791 ppm (fattening pigs), 3,508 ppm (lactating sows) and 1,687 ppm (gestating sows). Branched chain fatty acid (BCFA) was 1,634 ppm (piglet), 1,206 ppm (growing pigs), 868 ppm (fattening pigs), 493 ppm (lactating sows) and 185 ppm (gestating sows). Concentration of phenols was 209 ppm (piglet), 166 ppm (growing pigs), 127 ppm (fattening pigs), 85 ppm (lactating sows) and 36 ppm (gestating sows). Indoles was 18 ppm (piglet), 14 ppm (growing pigs), 8 ppm (fattening pigs), 6 ppm (lactating sows) and 4 ppm (gestating sows). Altogether, concentration of odorous compounds was decreased as pigs got aged.