• 한국잠사곤충학회지
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• 제29권1호
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• pp.7-11
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• 1987

1. 식재당년 비닐 피복은 무피복에 비해 탈포기는 2일, 연구기는 3일 앞당겼다. 2. 피복은 최장 가지 길이를 16.9-25.3cm 더 증가시켰으나, 2,780주 이상 밀식한 경우는 피복의 효과가 떨어졌다. 3. 밀식할수록 엽장과 폭이 작아지고, 가지 기부의 황변된 잎의 수는 증가하였다. 4. 밀식은 주당 가지수와 조장은 감소시켰으며, 정상지에 대한 왜소지의 비율은 증가시켰다. 그러나 10a당 가지수와 총조장은 증가하였다. 5. 식재밀도별 경년적 뽕잎 수량의 변이는 식재후 2년차까지는 계속 증가하였으나, 그 후부터 1,677주구는 926주구에 비해 증가 폭이 둔화되었고, 이보다 밀식한 구에서는 떨어지는 경향이었다. 6. 식재후 5년간 평균 뽕잎 수량은 2,780주구에서 가장 많아서 926주구 대비 46.6% 증수를 보였으며, 3,444주구가 다음으로 40%를, 1,667주구에서 29.9% 증수를 보였다. 7. 식재후 토양의 화학성은 pH, 유기물, Ca, Mg 등이 떨어졌으며, 926주 이상 심을 때는 인산, pH, O.M, Ca, Mg등의 함량이 저하되었다.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.2877-2882
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• 2013

Second-order rate constants ($k_{Ox^-}$) have been measured spectrophotometrically for nucleophilic substitution reactions of 4-nitrophenyl X-substituted-cinnamates (7a-7e) and Y-substituted-phenyl cinnamates (8a-8e) with butane-2,3-dione monoximate ($Ox^-$) in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The Hammett plot for the reactions of 7a-7e consists of two intersecting straight lines while the Yukawa-Tsuno plot exhibits an excellent linearity with ${\rho}_X$=0.85 and r=0.58, indicating that the nonlinear Hammett plot is not due to a change in the rate-determining step but is caused by resonance stabilization of the ground state (GS) of the substrate possessing an electron-donating group (EDG). The Br${\o}$nsted-type plot for the reactions of Y-substituted-phenyl cinnamates (8a-8e) is linear with ${\beta}_{lg}$ = -0.64, which is typical of reactions reported previously to proceed through a concerted mechanism. The ${\alpha}$-nucleophile ($Ox^-$) is more reactive than the reference normal-nucleophile ($4-ClPhO^-$). The magnitude of the ${\alpha}$-effect (i.e., the $k_{Ox^-}/k_{4-ClPhO^-}$ ratio) is independent of the electronic nature of the substituent X in the nonleaving group but increases linearly as the substituent Y in the leaving group becomes a weaker electron-withdrawing group (EWG). It has been concluded that the difference in solvation energy between $Ox^-$ and $4-ClPhO^-$ (i.e., GS effect) is not solely responsible for the ${\alpha}$-effect but stabilization of transition state (TS) through a cyclic TS structure contributes also to the Y-dependent ${\alpha}$-effect trend (i.e., TS effect).

• 인간식물환경학회지
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• 제24권6호
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• pp.629-638
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• 2021

Background and objective: This study was conducted to develop diameter growth models for thinned Quercus glauca Thunb. (QGT) stands to inform production goals for treatment and provide the information necessary for the systematic management of this stands. Methods: This study was conducted on QGT stands, of which initial thinning was completed in 2013 to develop a treatment system. To analyze the tree growth and trait response for each thinning treatment, forestry surveys were conducted in 2014 and 2021, and a one-way analysis of variance (ANOVA) was executed. In addition, non-linear least squares regression of the PROC NLIN procedure was used to develop an optimal diameter growth model. Results: Based on growth and trait analyses, the height and height-to-diameter (H/D) ratio were not different according to treatment plot (p > .05). For the diameter of basal height (DBH), the heavy thinning (HT) treatment plot was significantly larger than the control plot (p < .05). As a result of the development of diameter growth models by treatment plot, the mean squared error (MSE) of the Gompertz polymorphic equation (control: 2.2381, light thinning: 0.8478, and heavy thinning: 0.8679) was the lowest in all treatment plots, and the Shapiro-Wilk statistic was found to follow a normal distribution (p > .95), so it was selected as an equation fit for the diameter growth model. Conclusion: The findings of this study provide basic data for the systematic management of Quercus glauca Thunb. stands. It is necessary to construct permanent sample plots (PSP) that consider stand status, location conditions, and climatic environments.

• 한국통계학회:학술대회논문집
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• 한국통계학회 2000년도 추계학술발표회 논문집
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• pp.187-191
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• 2000

In the analysis of repeated measurements, multivariate regression models that account for the correlations among the observations from the same subject are widely used. Like the usual univariate regression models, these multivariate regression models also need some model diagnostic procedures. In this paper, we propose a simple graphical method to detect outliers and to investigate the goodness of model fit in repeated measures data. The graphical method is based on the quantile-quantile(Q-Q) plots of the $X^2$ distribution and the standard normal distribution. We also propose diagnostic measures to detect influential observations. The proposed method is illustrated using two examples.

• KSTLE International Journal
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• 제5권1호
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• pp.1-6
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• 2004

Nano-scale studies on adhesion and friction were conducted in Si-wafer (100) using Atomic Force Microscopy (AFM). Glass (Borosilicate) balls of radii 0.32$\mu\textrm{m}$, 1.25$\mu\textrm{m}$, and 2.5$\mu\textrm{m}$, mounted on cantilever (Contact Mode type NPS) were used as tips. Adhesion and friction between Si-wafer and glass tips were measured at ambient temperature (24${\pm}$1$^{\circ}C$) and humidity (45${\pm}$5%). Friction was measured as a function of applied normal load in the range of 0-160 nN. Results showed that, both adhesion and friction increased with the tip radii. Also, friction increased linearly as a function of applied normal load. The effect of tip size on adhesion and friction was explained as the influence of the capillary force exerted by meniscus and that of the contact area on these parameters respectively. The coefficient of friction was estimated in two different ways, as the slope from the plot of friction force against the applied normal load and as the ratio between the friction force and the applied normal load. Both these estimates showed that the coefficient of friction increased with the tip size. Further, the influence of the adhesion force on the coefficient of friction was also discussed.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.63-67
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• 2013

A bottom-modified (4-position) naphthalimide derivative 1 with 1,8-naphthyridine as binding site has been designed and synthesized. Compound 1 is the first 1,8-naphthyridine-modified naphthalimide-based sensor that can detect $Hg^{2+}$ selectively with respect to ratiometric fluorescent change and blue shift in organic aqueous solution. The Job's plot and FAB mass indicate that 1 formed a 1:1 complex with $Hg^{2+}$. A top-modified naphthalimide derivative 2 with 1,8-naphthyridin as binding site has also been synthesized for comparison.

• Bulletin of the Korean Chemical Society
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• 제34권5호
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• pp.1467-1472
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• 2013

Metabolomics is a field that studies systematic dynamics and secretion of metabolites from cells to understand biological pathways based on metabolite changes. The metabolic profiling of intact human colorectal tissues was performed using high-resolution magic angle spinning (HR-MAS) NMR spectroscopy, which was unnecessary to extract metabolites from tissues. We used two different groups of samples, which were defined as normal and cancer, from 9 patients with colorectal cancer and investigated the samples in NMR experiments with a water suppression pulse sequence. We applied target profiling and multivariative statistical analysis to the analyzed 1D NMR spectra to identify the metabolites and discriminate between normal and cancer tissues. Cancer tissue showed higher levels of arginine, betaine, glutamate, lysine, taurine and lower levels of glutamine, hypoxanthine, isoleucine, lactate, methionine, pyruvate, tyrosine relative to normal tissue. In the OPLS-DA (orthogonal partial least square discriminant analysis), the score plot showed good separation between the normal and cancer groups. These results suggest that metabolic profiling of colorectal cancer could provide new biomarkers.

• 한국토양비료학회지
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• 제40권3호
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• pp.201-207
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• 2007

답리작 보리재배 후 보릿짚을 시용하고 관개량, 경운방법을 달리하여 만추벼를 전북통에서 2년 동안 재배시 토양이화학성, 작업정도, 생육 및 수량성을 검토한 결과는 다음과 같다. 보릿짚 시용 후 경운방법 및 관개량에 따른 작업정도는 마른로타리 1회 + 물 로타리 1회 처리구에서 경운 + 물 로타리 1회(관행)보다 보릿짚 피복정도가 적었고 결주율 2.6%, 부묘율 1.7% 낮았으며 관개량이 많을수록 결주율과 부묘율이 낮아지는 경향을 나타냈다. 토양이화학성 변화는 마른로타리 1회 + 물 로타리 1회 처리구 심토에서 토양경도, 용적밀도가 낮아지고 공극율, 기상율이 증가되어 토양물리성이 개선되었으며 마른로타리 1회 + 물 로타리 1회 처리구에서 CEC가 높아지고 유기물, 유효인산 함량이 증가되었으며 C/N율이 낮아져 토양화학성이 개량되었다. 경운방법에 따른 벼의 유효경비율은 마른로타리 1회 + 물 로타리 2회 > 마른로타리 1회 + 물 로타리 1회 > 경운 + 물 로타리 1회 > 물 로타리 1회 순으로 높았으며 쌀 수량은 $500Mg\;ha^{-1}$ 관개시 마른로타리 1회 + 물 로타리 1회, $700Mg\;ha^{-1}$ 관개시 마른로타리 1회 + 물 로타리 2회 처리구에서 수수 및 영화수 확보가 많았고 현미천립중이 무거워 경운 + 물 로타리 1회(관행) 대비 각각 7%, 5% 증수되었다.

• 한국수산과학회지
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• 제29권3호
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• pp.386-392
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• 1996

A numerical method based on genetic algorithms was introduced to characterize the grain-size distribution more effectively. This technique was proved significant particularly for multimodal size distributions, as was verified for samples from Korea Strait continental shelf. Sediment samples collected from the Korea Strait continental shelf revealed that $96\%$ of the grain-size distributions were multimodal. Therefore, the use of grain-size parameters was not the ideal method. As an alternative method, the decomposition of sue curves into elementary normal component curves was used. Means and standard deviations of 593 decomposed normal components were calculated by a numerical method from 268 size curves of Korea Strait sediments. The mean values of decomposed normal components showed peaks at $1\~3\phi\;and\;7\~9\phi$ size classes. The plot of mean and standard deviation values of the coarse fraction normal components on the map showed a characteristic areal distribution. The characteristic distribution was found to derive from underlying Pleistocene sediment on the basis of sea bottom geologic distribution of the area. The method of decomposition into normal components was found to be more effective than the analysis using traditional grain-size parameters in investigation of multimodal size distribution of Korea Strait shelf sediment.

• Journal of Plant Biology
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• 제20권3호
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• pp.127-134
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• 1977

In order to investigate the changes of free amino acids during the differentiation and development of young spike in naked barley, a typical spring grain, Wanju, and two winter grains, Sedohadaka and Nonsankwa No. 1-6 differing in their spring habits, were analyzed at different growth stages by thin layer chromatography. In all the varieties 22 ninhydrin positive components were detected at the sowing time of March 5 and 20 components in the sowing plots of March 30. In case of the latter plot, β-alanine was identified only in both Wanju and Sedohadaka, whereas pipecolic acid was detected only in Nonsankwa No. 1-6. Particularly, it is interesting that β-alanine was observed only in the case showing the normal heading independent of the varieties and sowing times. Whether these components are directly related to the physiology of spring habits in barley or not is also a question to be answered. Of the major amino acids, alanine and γ-aminobutyric acid were always detected in appreciably large spots, and serine, leucine, aspartic acid, valine and asparagine were somewhat larger. In the plot of march 30, glutamic acid was also detected in very large spot in both Wanju and Sedohadaka at the stage of spikelet differentiation and in Nonsankwa No. 1-6 at the stage of bract differentiation. Histidine, which showed the only qualitative difference among the varieties during seed germination, cannot be observed at all. Proline observed considerably large spot during seed germination was always detected but very small except that it was observed in large spot at the stage of floret differentiation in Nonsankwa No. 1-6 in the plot of March 5.